|
Sulfur Nitride
Sulfur nitride may refer to a number of sulfur nitrogen compounds: * Pentasulfur hexanitride, *Tetrasulfur tetranitride, * Tetrasulfur dinitride, *Disulfur dinitride, *Polythiazyl, * Thiatetrazole, Additionally, some unstable species are known: * sulfur mononitride, SN, analogous to nitric oxide, NO * Disulfur mononitride, , analogous to nitrogen dioxide, .Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier *, , analogous to nitrous oxide, See also *Nitrogen oxide Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide * Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), o ...s, which are valence isoelectronic with sulfur nitrides References {{Chemistry index Sulfur–nitrogen compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pentasulfur Hexanitride
The element sulfur exists as many allotropes. In number of allotropes, sulfur is second only to carbon. Greenwood, 652 In addition to the allotropes, each allotrope often exists in polymorphs (different crystal structures of the same covalently bonded Sn molecules) delineated by Greek prefixes (α, β, etc.). Furthermore, because elemental sulfur has been an item of commerce for centuries, its various forms are given traditional names. Early workers identified some forms that have later proved to be single or mixtures of allotropes. Some forms have been named for their appearance, e.g. "mother of pearl sulfur", or alternatively named for a chemist who was pre-eminent in identifying them, e.g. "Muthmann's sulfur I" or "Engel's sulfur". Steudel, 17 The most commonly encountered form of sulfur is the orthorhombic polymorph of , which adopts a puckered ring – or "crown" – structure. Two other polymorphs are known, also with nearly identical molecular structures. Greenwood, 654 I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrasulfur Tetranitride
Tetrasulfur tetranitride is an inorganic compound with the formula . This vivid orange, opaque, crystalline explosive is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding. Nitrogen and sulfur have similar electronegativities. When the properties of atoms are so highly similar, they often form extensive families of covalently bonded structures and compounds. Indeed, a large number of S-N and S-NH compounds are known with as their parent. Structure adopts an unusual "extreme cradle" structure, with D2d point group symmetry. It can be viewed as a derivative of a (hypothetical) eight-membered ring (or more simply a 'deformed' eight-membered ring) of alternating sulfur and nitrogen atoms. The pairs of sulfur atoms across the ring are separated by 2.586 Å, resulting in a cage-like structure as determine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrasulfur Dinitride
The element sulfur exists as many allotropes. In number of allotropes, sulfur is second only to Allotropes of carbon, carbon.#Greenwood, Greenwood, 652 In addition to the allotropes, each allotrope often exists in Polymorphism (materials science), polymorphs (different crystal structures of the same covalently bonded Sn molecules) delineated by Greek prefixes (α, β, etc.). Furthermore, because elemental sulfur has been an item of commerce for centuries, its various forms are given traditional names. Early workers identified some forms that have later proved to be single or mixtures of allotropes. Some forms have been named for their appearance, e.g. "mother of pearl sulfur", or alternatively named for a chemist who was pre-eminent in identifying them, e.g. "Muthmann's sulfur I" or "Engel's sulfur".#Steudel, Steudel, 17 The most commonly encountered form of sulfur is the orthorhombic polymorph of , which adopts a puckered ring – or "crown" – structure. Two other polymorphs a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Disulfur Dinitride
Disulfur dinitride is the chemical compound with the formula . Preparation and reactions Passing gaseous over silver metal wool at 250–300 °C at low pressure (1 mmHg) yields cyclic . The silver reacts with the sulfur produced by the thermal decomposition of the to form , and the resulting catalyzes the conversion of the remaining into the four-membered ring , : : An alternative uses the less explosive . decomposes explosively above 30°C, and is shock sensitive. It readily sublimes, and is soluble in diethyl ether Diethyl ether, or simply ether, is an organic compound with the chemical formula , sometimes abbreviated as . It is a colourless, highly Volatility (chemistry), volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It belongs .... Traces of water cause it to polymerize into . In the solid state it spontaneously polymerizes forming . It forms adducts with Lewis acids via a nitrogen atom, e.g. , , , . Structure and bonding The mo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polythiazyl
Polythiazyl (polymeric sulfur nitride), , is an electrically conductive, gold- or bronze-colored polymer with metallic luster. It was the first conductive inorganic polymer discovered and was also found to be a superconductor at very low temperatures (below 0.26 K). It is a fibrous solid, described as "lustrous golden on the faces and dark blue-black", depending on the orientation of the sample. It is air stable and insoluble in all solvents. History The compound was first reported as early as 1910 by F.P. Burt, who obtained it by heating tetrasulfur tetranitride in vacuum over silver wool. The compound was the first compound with only non-metallic elements in which superconductivity could be demonstrated. However, the relatively low transition temperature at about 0.3 K makes a practical application unlikely.Alsfasser, R.; Janiak, C.; Klapötke, T.M.; Meyer, H.-J.: ''Moderne Anorganische Chemie'', Herausgeber Riedel, E., 3. Auflage 2007, Walter de Gruyter GmbH & Co. KG, Berli ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiatetrazole
A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of organic heterocycles. Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs, most biomass (cellulose and related materials), and many natural and synthetic dyes. More than half of known compounds are heterocycles. 59% of US FDA-approved drugs contain nitrogen heterocycles. Classification The study of organic heterocyclic chemistry focuses especially on organic unsaturated derivatives, and the preponderance of work and applications involves unstrained organic 5- and 6-membered rings. Included are pyridine, thiophene, pyrrole, and furan. Another large class of organic heterocycles refers to those fused to benzene rings. For example, the fused benzene derivatives of pyridin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mononitrogen Monosulfide
Sulfur mononitride is an inorganic compound with the molecular formula SN. It is the sulfur analogue of and Isoelectronicity, isoelectronic to the radical nitric oxide, NO. It was initially detected in 1975, in outer space in giant molecular clouds and later the coma of comets. This spurred further laboratory studies of the compound. Synthetically, it is produced by electric discharge in mixtures of nitrogen and sulfur compounds, or combustion in the gas phase and by photolysis in solution. Synthesis The NS Radical (chemistry), radical is a highly transient species, with a lifetime on the order of milliseconds, but it can be observed spectroscopically over short periods of time through several methods of generation. NS is too reactive to isolate as a solid or liquid, and has only been prepared as a vapor in low pressure or low-temperature matrices due to its tendency to rapidly oligomerize to more stable, diamagnetic species. Discharge of nitrogen and sulfur vapor Transmission ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitric Oxide
Nitric oxide (nitrogen oxide, nitrogen monooxide, or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its chemical formula (•N=O or •NO). Nitric oxide is also a heteronuclear diatomic molecule, a class of molecules whose study spawned early modern theories of chemical bonding. An important intermediate in industrial chemistry, nitric oxide forms in combustion systems and can be generated by lightning in thunderstorms. In mammals, including humans, nitric oxide is a signaling molecule in many physiological and pathological processes. It was proclaimed the " Molecule of the Year" in 1992. The 1998 Nobel Prize in Physiology or Medicine was awarded for discovering nitric oxide's role as a cardiovascular signalling molecule. Its impact extends beyond biology, with applications in medicine, such as the development of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Disulfur Mononitride
Disulfur is the diatomic molecule with the formula S2. It is analogous to the dioxygen molecule but rarely occurs at room temperature. This violet gas is the dominant species in hot sulfur vapors. S2 is one of the minor components of the atmosphere of Io, which is predominantly composed of SO2. The instability of S2 is usually described in the context of the double bond rule. Synthesis This violet gas is generated by heating sulfur and is the predominant species above 720 °C, comprising 80% of all vapor species at 530°C and 100 mm Hg, and 99% of the vapor at low pressure (1 mm Hg) at 730 °C. Disulfur can be produced when an atmosphere of COS is irradiated with UV light using a mercury photosensitizer or when CS2, H2S2, S2Cl2 or C2H4S, PSF3 or COS are irradiated. Natural occurrence Gaseous disulfur has been detected emanating from the surface of Jupiter's moon Io, from the vicinity of Pele volcano. Properties The ground state of S2 is a triplet: a dira ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen Dioxide
Nitrogen dioxide is a chemical compound with the formula . One of several nitrogen oxides, nitrogen dioxide is a reddish-brown gas. It is a paramagnetic, bent molecule with C2v point group symmetry. Industrially, is an intermediate in the synthesis of nitric acid, millions of tons of which are produced each year, primarily for the production of fertilizers. Nitrogen dioxide is poisonous and can be fatal if inhaled in large quantities. Cooking with a gas stove produces nitrogen dioxide which causes poorer indoor air quality. Combustion of gas can lead to increased concentrations of nitrogen dioxide throughout the home environment which is linked to respiratory issues and diseases. The LC50 ( median lethal dose) for humans has been estimated to be 174 ppm for a 1-hour exposure. It is also included in the NOx family of atmospheric pollutants. Properties Nitrogen dioxide is a reddish-brown gas with a pungent, acrid odor above and becomes a yellowish-brown liquid below . ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrous Oxide
Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or factitious air, among others, is a chemical compound, an Nitrogen oxide, oxide of nitrogen with the Chemical formula, formula . At room temperature, it is a colourless Flammability#Definitions, non-flammable gas, and has a slightly sweet scent and taste. At elevated temperatures, nitrous oxide is a powerful Oxidising agent, oxidiser similar to molecular oxygen. Nitrous oxide has significant Nitrous oxide (medication), medical uses, especially in surgery and dentistry, for its Anesthesia, anaesthetic and Analgesic, pain-reducing effects, and it is on the WHO Model List of Essential Medicines, World Health Organization's List of Essential Medicines. Its colloquial name, "laughing gas", coined by Humphry Davy, describes the Euphoria, euphoric effects upon inhaling it, which cause it to be used as a recreational drug inducing a brief "Dissociative, high". When abused chronically ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen Oxide
Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide * Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or nitrate radical *Nitrous oxide (), nitrogen(0,II) oxide * Dinitrogen dioxide (), nitrogen(II) oxide dimer * Dinitrogen trioxide (), nitrogen(II,IV) oxide * Dinitrogen tetroxide (), nitrogen(IV) oxide dimer *Dinitrogen pentoxide (), nitrogen(V) oxide, or nitronium nitrate * Nitrosyl azide (), nitrogen(−I,0,I,II) oxide * Nitryl azide () * Oxatetrazole () * Trinitramide ( or ), nitrogen(0,IV) oxide Anions Cations * Nitrosonium ( or ) * Nitronium ( or ) Atmospheric sciences In atmospheric chemistry: * (or NO''x'') refers to the sum of NO and . * (or NO''y'') refers to the sum of and all oxidized atmospheric odd-nitrogen species (''e.g.'' the sum of , , , etc.) * (or NO''z'') = − * Mixed Oxides of Nitrogen ("MON"): solu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
