Abieta-7,13-dien-18-al Dehydrogenase
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Abieta-7,13-dien-18-al Dehydrogenase
Abieta-7,13-dien-18-al dehydrogenase (, ''abietadienal dehydrogenase (ambiguous)'') is an enzyme with systematic name ''abieta-7,13-dien-18-al:NAD+ oxidoreductase''. This enzyme catalyses the following chemical reaction : abieta-7,13-dien-18-al + H2O + NAD+ \rightleftharpoons abieta-7,13-dien-18-oate + NADH + H+ This enzyme catalyses the last step of the pathway of abietic acid biosynthesis in ''Abies grandis ''Abies grandis'' (grand fir, giant fir, lowland white fir, great silver fir, western white fir, Vancouver fir, or Oregon fir) is a fir native to northwestern North America, occurring at altitudes of sea level to . It is a major constituent of t ...''. References External links * {{Portal bar, Biology, border=no EC 1.2.1 ...
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Enzyme
An enzyme () is a protein that acts as a biological catalyst by accelerating chemical reactions. The molecules upon which enzymes may act are called substrate (chemistry), substrates, and the enzyme converts the substrates into different molecules known as product (chemistry), products. Almost all metabolism, metabolic processes in the cell (biology), cell need enzyme catalysis in order to occur at rates fast enough to sustain life. Metabolic pathways depend upon enzymes to catalyze individual steps. The study of enzymes is called ''enzymology'' and the field of pseudoenzyme, pseudoenzyme analysis recognizes that during evolution, some enzymes have lost the ability to carry out biological catalysis, which is often reflected in their amino acid sequences and unusual 'pseudocatalytic' properties. Enzymes are known to catalyze more than 5,000 biochemical reaction types. Other biocatalysts include Ribozyme, catalytic RNA molecules, also called ribozymes. They are sometimes descr ...
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List Of Enzymes
Enzymes are listed here by their classification in the International Union of Biochemistry and Molecular Biology's Enzyme Commission (EC) numbering system: :Oxidoreductases (EC 1) ( Oxidoreductase) * Dehydrogenase * Luciferase * DMSO reductase :EC 1.1 (act on the CH-OH group of donors) * :EC 1.1.1 (with NAD+ or NADP+ as acceptor) ** Alcohol dehydrogenase (NAD) ** Alcohol dehydrogenase (NADP) ** Homoserine dehydrogenase ** Aminopropanol oxidoreductase ** Diacetyl reductase ** Glycerol dehydrogenase ** Propanediol-phosphate dehydrogenase ** glycerol-3-phoshitiendopene dehydrogenase (NAD+) ** D-xylulose reductase ** L-xylulose reductase ** Lactate dehydrogenase ** Malate dehydrogenase ** Isocitrate dehydrogenase ** HMG-CoA reductase * :EC 1.1.2 (with a cytochrome as acceptor) * :EC 1.1.3 (with oxygen as acceptor) ** Glucose oxidase ** L-gulonolactone oxidase ** Thiamine oxidase ** Xanthine oxidase * EC 1.1.4 (with a disulfide as accep ...
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Catalysis
Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst. The rate increase occurs because the catalyst allows the reaction to occur by an alternative mechanism which may be much faster than the noncatalyzed mechanism. However the noncatalyzed mechanism does remain possible, so that the total rate (catalyzed plus noncatalyzed) can only increase in the presence of the catalyst and never decrease. Catalysis may be classified as either homogeneous, whose components are dispersed in the same phase (usual ...
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Chemical Reaction
A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, energy change as new products are generated. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the Atomic nucleus, nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive Chemical element, elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reagent, reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more Product (c ...
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Abietic Acid
Abietic acid (also known as ''abietinic acid'' or ''sylvic acid'') is a diterpenoid found in coniferous trees. It is supposed to exist to defend the host plant from insect attack or various wounds. Chemically, it is a complicated molecule featuring two alkene groups and a carboxylic acid within a chiral tricyclic framework. As the major component of rosin, it is commercially important. Historically speaking, it was a major component of naval stores. It is the most common of the resin acids. Another common resin acid is pimaric acid, which converts to abietic acid upon heating. Characteristics and occurrence Abietic acid is found in rosin obtained from pine trees. Pure abietic acid is a colorless solid, but commercial samples are usually a glassy or partly crystalline yellowish solid that melts at temperatures as low as . Abietic acid is soluble in alcohols, acetone, and ethers. Its esters and salts are called an abietates, e.g. ethyl abietate and sodium abietate.Lars-Hugo Norlin ...
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Abies Grandis
''Abies grandis'' (grand fir, giant fir, lowland white fir, great silver fir, western white fir, Vancouver fir, or Oregon fir) is a fir native to northwestern North America, occurring at altitudes of sea level to . It is a major constituent of the Grand Fir/Douglas Fir Ecoregion of the Cascade Range. The tree typically grows to in height, and may be the tallest ''Abies'' species in the world. There are two varieties, the taller coast grand fir, found west of the Cascade Mountains, and the shorter interior grand fir, found east of the Cascades. It was first described in 1831 by David Douglas. It is closely related to white fir. The bark was historically believed to have medicinal properties, and it is popular in the United States as a Christmas tree. Its lumber is a softwood, and it is harvested as a hem fir. It is used in paper-making, as well as construction for framing and flooring, where it is desired for its resistance to splitting and splintering. Description ''Abi ...
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