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Calorescence
Calorescence is a term describing the process whereby matter absorbs infrared radiant energy and emits visible radiant energy in its place. For example, some kinds of flammable gas give off large amounts of radiant heat and very little visible light when burning, and if a piece of metal is placed into such a flame, the metal will become bright red-hot—which is to say the metal absorbs invisible infrared and emits visible radiation. The word ''calorescence'' was coined by John Tyndall in 1864 on the model of the word ''fluorescence'' which had been coined in 1852. At that time, fluorescence was defined as absorption in the ultraviolet part of the spectrum followed by emission in the visible part of the spectrum. Calorescence was defined complementarily as absorption in the infrared followed by emission in the visible. Earlier, George Stokes had shown the reverse phenomenon: the emission of infrared following the absorption of visible light. The following is a laboratory demonst ...
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John Tyndall
John Tyndall (; 2 August 1820 – 4 December 1893) was an Irish physicist. His scientific fame arose in the 1850s from his study of diamagnetism. Later he made discoveries in the realms of infrared radiation and the physical properties of air, proving the connection between atmospheric Carbon dioxide, CO and what is now known as the greenhouse effect in 1859. Tyndall also published more than a dozen science books which brought state-of-the-art 19th century experimental physics to a wide audience. From 1853 to 1887 he was professor of physics at the Royal Institution of Great Britain in London. He was elected as a member to the American Philosophical Society in 1868. Early years and education Tyndall was born in Leighlinbridge, County Carlow, Ireland. His father was a local police constable, descended from Gloucestershire emigrants who settled in southeast Ireland around 1670. Tyndall attended the local schools (Ballinabranna Primary School) in County Carlow until his late t ...
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Infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those of red light (the longest waves in the visible spectrum), so IR is invisible to the human eye. IR is generally (according to ISO, CIE) understood to include wavelengths from around to . IR is commonly divided between longer-wavelength thermal IR, emitted from terrestrial sources, and shorter-wavelength IR or near-IR, part of the solar spectrum. Longer IR wavelengths (30–100 μm) are sometimes included as part of the terahertz radiation band. Almost all black-body radiation from objects near room temperature is in the IR band. As a form of EMR, IR carries energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon. It was long known that fires e ...
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Emission Spectroscopy
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances. Emission In physics, emission is the process by which a higher energy quantum mechanical state of a particle becomes converted to a lower one through the emission of a photon, resulting in the production of light. ...
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Incandescence
Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electronic, molecular, and lattice oscillations in a material. Kinetic energy is converted to electromagnetism due to Larmor formula, charge-acceleration or dipole oscillation. At room temperature, most of the emission is in the infrared (IR) spectrum, though above around 525 °C (977 °F) enough of it becomes Visible spectrum, visible for the matter to visibly glow. This visible glow is called incandescence. Thermal radiation is one of the fundamental mechanisms of heat transfer, along with Thermal conduction, conduction and Convection (heat transfer), convection. The primary method by which the Sun transfers heat to the Earth is thermal radiation. This energy is partially absorbed and scattered in the atmosphere, the latter process bei ...
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Luminescence
Luminescence is a spontaneous emission of radiation from an electronically or vibrationally excited species not in thermal equilibrium with its environment. A luminescent object emits ''cold light'' in contrast to incandescence, where an object only emits light after heating. Generally, the emission of light is due to the movement of electrons between different energy levels within an atom after excitation by external factors. However, the exact mechanism of light emission in vibrationally excited species is unknown. The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as ''luminising''. Types * Ionoluminescence, a result of bombardment by fast ions * Radioluminescence, a result of bombardment by ionizing radiation * Electroluminescence, a result of an electric current passed through a substance ** Cathodoluminescence, a result of a luminescent material being struck by elect ...
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Photon Upconversion
Photon upconversion (UC) is a process in which the sequential Absorption (electromagnetic radiation), absorption of two or more photons leads to the Emission spectrum, emission of light at shorter wavelength than the excitation wavelength. It is an Stokes shift, anti-Stokes type emission. An example is the conversion of infrared light to visible light. Upconversion can take place in both organic and inorganic materials, through a number of different mechanisms. Organic molecules that can achieve photon upconversion through triplet-triplet annihilation are typically Polycyclic aromatic hydrocarbon, polycyclic aromatic hydrocarbons (PAHs). Inorganic materials capable of photon upconversion often contain ions of d-block or f-block elements. Examples of these ions are lanthanides, Ln3+, titanium, Ti2+, nickel, Ni2+, molybdenum, Mo3+, rhenium, Re4+, osmium, Os4+, and so on. Physical mechanisms There are three basic mechanisms for photon upconversion in inorganic materials and at leas ...
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Photoluminescence
Photoluminescence (abbreviated as PL) is light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (i.e. photons that excite electrons to a higher energy level in an atom), hence the prefix ''photo-''. Following excitation, various relaxation processes typically occur in which other photons are re-radiated. Time periods between absorption and emission may vary: ranging from short femtosecond-regime for emission involving free-carrier plasma in inorganic semiconductorsHayes, G.R.; Deveaud, B. (2002). "Is Luminescence from Quantum Wells Due to Excitons?". ''Physica Status Solidi A'' 190 (3): 637–640doi:10.1002/1521-396X(200204)190:33.0.CO;2-7/ref> up to milliseconds for phosphoresence processes in molecular systems; and under special circumstances delay of emission may even span to minutes or hours. Observation of photoluminescence at a certain ...
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Platinum
Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name originates from Spanish language, Spanish , a diminutive of "silver". Platinum is a member of the platinum group of elements and group 10 element, group 10 of the periodic table of elements. It has six naturally occurring isotopes. It is one of the Abundance of elements in Earth's crust, rarer elements in Earth's crust, with an average abundance of approximately 5 microgram, μg/kg, making platinum about 30 times rarer than gold. It occurs in some nickel and copper ores along with some Native element mineral, native deposits, with 90% of current production from deposits across Russia's Ural Mountains, Colombia, the Sudbury Basin, Sudbury basin of Canada, and a large reserve in South Africa. Because of its scarcity in Earth's crust, only a f ...
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Water Absorption
The absorption of electromagnetic radiation by water depends on the state of matter, state of the water. The Absorption (electromagnetic radiation), absorption in the gas phase occurs in three regions of the spectrum. Rotational spectroscopy, Rotational transitions are responsible for absorption in the microwave and far-infrared, Vibrational transition, vibrational transitions in the mid-infrared and near-infrared. Vibrational bands have rotational fine structure. Electronic transitions occur in the vacuum ultraviolet regions. Its weak absorption in the visible light, visible spectrum results in the pale blue color of water. Overview The water molecule, in the gaseous state, has three types of transition that can give rise to absorption of electromagnetic radiation: * Rotational transitions, in which the molecule gains a quantum of rotational energy. Atmospheric water vapour at ambient temperature and pressure gives rise to absorption in the far-infrared region of the spec ...
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Emission (electromagnetic Radiation)
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances. Emission In physics, emission is the process by which a higher energy quantum mechanical state of a particle becomes converted to a lower one through the emission of a photon, resulting in the production of light ...
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Radiant Energy
In physics, and in particular as measured by radiometry, radiant energy is the energy of electromagnetic radiation, electromagnetic and gravitational radiation. As energy, its SI unit is the joule (J). The quantity of radiant energy may be calculated by Integral, integrating radiant flux (or radiant flux, power) with respect to time. The symbol ''Q''e is often used throughout literature to denote radiant energy ("e" for "energetic", to avoid confusion with photometric quantities). In branches of physics other than radiometry, electromagnetic energy is referred to using ''E'' or ''W''. The term is used particularly when electromagnetic radiation is emitted by a source into the surrounding environment. This radiation may be visible or invisible to the human eye. Terminology use and history The term "radiant energy" is most commonly used in the fields of radiometry, solar energy, heating and lighting, but is also sometimes used in other fields (such as telecommunications). In modern ...
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