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Zirconyl Chloride
Zirconyl chloride is the inorganic compound with the formula of r4(OH)8(H2O)16l8(H2O)12, more commonly written ZrOCl2·8H2O, and referred to as zirconyl chloride octahydrate. It is a white solid and is the most common water-soluble derivative of zirconium. A compound with the formula ZrOCl2 has not been characterized. Production and structure The salt is produced by hydrolysis of zirconium tetrachloride or treating zirconium oxide with hydrochloric acid.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. It adopts a tetrameric structure, consisting of the cation r4(OH)8sup>8+. features four pairs of hydroxide bridging ligands linking four Zr4+ centers. The chloride anions are not ligands, consistent with the high oxophilicity of Zr(IV). The salt crystallizes as tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconium
Zirconium is a chemical element; it has Symbol (chemistry), symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyish-white color that closely resembles hafnium and, to a lesser extent, titanium. It is solid at room temperature, Ductility, ductile, malleable and corrosion-resistant. The name ''zirconium'' is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian Language, Persian ''Jargoon, zargun'' (zircon; ''zar-gun'', "gold-like" or "as gold"). Besides zircon, zirconium occurs in over 140 other minerals, including baddeleyite and eudialyte; most zirconium is produced as a byproduct of minerals mined for titanium and tin. Zirconium forms a variety of inorganic chemistry, inorganic compounds, such as zirconium dioxide, and organometallic compounds, such as zirconocene dichloride. Five isotope ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconium Tetrachloride
Zirconium is a chemical element; it has symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyish-white color that closely resembles hafnium and, to a lesser extent, titanium. It is solid at room temperature, ductile, malleable and corrosion-resistant. The name ''zirconium'' is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'', "gold-like" or "as gold"). Besides zircon, zirconium occurs in over 140 other minerals, including baddeleyite and eudialyte; most zirconium is produced as a byproduct of minerals mined for titanium and tin. Zirconium forms a variety of inorganic compounds, such as zirconium dioxide, and organometallic compounds, such as zirconocene dichloride. Five isotopes occur naturally, four of which are stable. The metal and its alloys are ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconium Oxide
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zirconium silicate or zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. Etymology Because it was produced from halite, rock salt according to the methods of Johann Rudolph Glauber, hydrochloric acid was historically called by European alchemists ''spirits of salt'' or ''acidum salis'' (salt acid). Both names are still used, especially in other languages, such as , , , , , , , , , , (''ensan''), zh, 盐酸 (''yánsuān''), and (''yeomsan''). Gaseous HCl was called ''marine acid air''. The name ''muriatic acid'' has the same origin (''muriatic'' means "pertaining to brine or salt", hence ''muriate'' means hydrochloride), and this ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bridging Ligand
In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions. The ligand may be atomic or polyatomic. Virtually all complex organic compounds can serve as bridging ligands, so the term is usually restricted to small ligands such as pseudohalides or to ligands that are specifically designed to link two metals. In naming a complex wherein a single atom bridges two metals, the bridging ligand is preceded by the Greek letter mu, μ, with a subscript number denoting the number of metals bound to the bridging ligand. μ2 is often denoted simply as μ. When describing coordination complexes care should be taken not to confuse μ with η ('eta'), which relates to hapticity. Ligands that are not bridging are called terminal ligands. List of bridging ligands Virtually all ligands are known to bridge, with the exception of amines and ammonia. Common bridging ligands include most of the common anions. Many simple organic ligands form s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anion
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ ( potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− ( chloride ion) and OH− ( hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed ''monatomic ions'', ''atomic ions'' or ''simple ions'', while ions consisting of two or more atoms are termed polyatomic ions or ''molecular ions''. If only a + or − is present, it indi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ligand
In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs, often through Lewis acids and bases, Lewis bases. The nature of metal–ligand bonding can range from covalent bond, covalent to ionic bond, ionic. Furthermore, the metal–ligand bond order can range from one to three. Ligands are viewed as Lewis bases, although rare cases are known to involve Lewis acids and bases, Lewis acidic "ligands". Metals and metalloids are bound to ligands in almost all circumstances, although gaseous "naked" metal ions can be generated in a high vacuum. Ligands in a complex dictate the reactivity (chemistry), reactivity of the central atom, including ligand substitution rates, the reactivity of the ligands themselves, and redox. Ligand selection requires critical consideration in many practical are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxophilicity
Oxophilicity is the tendency of certain chemical compounds to form oxides by hydrolysis or abstraction of an oxygen atom from another molecule, often from organic compounds. The term is often used to describe metal centers, commonly the early transition metals such as titanium, niobium, and tungsten. Oxophilicity is often stated to be related to the hardness of the element, within the HSAB theory ( hard and soft (Lewis) acids and bases), but it has been shown that oxophilicity depends more on the electronegativity and effective nuclear charge of the element than on its hardness. This explains why the early transition metals, whose electronegativities and effective nuclear charges are low, are very oxophilic. Many main group compounds are also oxophilic, such as derivatives of aluminium, silicon, and phosphorus(III). The handling of oxophilic compounds often requires air-free techniques. Examples Complexes of oxophilic metals typically are prone to hydrolysis. For example, the high ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetragonal
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the Cube (geometry), cube becomes a rectangular Prism (geometry), prism with a square base (''a'' by ''a'') and height (''c'', which is different from ''a''). Bravais lattices There are two tetragonal Bravais lattices: the primitive tetragonal and the body-centered tetragonal. The body-centered tetragonal lattice is equivalent to the primitive tetragonal lattice with a smaller unit cell, while the face-centered tetragonal lattice is equivalent to the body-centered tetragonal lattice with a smaller unit cell. Crystal classes The point groups that fall under this crystal system are listed below, followed by their representations in international notation, Schoenflies notation, orbifold notation, Coxeter notation and mineral examples.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconyl Acetate
Zirconium(IV) acetate or zirconyl acetate, or just zirconium acetate, usually refers to the chemical formula (hexazirconium(IV) tetroxide tetrahydroxide dodecaacetate). It is a white solid formed by the reaction of zirconyl chloride with acetic acid. Claims of (zirconium(IV) acetate) have been superseded by experiments using X-ray crystallography. The species is a common precursor to metal-organic frameworks (MOFs). The structure of the 8.5 hydrate () has been determined by EXAFS. The core can be described as a octahedron is face-capped with oxide and hydroxide ligands In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's .... References {{Acetates Zirconium(IV) compounds Acetates ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
