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Vinyl Cation
The vinyl cation is a carbocation with the positive charge on an alkene carbon. Its empirical formula of the parent ion is . Vinyl cation are invoked as reactive intermediates in solvolysis of vinyl halides, as well as electrophilic addition to alkynes and allenes. History Vinyl cations have long been poorly-understood and were initially thought to be too high energy to form as reactive intermediates. Vinyl cations were first proposed in 1944 as a reactive intermediate for the acid-catalyzed hydrolysis of alkoxyacetylenes to give alkyl acetate. In the first step of their facile hydration reaction, which was the rate limiting step, a vinyl cation reactive intermediate was proposed; the positive charge was believed to formally lie on a dicoordinate carbon. This is the first time such a transition state can be found in the literature. In 1959, Grob and Cseh detected vinyl cations during solvolysis reactions of alpha-vinyl halides. Indeed, for this contribution, Grob has been called ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbocation
Carbocation is a general term for ions with a positively charged carbon atom. In the present-day definition given by the IUPAC, a carbocation is any even-electron cation with significant partial positive charge on a carbon atom. They are further classified in two main categories according to the coordination number of the charged carbon: three in the carbenium ions and five in the carbonium ions. Among the simplest carbocations are the methenium (a carbenium ion), methanium (a carbonium ion), acylium ions , and Vinyl cation, vinyl cations. Until the early 1970s, carbocations were called ''carbonium ions''. This nomenclature was proposed by George Andrew Olah, G. A. Olah. Carbonium ions, as originally defined by Olah, are characterized by a Three-center two-electron bond, three-center two-electron delocalized bonding scheme and are essentially synonymous with so-called 'non-classical carbocations', which are carbocations that contain bridging C–C or C–H σ-bonds. However ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photochemical
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm). In nature, photochemistry is of immense importance as it is the basis of photosynthesis, vision, and the formation of vitamin D with sunlight. It is also responsible for the appearance of DNA mutations leading to skin cancers. Photochemical reactions proceed differently than temperature-driven reactions. Photochemical paths access high-energy intermediates that cannot be generated thermally, thereby overcoming large activation barriers in a short period of time, and allowing reactions otherwise inaccessible by thermal processes. Photochemistry can also be destructive, as illustrated by the photodegradation of plastics. Concept Grotthuss–Draper law and Stark–Einstein law Photoex ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronic Effect
An electric effect influences the structure, reactivity, or properties of a molecule but is neither a traditional bond nor a steric effect. In organic chemistry, the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry (stereochemistry) of a molecule. The term polar effect is sometimes used to refer to electronic effects, but also may have the more narrow definition of effects resulting from non-conjugated substituents. Types Redistributive effects Induction is the redistribution of electron density through a traditional sigma bonded structure according to the electronegativity of the atoms involved. The inductive effect drops across every sigma bond involved limiting its effect to only a few bonds. Conjugation is a redistribution of electron density similar to induction but transmitted through interconnected pi-bonds. Conjugation is not only affected by electronegativity of the connected atoms but also aff ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
SVC2
SVC or .svc may refer to: Biology * Spring viraemia of carp, a disease of fish * Superior vena cava, a heart vein Colleges * Saginaw Valley College, now Saginaw Valley State University, Michigan, US * School of Visual Concepts, Seattle, Washington, US * Southern Vermont College, near Bennington, US * Saint Vincent's College, in Dipolog City, Philippines Finance * Salvadoran colón, ISO 4217 currency code * Stored-value card, a type of payment card Organizations * Shanghai Volunteer Corps (1853−1942), of the Shanghai International Settlement * Skills and Volunteering Cymru, a charity in Cardiff, Wales * Sun Valley Center for the Arts and Humanities, Sun Valley, Idaho, US Technology * Saab Variable Compression engine * Static VAR compensator, electrical power factor compensator Computing * IBM SAN Volume Controller * Supervisor Call instruction, a mainframe computer instruction * Support-vector clustering, similar to support vector machine * .svc, Microsoft I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stabilized VC1
Stabilizer, stabiliser, stabilisation or stabilization may refer to: Chemistry and food processing * Stabilizer (chemistry), a substance added to prevent unwanted change in state of another substance ** Polymer stabilizers are stabilizers used specifically in plastic or other polymers * Stabilizer (food), a type of food additive * Wood stabilization, a wood preservation process to prevent distortion caused by moisture * Clarification and stabilization of wine Mathematics * Stabilization (category theory) * Stabilizer subgroup Technology * Buoyancy compensator (diving) adjusts buoyancy. * Stabilizer (aircraft), surfaces to help keep aircraft under control. Includes: ** Vertical stabilizer of airplanes ** Tailplane or horizontal stabilizer * Stabilizer (ship), fins on ships to counteract roll * Stabilizer, another name for bicycle training wheels * Stabilizers, the extendable legs mounted on a land vehicle which are folded out when stabilization is required; see Outrigger * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Magnetic Resonance Spectroscopy
Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a Spectroscopy, spectroscopic technique based on re-orientation of Atomic nucleus, atomic nuclei with non-zero nuclear spins in an external magnetic field. This re-orientation occurs with absorption of electromagnetic radiation in the radio frequency region from roughly 4 to 900 MHz, which depends on the Isotope, isotopic nature of the nucleus and increases proportionally to the strength of the external magnetic field. Notably, the resonance frequency of each NMR-active nucleus depends on its chemical environment. As a result, NMR spectra provide information about individual functional groups present in the sample, as well as about connections between nearby nuclei in the same molecule. As the NMR spectra are unique or highly characteristic to individual compounds and functional groups, NMR spectroscopy is one of the most important methods to identify ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
