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X-ray Notation
X-ray notation is a method of labeling atomic orbitals that grew out of X-ray science. Also known as IUPAC notation, it was adopted by the International Union of Pure and Applied Chemistry in 1991 as a simplification of the older Siegbahn notation. In X-ray notation, every principal quantum number is given a letter associated with it. In many areas of physics and chemistry, atomic orbitals are described with spectroscopic notation (1s, 2s, 2p, 3s, 3p, etc.), but the more traditional X-ray notation is still used with most X-ray spectroscopy techniques including AES and XPS. Conversion Uses *X-ray sources are classified by the type of material and orbital used to generate them. For example, CuKα X-rays are emitted from the K orbital of copper. *X-ray absorption is reported as which orbital absorbed the x-ray photon. In EXAFS and XMCD the L-edge or the L absorption edge is the point where the L orbital begins to absorb x-rays. * Auger peaks are identified with three orbital de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Orbitals
In quantum mechanics, an atomic orbital () is a function describing the location and wave-like behavior of an electron in an atom. This function describes an electron's charge distribution around the atom's nucleus, and can be used to calculate the probability of finding an electron in a specific region around the nucleus. Each orbital in an atom is characterized by a set of values of three quantum numbers , , and , which respectively correspond to electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis ( magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally complex-valued. Real-valued orbitals can be formed as linear combinations of and orbitals, and are often labeled using associated harmonic polynomials (e.g., ''xy'', ) which describe their angular structure. An orbital can be occupied by a maximum of two electrons, each with its own projection of spin m_s. The simp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray
An X-ray (also known in many languages as Röntgen radiation) is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ranging from 10 Nanometre, nanometers to 10 Picometre, picometers, corresponding to frequency, frequencies in the range of 30 Hertz, petahertz to 30 Hertz, exahertz ( to ) and photon energies in the range of 100 electronvolt, eV to 100 keV, respectively. X-rays were discovered in 1895 in science, 1895 by the German scientist Wilhelm Röntgen, Wilhelm Conrad Röntgen, who named it ''X-radiation'' to signify an unknown type of radiation.Novelline, Robert (1997). ''Squire's Fundamentals of Radiology''. Harvard University Press. 5th edition. . X-rays can penetrate many solid substances such as construction materials and living tissue, so X-ray radiography is widely used in medical diagnostics (e.g., checking for Bo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
International Union Of Pure And Applied Chemistry
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. IUPAC's executive director heads this administrative office, currently Greta Heydenrych. IUPAC was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry. Its members, the National Adhering Organizations, can be national chemistry societies, national academies of sciences, or other bodies representing chemists. There are fifty-four National Adhering Organizations and three Associate National Adhering Organizations. IUPAC's Inter-divisional Committee ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Siegbahn Notation
The Siegbahn notation is used in X-ray spectroscopy to name the spectral lines that are characteristic to elements. It was introduced by Manne Siegbahn. The characteristic lines in X-ray emission spectra correspond to atomic electronic transitions where an electron jumps down to a vacancy in one of the inner shells of an atom. Such a hole in an inner shell may have been produced by bombardment with electrons in an X-ray tube, by other particles as in PIXE, by other X-rays in X-ray fluorescence or by radioactive decay of the atom's nucleus. Although still widely used in spectroscopy, this notation is unsystematic and often confusing. For these reasons, International Union of Pure and Applied Chemistry (IUPAC) recommends another nomenclature. History The use of the letters K and L to denote X-rays originates in a 1911 paper by Charles Glover Barkla, titled ''The Spectra of the Fluorescent Röntgen Radiations'' ("Röntgen radiation" is an archaic name for "X-rays"). By 1913, H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectroscopic Notation
Spectroscopic notation provides a way to specify atomic ionization states, atomic orbitals, and molecular orbitals. Ionization states Spectroscopists customarily refer to the spectrum arising from a given ionization state of a given element by the element's symbol followed by a Roman numeral. The numeral I is used for spectral lines associated with the neutral element, II for those from the first ionization state, III for those from the second ionization state, and so on. For example, "He I" denotes lines of neutral helium, and "C IV" denotes lines arising from the third ionization state, C3+, of carbon. This notation is used for example to retrieve data from thNIST Atomic Spectrum Database Atomic and molecular orbitals Before atomic orbitals were understood, spectroscopists discovered various distinctive series of spectral lines in atomic spectra, which they identified by letters. These letters were later associated with the azimuthal quantum number, ''ℓ''. The let ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Auger Electron Spectroscopy
A Hanford scientist uses an Auger electron spectrometer to determine the elemental composition of surfaces. Auger electron spectroscopy (AES; pronounced in French) is a common analytical technique used specifically in the study of surfaces and, more generally, in the area of materials science. It is a form of electron spectroscopy that relies on the Auger effect, based on the analysis of energetic electrons emitted from an excited atom after a series of internal relaxation events. The Auger effect was discovered independently by both Lise Meitner and Pierre Auger in the 1920s. Though the discovery was made by Meitner and initially reported in the journal ''Zeitschrift für Physik'' in 1922, Auger is credited with the discovery in most of the scientific community. Until the early 1950s Auger transitions were considered nuisance effects by spectroscopists, not containing much relevant material information, but studied so as to explain anomalies in X-ray spectroscopy data. Since 195 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Photoelectron Spectroscopy
X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the very topmost 50-60 atoms, 5-10 nm of any surface. It belongs to the family of photoemission spectroscopies in which electron population spectra are obtained by irradiating a material with a beam of X-rays. XPS is based on the photoelectric effect that can identify the elements that exist within a material (elemental composition) or are covering its surface, as well as their chemical state, and the overall electronic structure and density of the electronic states in the material. XPS is a powerful measurement technique because it not only shows what elements are present, but also what other elements they are bonded to. The technique can be used in line profiling of the elemental composition across the surface, or in depth profiling when paired with ion-beam etching. It is often applied to study chemical processes in the materials in their as-received state or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Numbers
In Quantum mechanics, quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system. To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantum numbers includes the Principal quantum number, principal, Azimuthal quantum number, azimuthal, Magnetic quantum number, magnetic, and Spin quantum number, spin quantum numbers. To describe other systems, different quantum numbers are required. For subatomic particles, one needs to introduce new quantum numbers, such as the flavour (particle physics), flavour of quarks, which have no classical correspondence. Quantum numbers are closely related to eigenvalues of observables. When the corresponding observable commutes with the Hamiltonian (quantum mechanics), Hamiltonian of the system, the quantum number is said to be "Good quantum number, good", and acts as a constant of motion in the quantum dynamics. History Elect ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Term Symbol
In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom. So while the word ''symbol'' suggests otherwise, it represents an actual ''value'' of a physical quantity. For a given electron configuration of an atom, its state depends also on its total angular momentum, including spin and orbital components, which are specified by the term symbol. The usual atomic term symbols assume angular momentum coupling#LS coupling, LS coupling (also known as Russell–Saunders coupling) in which the all-electron total quantum numbers for orbital (''L''), spin (''S'') and total (''J'') angular momenta are good quantum numbers. In the terminology of atomic spectroscopy, ''L'' and ''S'' together specify a term; ''L'', ''S'', and ''J'' specify a level; and ''L'', ''S'', ''J'' and the magnetic quantum number ''M''''J'' specify a state. The conventional term symbol has the form 2''S''+1''L'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absorption (electromagnetic Radiation)
In physics, absorption of electromagnetic radiation is how matter (typically electrons bound in atoms) takes up a photon's energy—and so transforms electromagnetic energy into internal energy of the absorber (for example, thermal energy). A notable effect of the absorption of electromagnetic radiation is attenuation of the radiation; attenuation is the gradual reduction of the intensity of light waves as they propagate through a medium. Although the absorption of waves does not usually depend on their intensity (linear absorption), in certain conditions (optics) the medium's transparency changes by a factor that varies as a function of wave intensity, and saturable absorption (or nonlinear absorption) occurs. Quantifying absorption Many approaches can potentially quantify radiation absorption, with key examples following. * The absorption coefficient along with some closely related derived quantities * The attenuation coefficient (NB used infrequently with meaning ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Magnetic Circular Dichroism
X-ray magnetic circular dichroism (XMCD) is a difference spectrum of two X-ray absorption spectra (XAS) taken in a magnetic field, one taken with left circularly polarized light, and one with right circularly polarized light. By closely analyzing the difference in the XMCD spectrum, information can be obtained on the magnetic properties of the atom, such as its spin and orbital magnetic moment. Using XMCD magnetic moments below 10−5 μB can be observed. In the case of transition metals such as iron, cobalt, and nickel, the absorption spectra for XMCD are usually measured at the L-edge. This corresponds to the process in the iron case: with iron, a 2p electron is excited to a 3d state by an X-ray of about 700 eV. Because the 3d electron states are the origin of the magnetic properties of the elements, the spectra contain information on the magnetic properties. In rare-earth elements usually, the M4,5-edges are measured, corresponding to electron excitations from a 3d s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
