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Buckingham (unit)
The buckingham (symbol: B) is a CGS unit of electric quadrupole, named in honour of the chemical physicist A. David Buckingham who was the first to measure a molecular quadrupole moment. It is defined as . This is equivalent to 1 debye-ångström, where 1 debye = is the CGS unit of molecular dipole moment and 1 ångström = . One buckingham corresponds to the quadrupole moment resulting from two opposing dipole moments of equal magnitude of 1 debye that are separated by a distance of 1 ångström, a typical bond length. This is analogous to the debye for the dipole moment of two opposing charges of separated by 1 ångström, and the name Buckingham for the unit was suggested by Peter Debye Peter Joseph William Debye ( ; born Petrus Josephus Wilhelmus Debije, ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born in Maastricht, Neth ... in 1963 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Centimetre–gram–second System Of Units
The centimetre–gram–second system of units (CGS or cgs) is a variant of the metric system based on the centimetre as the unit of length, the gram as the unit of mass, and the second as the unit of time. All CGS mechanical units are unambiguously derived from these three base units, but there are several different ways in which the CGS system was extended to cover electromagnetism. The CGS system has been largely supplanted by the MKS system based on the metre, kilogram, and second, which was in turn extended and replaced by the International System of Units (SI). In many fields of science and engineering, SI is the only system of units in use, but CGS is still prevalent in certain subfields. In measurements of purely mechanical systems (involving units of length, mass, force, energy, pressure, and so on), the differences between CGS and SI are straightforward: the unit-conversion factors are all powers of 10 as and . For example, the CGS unit of force is the dyne, w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quadrupole
A quadrupole or quadrapole is one of a sequence of configurations of things like electric charge or current, or gravitational mass that can exist in ideal form, but it is usually just part of a multipole expansion of a more complex structure reflecting various orders of complexity. Mathematical definition The quadrupole moment tensor ''Q'' is a rank-two tensor—3×3 matrix. There are several definitions, but it is normally stated in the traceless form (i.e. Q_ + Q_ + Q_ = 0). The quadrupole moment tensor has thus nine components, but because of transposition symmetry and zero-trace property, in this form only five of these are independent. For a discrete system of \ell point charges or masses in the case of a gravitational quadrupole, each with charge q_\ell, or mass m_\ell, and position \mathbf_\ell = \left(r_, r_, r_\right) relative to the coordinate system origin, the components of the ''Q'' matrix are defined by: Q_ = \sum_\ell q_\ell\left(3r_ r_ - \left\, \mathbf_\el ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Physicist
Chemical physics is a branch of physics that studies chemical processes from a physical point of view. It focuses on understanding the physical properties and behavior of chemical systems, using principles from both physics and chemistry. This field investigates physicochemical phenomena using techniques from atomic and molecular physics and condensed matter physics. The United States Department of Education defines chemical physics as "A program that focuses on the scientific study of structural phenomena combining the disciplines of physical chemistry and atomic/molecular physics. Includes instruction in heterogeneous structures, alignment and surface phenomena, quantum theory, mathematical physics, statistical and classical mechanics, chemical kinetics, and laser physics." Distinction between chemical physics and physical chemistry While at the interface of physics and chemistry, chemical physics is distinct from physical chemistry as it focuses more on using physical t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statcoulomb
The statcoulomb (statC), franklin (Fr), or electrostatic unit of charge (esu) is the unit of measurement for electrical charge used in the centimetre–gram–second electrostatic units variant (CGS-ESU) and Gaussian systems of units. In terms of the Gaussian base units, it is That is, it is defined so that the proportionality constant in Coulomb's law using CGS-ESU quantities is a dimensionless quantity equal to 1. Definition and relation to CGS base units Coulomb's law in the CGS-Gaussian system takes the form F = \frac , where ''F'' is the force, ''q'' and ''q'' are the two electric charges, and ''r'' is the distance between the charges. This serves to define charge as a quantity in the Gaussian system. The statcoulomb is defined such that if two electric charges of 1 statC each and have a separation of , the force of mutual electrical repulsion is 1 dyne. Substituting ''F'' = 1 dyn, ''q'' = ''q'' = 1 statC, and ''r'' = 1 cm, we get: F ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Centimetre
upright=1.35, Different lengths as in respect to the electromagnetic spectrum, measured by the metre and its derived scales. The microwave is in-between 1 meter to 1 millimeter. A centimetre (International spelling) or centimeter (American English), with SI symbol cm, is a Units of measurement, unit of length in the International System of Units (SI) equal to one hundredth of a metre, ''centi-'' being the SI prefix for a factor of . Equivalently, there are 100 centimetres in 1 metre. The centimetre was the base unit of length in the now deprecated centimetre–gram–second (CGS) system of units. Though for many physical quantities, SI prefixes for factors of 103—like ''milli-'' and ''kilo-''—are often preferred by technicians, the centimetre remains a practical unit of length for many everyday measurements; for instance, human height is commonly measured in centimetres. A centimetre is approximately the width of the fingernail of an average adult person. Equivalenc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Debye
The debye ( , ; symbol: D) is a CGS unit (a non- SI metric unit) of electric dipole momentTwo equal and opposite charges separated by some distance constitute an electric dipole. This dipole possesses an electric dipole moment whose value is given as charge times length of separation. The dipole itself is a vector whose direction coincides with the position vector of the positive charge with respect to the negative charge: : p = ''q''r. named in honour of the physicist Peter J. W. Debye. It is defined as statcoulomb-centimetres.The statcoulomb is also known as the franklin or electrostatic unit of charge. : 1 statC = 1 Fr = 1 esu = 1 cm3/2⋅g1/2⋅s−1. Historically the debye was defined as the dipole moment resulting from two charges of opposite sign but an equal magnitude of 10−10 statcoulomb10−10 statcoulomb corresponds to approximately 0.2083 units of elementary charge. (generally called e.s.u. (electrostatic unit) in ol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Dipole Moment
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways: * An electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system is a pair of charges of equal magnitude but opposite sign separated by some typically small distance. (A permanent electric dipole is called an electret.) * A magnetic dipole is the closed circulation of an electric current system. A simple example is a single loop of wire with constant current through it. A bar magnet is an example of a magnet with a permanent magnetic dipole moment. Dipoles, whether electric or magnetic, can be characterized by their dipole moment, a vector quantity. For the simple electric dipole, the electric dipole moment points from the negative charge towards the positive charge, and has a magnitude equal to the strength of each charge times the separation between the charges. (To be precise: for the definit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ångström
The angstrom (; ) is a unit of length equal to m; that is, one ten- billionth of a metre, a hundred-millionth of a centimetre, 0.1 nanometre, or 100 picometres. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). It was originally spelled with Swedish letters, as Ångström and later as ångström (). The latter spelling is still listed in some dictionaries, but is now rare in English texts. Some popular US dictionaries list only the spelling ''angstrom''. The unit's symbol is Å, which is a letter of the Swedish alphabet, regardless of how the unit is spelled. However, "A" or "A.U." may be used in less formal contexts or typographically limited media. The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals, wavelengths of electromagnetic radiation, and dimensions of integrated circuit p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bond Length
In molecular geometry, bond length or bond distance is defined as the average distance between Atomic nucleus, nuclei of two chemical bond, bonded atoms in a molecule. It is a Transferability (chemistry), transferable property of a bond between atoms of fixed types, relatively independent of the rest of the molecule. Explanation Bond length is related to bond order: when more electrons participate in bond formation the bond is shorter. Bond length is also inversely related to bond strength and the bond dissociation energy: all other factors being equal, a stronger bond will be shorter. In a bond between two identical atoms, half the bond distance is equal to the covalent radius. Bond lengths are measured in the solid phase by means of X-ray diffraction, or approximated in the gas phase by microwave spectroscopy. A bond between a given pair of atoms may vary between different molecules. For example, the carbon to hydrogen bonds in methane are different from those in methyl chlori ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peter Debye
Peter Joseph William Debye ( ; born Petrus Josephus Wilhelmus Debije, ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born in Maastricht, Netherlands, Debye enrolled in the Aachen University of Technology in 1901. In 1905, he completed his first degree in electrical engineering. He published his first paper, a mathematically elegant solution of a problem involving eddy currents, in 1907. At Aachen, he studied under the theoretical physicist Arnold Sommerfeld, who later claimed that his most important discovery was Peter Debye. In 1906, Sommerfeld received an appointment at Munich, Bavaria, and took Debye with him as his assistant. Debye got his Ph.D. with a dissertation on radiation pressure in 1908. In 1910, he derived the Planck radiation formula using a method which Max Planck agreed was simpler than his own. In 1911, when Albert Einstein took an appointment as a profes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
