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Vitriol
Vitriol is the general chemical name encompassing a class of chemical compounds comprising sulfates of certain metalsoriginally, iron or copper. Those mineral substances were distinguished by their color, such as green vitriol for hydrated iron(II) sulfate and blue vitriol for hydrated copper(II) sulfate.Vitriol
entry in the online Encyclopaedia Britannica. Accessed on 2020-08-28.
These materials were found originally as crystals formed by evaporation of groundwater that percolated through minerals and collected in pools on the floors of old mines. The word ''vitriol'' comes from the Latin word ''vitriolus'', meaning "small glass", as those ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Iron(II) Sulfate
Iron(II) sulfate or ferrous sulfate (British English: sulphate instead of sulfate) denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7), but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol ( vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate ( hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex e(H2O)6sup>2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas. It is on the World Health Organization's List o ...
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Copper(II) Sulfate
Copper(II) sulfate is an inorganic compound with the chemical formula . It forms hydrates , where ''n'' can range from 1 to 7. The pentahydrate (''n'' = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, while its anhydrous form is white. Older names for the pentahydrate include blue vitriol, bluestone, vitriol of copper,Antoine-François de Fourcroy, tr. by Robert Heron (1796) "Elements of Chemistry, and Natural History: To which is Prefixed the Philosophy of Chemistry". J. Murray and others, Edinburgh. Page 348. and Roman vitriol.Oxford University Press,Roman vitriol, Oxford Living Dictionaries. Accessed on 2016-11-13 It exothermically dissolves in water to give the aquo complex , which has octahedral molecular geometry. The structure of the solid pentahydrate reveals a polymeric structure wherein copper is again octahedral but bound to four water ligands. The centers are interconnected by sulfate anions to form chains. Preparation and ...
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Diethyl Ether
Diethyl ether, or simply ether, is an organic compound with the chemical formula , sometimes abbreviated as . It is a colourless, highly Volatility (chemistry), volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It belongs to the ether class of organic compounds. It is a common solvent and was formerly used as a general anesthetic. Production Most diethyl ether is produced as a byproduct of the vapor-phase Hydration reaction, hydration of ethylene to make ethanol. This process uses solid-supported phosphoric acid Catalysis, catalysts and can be adjusted to make more ether if the need arises: Vapor-phase Dehydration reaction, dehydration of ethanol over some Aluminium oxide, alumina catalysts can give diethyl ether yields of up to 95%. : Diethyl ether can be prepared both in laboratories and on an industrial scale by the acid ether synthesis. Uses The dominant use of diethyl ether is as a solvent. One particular application is in the production of cell ...
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Sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedral arrangement. The symmetry of the isolated anion is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid. The tetrahedral ...
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Zinc Sulfate
Zinc sulfate is an inorganic compound with the formula ZnSO4. It forms hydrates ZnSO4·''n''H2O, where ''n'' can range from 0 to 7. All are colorless solids. The most common form includes water of crystallization as the heptahydrate, with the chemical formula, formula . As early as the 16th century it was prepared on a large scale, and was historically known as "white vitriol" (the name was used, for example, in 1620s by the collective writing under the pseudonym of Basil Valentine). Zinc sulfate and its hydrates are colourless solids. Uses Manufacturing The main application of the heptahydrate is as a coagulant in the production of rayon. It is also a precursor to the pigment lithopone. It is also used as an electrolyte for zinc electroplating, as a mordant in dyeing, and as a preservative for skins and leather. Nutrition Zinc sulfate is used to supply zinc in animal feeds, fertilizers, toothpaste, and agricultural sprays. Zinc sulfate, like many zinc compounds, can be used to ...
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Dioscorides
Pedanius Dioscorides (, ; 40–90 AD), "the father of pharmacognosy", was a Greek physician, pharmacologist, botanist, and author of (in the original , , both meaning "On Materia medica, Medical Material") , a 5-volume Greek encyclopedic pharmacopeia on herbal medicine and related medicinal substances, that was widely read for more than 1,500 years. For almost two millennia Dioscorides was regarded as the most prominent writer on plants and plant drugs. Life A native of Anazarbus, Cilicia, Asia Minor, Dioscorides likely studied medicine nearby at the school in Tarsus, Mersin, Tarsus, which had a pharmacological emphasis, and he dedicated his medical books to Laecanius Arius, a medical practitioner there. Though he writes he lived a "soldier's life" or "soldier-like life", his pharmacopeia refers almost solely to plants found in the Greek-speaking eastern Mediterranean, making it likely that he served in campaigns, or travelled in a civilian capacity, less widely as supposed. T ...
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Pliny The Elder
Gaius Plinius Secundus (AD 23/24 79), known in English as Pliny the Elder ( ), was a Roman Empire, Roman author, Natural history, naturalist, and naval and army commander of the early Roman Empire, and a friend of the Roman emperor, emperor Vespasian. He wrote the encyclopedic (''Natural History''), a comprehensive thirty-seven-volume work covering a vast array of topics on human knowledge and the natural world, which became an editorial model for encyclopedias. He spent most of his spare time studying, writing, and investigating natural and geographic phenomena in the field. Among Pliny's greatest works was the twenty-volume ''Bella Germaniae'' ("The History of the German Wars"), which is Lost literary work, no longer extant. ''Bella Germaniae'', which began where Aufidius Bassus' ''Libri Belli Germanici'' ("The War with the Germans") left off, was used as a source by other prominent Roman historians, including Plutarch, Tacitus, and Suetonius. Tacitus may have used ''Bella Ger ...
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Sumer
Sumer () is the earliest known civilization, located in the historical region of southern Mesopotamia (now south-central Iraq), emerging during the Chalcolithic and Early Bronze Age, early Bronze Ages between the sixth and fifth millennium BC. Like nearby Elam, it is one of the Cradle of civilization, cradles of civilization, along with ancient Egypt, Egypt, the Indus Valley Civilisation, Indus Valley, the Erligang culture of the Yellow River valley, Caral-Supe civilization, Caral-Supe, and Mesoamerica. Living along the valleys of the Tigris and Euphrates rivers, Sumerian farmers grew an abundance of grain and other crops, a surplus of which enabled them to form urban settlements. The world's earliest known texts come from the Sumerian cities of Uruk and Jemdet Nasr, and date to between , following a period of proto-writing . Name The term "Sumer" () comes from the Akkadian Empire, Akkadian name for the "Sumerians", the ancient non-Semitic languages, Semitic-speaking inhabitan ...
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Classical Antiquity
Classical antiquity, also known as the classical era, classical period, classical age, or simply antiquity, is the period of cultural History of Europe, European history between the 8th century BC and the 5th century AD comprising the interwoven civilizations of ancient Greece and ancient Rome, Rome known together as the Greco-Roman world, centered on the Mediterranean Basin. It is the period during which ancient Greece and Rome flourished and had major influence throughout much of Europe, North Africa, and West Asia. Classical antiquity was succeeded by the period now known as late antiquity. Conventionally, it is often considered to begin with the earliest recorded Homeric Greek, Epic Greek poetry of Homer (8th–7th centuries BC) and end with the fall of the Western Roman Empire in 476 AD. Such a wide span of history and territory covers many disparate cultures and periods. ''Classical antiquity'' may also refer to an idealized vision among later people of what was, in Ed ...
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Aluminium Sulfate
Aluminium sulfate is a salt with the chemical formula, formula . It is soluble in water and is mainly used as a Coagulation (water treatment), coagulating agent (promoting particle collision by neutralizing charge) in the purification of drinking water and wastewater treatment plants, and also in paper manufacturing. The anhydrous form occurs naturally as a rare mineral millosevichite, found for example in volcanic environments and on burning coal-mining waste dumps. Aluminium sulfate is rarely, if ever, encountered as the anhydrous salt. It forms a number of different hydrates, of which the hexadecahydrate and octadecahydrate are the most common. The heptadecahydrate, whose formula can be written as , occurs naturally as the mineral alunogen. Aluminium sulfate is sometimes called alum or papermaker's alum in certain industries. However, the name "alum" is more commonly and properly used for any double sulfate salt with the generic formula , where ''X'' is a valence (chemistry) ...
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