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Activator (phosphor)
In phosphors and scintillators, the activator is the element added as dopant to the crystal of the material to create desired type of nonhomogeneities. In luminescence, only a small fraction of atoms, called emission centers or luminescence centers, emit light. In inorganic phosphors, these inhomogeneities in the crystal structure are created usually by addition of a trace amount of dopants, impurities called activators. (In rare cases dislocations or other crystal defects can play the role of the impurity.) The wavelength emitted by the emission center is dependent on the atom itself, its electronic configuration, and on the surrounding crystal structure. The activators prolong the emission time (afterglow). In turn, other materials (such as nickel) can be used to quench the afterglow and shorten the decay part of the phosphor emission characteristics. The electronic configuration of the activator depends on its oxidation state and is crucial for the light emission. Oxidation of ...
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Phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam ( cathode rays) in a cathode-ray tube. When a phosphor is exposed to radiation, the orbital electrons in its molecules are excited to a higher energy level; when they return to their former level they emit the energy as light of a certain color. Phosphors can be classified into two categories: fluorescent substances which emit the energy immediately and stop glowing when the exciting radiation is turned off, and phosphorescent substances which emit the energy after a delay, so they keep glowing after the radiation is turned off, decaying in brightness over a period of milliseconds to days. Fluorescent materials are used in applications in wh ...
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Forbidden Gap
Forbidden may refer to: Science * Forbidden mechanism, a spectral line associated with absorption or emission of photons Films * ''Forbidden'' (1919 film), directed by Phillips Smalley and Lois Weber * ''Forbidden'' (1932 film), directed by Frank Capra * ''Forbidden'' (1949 film), directed by George King * ''Forbidden'' (1953 film), directed by Rudolph Maté * ''Forbidden'' (''Proibito''), a 1954 Italian film directed by Mario Monicelli * ''Forbidden'' (1984 film), directed by Anthony Page * ''The Forbidden'', a 2018 Uganda film Literature * ''Forbidden'' (Cooney novel), a 1994 novel by Caroline B. Cooney * ''Forbidden'' (Dekker and Lee novel), 2011 novel by Ted Dekker and Tosca Lee * ''Forbidden'', a 2010 novel by Tabitha Suzuma * "The Forbidden", short story by Clive Barker, from the Books of Blood Music * Forbidden (band), an American thrash metal band * ''Forbidden'' (Black Sabbath album) (1995), also the title track * ''Forbidden'' (Todrick Hall album) (2018), also ...
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Spinthariscope
A spinthariscope () is a device for observing individual Radioactive decay, nuclear disintegrations caused by the interaction of ionizing radiation with a phosphor (see radioluminescence) or scintillator. Invention The spinthariscope was invented by William Crookes in 1903. While observing the apparently uniform fluorescence on a zinc sulfide screen created by the radioactive emissions (mostly alpha radiation) of a sample of radium bromide, he spilled some of the sample, and, owing to its extreme rarity and cost, he was eager to find and recover it. Upon inspecting the zinc sulfide screen under a microscope, he noticed separate flashes of light created by individual alpha particle collisions with the screen. Crookes took his discovery a step further and invented a device specifically intended to view these scintillations. It consisted of a small screen coated with zinc sulfide affixed to the end of a tube, with a tiny amount of radium salt suspended a short distance from the scree ...
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Radium Dial
Radium is a chemical element; it has symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) upon exposure to air, forming a black surface layer of radium nitride (Ra3N2). All isotopes of radium are radioactive, the most stable isotope being radium-226 with a half-life of 1,600 years. When radium decays, it emits ionizing radiation as a by-product, which can excite fluorescent chemicals and cause radioluminescence. For this property, it was widely used in self-luminous paints following its discovery. Of the radioactive elements that occur in quantity, radium is considered particularly toxic, and it is carcinogenic due to the radioactivity of both it and its immediate decay product radon as well as its tendency to accumulate in the bones. Radium, in the form of radium chloride, was discovered by Mari ...
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Silver
Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found in the Earth's crust in the pure, free elemental form ("native metal, native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of the seven metals of antiquity, silver has had an enduring role in most human cultures. Other than in currency and as an in ...
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Cathode Ray Tube
A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a Film frame, frame of video on an Analog television, analog television set (TV), Digital imaging, digital raster graphics on a computer monitor, or other phenomena like radar targets. A CRT in a TV is commonly called a picture tube. CRTs have also been Williams tube, used as memory devices, in which case the screen is not intended to be visible to an observer. The term ''cathode ray'' was used to describe electron beams when they were first discovered, before it was understood that what was emitted from the cathode was a beam of electrons. In CRT TVs and computer monitors, the entire front area of the tube is scanned repeatedly and systematically in a fixed pattern called a raster scan, raster. In color devices, an image is produced by con ...
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Phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluorescence, a phosphorescent material does not immediately reemit the radiation it absorbs. Instead, a phosphorescent material absorbs some of the radiation energy and reemits it for a much longer time after the radiation source is removed. In a general sense, there is no distinct boundary between the emission times of fluorescence and phosphorescence (i.e.: if a substance glows under a black light it is generally considered fluorescent, and if it glows in the dark it is often simply called phosphorescent). In a modern, scientific sense, the phenomena can usually be classified by the three different mechanisms that produce the light, and the typical timescales during which those mechanisms emit light. Whereas fluorescent materials stop emitti ...
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Zinc Sulfide
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparency and translucency, transparent, and it is used as a window for visible light, visible optics and infrared optics. Structure ZnS exists in two main crystalline forms. This dualism is an example of polymorphism (materials science), polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite. The hexagonal form is known as the mineral wurtzite, although it also can be produced synthetically.. The transition from the sphalerite form to the wurtzite form occurs at around 1020 °C. Applications Luminescent mate ...
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Copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable, unalloyed metallic form. This means that copper is a native metal. This led to very early human use in several regions, from . Thousands of years later, it was the first metal to be smelted from sulfide ores, ; the first metal to be cast into a shape in a mold, ; and the first metal to be purposely alloyed with another metal, tin, to create bronze, ...
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Forbidden Mechanism
In spectroscopy, a forbidden mechanism (forbidden transition or forbidden line) is a spectral line associated with absorption or emission of photons by atomic nuclei, atoms, or molecules which undergo a transition that is not allowed by a particular selection rule but is allowed if the approximation associated with that rule is not made. For example, in a situation where, according to usual approximations (such as the electric dipole moment, electric dipole approximation for the interaction with light), the process cannot happen, but at a higher level of approximation (e.g. magnetic dipole moment, magnetic dipole, or electric quadrupole) the process is allowed but at a low rate. An example is phosphorescence, phosphorescent materials, which absorb light and form an excited state whose decay involves a Spin (physics), spin flip, and is therefore forbidden by electric dipole transitions. The result is emission of light slowly over minutes or hours. Should an atomic nucleus, atom or ...
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Metastable State
In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is only slightly pushed, it will settle back into its hollow, but a stronger push may start the ball rolling down the slope. Bowling pins show similar metastability by either merely wobbling for a moment or tipping over completely. A common example of metastability in science is isomerisation. Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by (possibly large) barriers in the potential energy. During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values. In isolation: *the state of least energy is the only one the system will inhabit for an indefinite length of time, until more external energy is added to the system (unique "absolu ...
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Photomultiplier
A photomultiplier is a device that converts incident photons into an electrical signal. Kinds of photomultiplier include: * Photomultiplier tube, a vacuum tube converting incident photons into an electric signal. Photomultiplier tubes (PMTs for short) are members of the class of vacuum tubes, and more specifically vacuum phototubes, which are extremely sensitive detectors of light in the ultraviolet, visible, and near-infrared ranges of the electromagnetic spectrum. ** Magnetic photomultiplier, developed by the Soviets in the 1930s. ** Electrostatic photomultiplier, a kind of photomultiplier tube demonstrated by Jan Rajchman of RCA Laboratories in Princeton, NJ in the late 1930s which became the standard for all future commercial photomultipliers. The first mass-produced photomultiplier, the Type 931, was of this design and is still commercially produced today. * Silicon photomultiplier, a solid-state device converting incident photons into an electric signal. Silicon photomul ...
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