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Thallium(III) Oxide
Thallium(III) oxide, also known as thallic oxide, is a chemical compound of thallium and oxygen. It occurs in nature as the rare mineral avicennite. Its structure is related to that of Mn2O3 which has a bixbyite like structure. Tl2O3 is metallic with high conductivity and is a degenerate n-type semiconductor which may have potential use in solar cells. A method of producing Tl2O3 by MOCVD is known. Any practical use of thallium(III) oxide will always have to take account of thallium's poisonous nature. Contact with moisture and acids may form poisonous thallium compounds. Production It is produced by the reaction of thallium with oxygen or hydrogen peroxide in an alkaline thallium(I) solution. Alternatively, it can be created by the oxidation of thallium(I) nitrate by chlorine in an aqueous potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical ...
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Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc) Note: the term fcc is often used in synonym for the ''cubic close-packed'' or ccp structure occurring in metals. However, fcc stands for a face-centered cubic Bravais lattice, which is not necessarily close-packed when a motif is set onto the lattice points. E.g. the diamond and the zincblende lattices are fcc but not close-packed. Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais latices ...
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Metalorganic Vapour Phase Epitaxy
Metalorganic vapour-phase epitaxy (MOVPE), also known as organometallic vapour-phase epitaxy (OMVPE) or metalorganic chemical vapour deposition (MOCVD), is a chemical vapour deposition method used to produce single- or polycrystalline thin films. It is a process for growing crystalline layers to create complex semiconductor multilayer structures. In contrast to molecular-beam epitaxy (MBE), the growth of crystals is by chemical reaction and not physical deposition. This takes place not in vacuum, but from the gas phase at moderate pressures (10 to 760 Torr). As such, this technique is preferred for the formation of devices incorporating thermodynamically metastable alloys, and it has become a major process in the manufacture of optoelectronics, such as light-emitting diodes, its most widespread application. It was first demonstrated in 1967 at North American Aviation (later Rockwell International) Autonetics Division in Anaheim CA by Harold M. Manasevit. Basic principles ...
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Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utilize its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous ...
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Thallium(I) Nitrate
Thallium(I) nitrate, also known as thallous nitrate, is a thallium compound with the formula Tl NO3. It is a colorless and highly toxic salt. Preparation Thallium(I) nitrate can be produced by reacting thallium(I) iodide with nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com .... However, the production is simpler starting from the metal, its hydroxide or the carbonate: Heinrich Remy: ''Lehrbuch der Anorganischen Chemie'' Band I + II, Leipzig 1973. : : Toxicity Thallium(I) nitrate is extremely toxic, like many other thallium compounds. It is highly toxic by ingestion but can also be absorbed through skin due to its solubility in water.National Center for Biotechnology Information (2023). PubChem Compound Summary for CID 24937, Thallium nitrate. Retrieved March ...
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Hydrogen Peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscosity, viscous than Properties of water, water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as both a monopropellant and an oxidizer in rocketry. Hydrogen peroxide is a reactive oxygen species and the simplest peroxide, a compound having an oxygen–oxygen single bond. It decomposes slowly into water and elemental oxygen when exposed to light, and rapidly in the presence of organic or reactive compounds. It is typically stored with a Stabilizer (chemistry), stabilizer in a weakly acidic solution in an opaque bottle. Hydrogen peroxide is found in biological systems including the human body. Enzymes that u ...
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Acid
An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid. The first category of acids are the proton donors, or Brønsted–Lowry acid–base theory, Brønsted–Lowry acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Acid–base reaction#Arrhenius theory, Arrhenius acids. Johannes Nicolaus Brønsted, Brønsted and Martin Lowry, Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted–Lowry or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+. Aqueous Arrhenius acids have characteristic properties that provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and ...
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Moisture
Moisture is the presence of a liquid, especially water, often in trace amounts. Moisture is defined as water in the adsorbed or absorbed phase. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapor present in the air. The soil also includes moisture. Moisture control in products Control of moisture in products can be a vital part of the process of the product. There is a substantial amount of moisture in what seems to be dry matter. Ranging in products from cornflake cereals to laundry detergent, washing powders, moisture can play an important role in the final quality of the product. There are two main aspects of concern in moisture control in products: allowing too much moisture or too little of it. For example, adding some water to cornflake cereal, which is sold by weight, reduces costs and prevents it from tasting too dry, but adding too much water can affect th ...
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Chemistry Of Materials
Chemistry of Materials is a peer-reviewed scientific journal, published since 1989 by the American Chemical Society. It was founded by Leonard V. Interrante, who was the Editor-in-Chief until 2013. Jillian M. Buriak took over as Editor-in-Chief in January 2014. She was followed by Sara E. Skrabalak, who assumed the position of Editor-in-Chief in November 2020. Abstracting, indexing, and impact factor According to the ''Journal Citation Reports'', ''Chemistry of Materials'' has a 2022 impact factor of 8.6. It is indexed in the following bibliographic databases: *Scopus *Web of Science *British Library The British Library is the national library of the United Kingdom. Based in London, it is one of the largest libraries in the world, with an estimated collection of between 170 and 200 million items from multiple countries. As a legal deposit li ... *CAS Source Index See also * ACS Materials Letters References External links * Chemistry journals Materials science j ...
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Solar Cells
A solar cell, also known as a photovoltaic cell (PV cell), is an electronic device that converts the energy of light directly into electricity by means of the photovoltaic effect.Solar Cells
chemistryexplained.com
It is a type of photoelectric cell, a device whose electrical characteristics (such as current, , or resistance) vary when it is exposed to light. Individual solar cell devices are often the electrical building blocks of
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Bixbyite
Bixbyite is a manganese iron oxide mineral with chemical formula: . The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 – 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra. It is commonly associated with beryl, quartz, spessartine, hematite, pseudobrookite, hausmannite, braunite and topaz in pneumatolytic or hydrothermal veins and cavities and in metamorphic rocks. It can also be found in lithophysal cavities in rhyolite. Typical localities are Jhabua and Chhindwara districts, India and the Thomas Range in Juab County, Utah. It is also reported from San Luis Potosi, Mexico; northern Patagonia, Argentina; Girona, Catalonia, Spain; Sweden, Germany, Namibia, Zimbabwe, and South Africa. Bixbyite was named for the American mineralogist Maynard Bixby (1853–1935), responsible ...
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Semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called " metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easil ...
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Bixbyite
Bixbyite is a manganese iron oxide mineral with chemical formula: . The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 – 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra. It is commonly associated with beryl, quartz, spessartine, hematite, pseudobrookite, hausmannite, braunite and topaz in pneumatolytic or hydrothermal veins and cavities and in metamorphic rocks. It can also be found in lithophysal cavities in rhyolite. Typical localities are Jhabua and Chhindwara districts, India and the Thomas Range in Juab County, Utah. It is also reported from San Luis Potosi, Mexico; northern Patagonia, Argentina; Girona, Catalonia, Spain; Sweden, Germany, Namibia, Zimbabwe, and South Africa. Bixbyite was named for the American mineralogist Maynard Bixby (1853–1935), responsible ...
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