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Calcium Chlorate
Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer. Production Calcium chlorate is produced by passing chlorine gas through a hot suspension of calcium hydroxide in water, producing calcium hypochlorite, which disproportionates when heated with excess chlorine to give calcium chlorate and calcium chloride: : 6 Ca(OH)2 + 6 Cl2 → Ca(ClO3)2 + 5 CaCl2 + 6 H2O This is also the first step of the Liebig process for the manufacture of potassium chlorate. In theory, electrolysis of hot calcium chloride solution will produce the chlorate salt, analogous to the process used for the manufacture of sodium chlorate. In practice, electrolysis is complicated by calcium hydroxide depositing on the cathode, preventing the flow of current. Reactions When concentrated solutions of calcium chlorate and potassium chloride are combined, potassium chlorate precipitates: : Ca(ClO3)2 + 2 KCl → 2 KClO3 + CaCl2 Th ...
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Deliquescent
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption (chemistry), absorption or adsorption from the surrounding Natural environment, environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g. changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance. For example, a finely dispersed hygroscopic powder, such as a salt, may become clumpy over time due to collection of moisture from the surrounding environment. ''Deliquescent'' materials are sufficiently hygroscopic that they dissolve in the water they absorb, forming an aqueous solution. Hygroscopy is essential for many plant and animal species' attainment of hydration, nutrition, reproduction and/or seed dispersal. Biological evolution created hygroscopic solutions for water harvesting, filament tensile strength, ...
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Calcium Hypochlorite
Calcium hypochlorite is an inorganic compound with chemical formula , also written as . It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. This compound is relatively stable as a solid and solution and has greater available chlorine than sodium hypochlorite. "Pure" samples have 99.2% active chlorine. Given common industrial purity, an active chlorine content of 65-70% is typical. It is the main active ingredient of commercial products called bleaching powder, used for water treatment and as a bleaching agent. History Charles Tennant and Charles Macintosh developed an industrial process in the late 18th century for the manufacture of chloride of lime, patenting it in 1799. Tennant's process is essentially still used today, and became of military importance during World War I, because calcium hypochlorite was the active ingredient in trench disinfectant. Uses Sanitation Calcium hypochlor ...
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Chlorates
Chlorate is the common name of the anion, whose chlorine atom is in the +5 oxidation state. The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid. Other oxyanions of chlorine can be named "chlorate" followed by a Roman numeral in parentheses denoting the oxidation state of chlorine: e.g., the ion commonly called perchlorate can also be called chlorate(VII). As predicted by valence shell electron pair repulsion theory, chlorate anions have trigonal pyramidal structures. Chlorates are powerful oxidizers and should be kept away from organics or easily oxidized materials. Mixtures of chlorate salts with virtually any combustible material (sugar, sawdust, charcoal, organic solvents, metals, etc.) will readily deflagrate. Chlorates were once widely used in pyrotechnics for this reason, though their use has fallen due to their instability. Most pyrotechnic applications that formerly used chlorates now use the more stab ...
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Sulfur
Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere Th ...
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Pyrotechnics
Pyrotechnics is the science and craft of creating fireworks, but also includes safety matches, oxygen candles, Pyrotechnic fastener, explosive bolts (and other fasteners), parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. This trade relies upon self-contained and self-sustained exothermic chemical reactions to make heat, light, gas, smoke and/or sound. The name etymology, comes from the Greek words ''pyr'' (πυρ; 'fire') and ''technikós'' (τεχνικός; 'artistic'). Improper use of pyrotechnics could lead to List of pyrotechnic incidents, pyrotechnic accidents. People responsible for the safe storage, handling, and functioning of pyrotechnic devices are known as pyrotechnicians. Proximate pyrotechnics Explosions, flashes, smoke, flames, fireworks and other pyrotechnic-driven effects used in the entertainment industry are referred to as proximate pyrotechnics. Proximate refers to the pyrotechnic device's location relative to ...
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Herbicide
Herbicides (, ), also commonly known as weed killers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page for EPA reports on pesticide use ihere Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides (sometimes called "total weed killers") kill plants indiscriminately. The combined effects of herbicides, nitrogen fertilizer, and improved cultivars has increased yields (per acre) of major crops by three to six times from 1900 to 2000. In the United States in 2012, about 91% of all herbicide usage, was determined by weight applied, in agriculture. In 2012, world pesticide expenditures totaled nearly US$24.7 billion; herbicides were about 44% of those sales and constituted the biggest portion, followed by insecticides, fungicides, and fumigants. Herbicide is also used ...
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Ammonium Chlorate
Ammonium chlorate is an inorganic compound with the formula NH4ClO3. It is obtained by neutralizing chloric acid with either ammonia or ammonium carbonate, or by precipitating barium, strontium or calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ... chlorates with ammonium carbonate or ammonium sulfate, producing the respective carbonate or sulfate precipitate and an ammonium chlorate solution. Ammonium chlorate crystallizes in small needles, readily soluble in water. The bitartrate method is a candidate for production and can be used if exotic chlorates are currently inaccessible or need to be synthesized. Warm solutions of potassium chlorate and ammonium bitartrate are needed. The latter can be synthesized by adding aqueous ammonia to an excess of tartaric acid. Then, ...
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Calcium Sulfate
Calcium sulfate (or calcium sulphate) is an inorganic salt with the chemical formula . It occurs in several hydrated forms; the anhydrous state (known as anhydrite) is a white crystalline solid often found in evaporite deposits. Its dihydrate form is the mineral gypsum, which may be dehydrated to produce bassanite, the hemihydrate state. Gypsum occurs in nature as crystals ( selenite) or fibrous masses ( satin spar), typically colorless to white, though impurities can impart other hues. All forms of calcium sulfate are sparingly soluble in waterFranz Wirsching "Calcium Sulfate" in Ullmann's Encyclopedia of Industrial Chemistry, 2012 Wiley-VCH, Weinheim. and cause permanent hardness when dissolved therein. Hydration states Calcium sulfate occurs at three levels of hydration with different crystallographic structures: anhydrous, dihydrate, and hemihydrate. The anhydrous ( anhydrite) crystallizes as an tightly-bound orthohombic lattice with space group Pnma, in which each ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Calcium Carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues. Chemistry Calcium carbonate shares the typical properties of other carbonates. Notably, it: *reacts with acids, releasing carbonic acid which quickly disintegrates into carbon dioxide and water: : *releases carbon dioxide upon heating, called a thermal decomposition reaction, or calcination (to above 840 °C in the case of ), t ...
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Potassium Chloride
Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. KCl is used as a salt substitute for table salt (NaCl), a fertilizer, as a medication, in scientific applications, in domestic water softeners (as a substitute for sodium chloride salt), as a feedstock, and in food processing, where it may be known as E number additive E508. It occurs naturally as the mineral sylvite, which is named after salt's historical designations ''sal degistivum Sylvii'' and ''sal febrifugum Sylvii'', and in combination with sodium chloride as sylvinite. Uses Fertilizer The majority of the potassium chloride produced is used for making fertilizer, called potash, since the growth of many plants is limited by potassium availabil ...
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Cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional current describes the direction in which positive charges move. Electrons, which are the carriers of current in most electrical systems, have a negative electrical charge, so the movement of electrons is ''opposite'' to that of the conventional current flow: this means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity ...
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