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Proton Transfer Reaction Mass Spectrometry
Proton-transfer-reaction mass spectrometry (PTR-MS) is an analytical chemistry technique that uses gas phase hydronium reagent ions which are produced in an ion source. PTR-MS is used for online monitoring of volatile organic compounds (VOCs) in ambient air and was developed in 1995 by scientists at the Institut für Ionenphysik at the Leopold-Franzens University in Innsbruck, Austria. A PTR-MS instrument consists of an ion source that is directly connected to a drift tube (in contrast to SIFT-MS no mass filter is interconnected) and an analyzing system (quadrupole mass analyzer or time-of-flight mass spectrometer). Commercially available PTR-MS instruments have a response time of about 100 ms and reach a detection limit in the single digit pptv or even ppqv region. Established fields of application are environmental research, food and flavor science, biological research, medicine, security, cleanroom monitoring, etc. Theory With H3O+ as the reagent ion the proton transfer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Earth's Atmosphere
The atmosphere of Earth is composed of a layer of gas mixture that surrounds the Earth's planetary surface (both lands and oceans), known collectively as air, with variable quantities of suspended aerosols and particulates (which create weather features such as clouds and hazes), all retained by Earth's gravity. The atmosphere serves as a protective buffer between the Earth's surface and outer space, shields the surface from most meteoroids and ultraviolet solar radiation, keeps it warm and reduces diurnal temperature variation (temperature extremes between day and night) through heat retention (greenhouse effect), redistributes heat and moisture among different regions via air currents, and provides the chemical and climate conditions allowing life to exist and evolve on Earth. By mole fraction (i.e., by quantity of molecules), dry air contains 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other trace gases (see Composition below ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged (cationic) polyatomic ion, molecular ion with the chemical formula or . It is formed by the protonation, addition of a proton (a hydrogen nucleus) to ammonia (). Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by Organic compound, organic or other groups (indicated by R). Not only is ammonium a source of nitrogen and a key metabolite for many living organisms, but it is an integral part of the global nitrogen cycle. As such, human impact in recent years could have an effect on the biological communities that depend on it. Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted–Lowry acid–base theory, Brønsted acids (proton donors): : The ammonium ion is mildly acidic, reacting with Brønsted bases to return ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Time-of-flight Mass Spectrometry
Time-of-flight mass spectrometry (TOFMS) is a method of mass spectrometry in which an ion's mass-to-charge ratio is determined by a time of flight measurement. Ions are accelerated by an electric field of known strength. This acceleration results in an ion having the same kinetic energy as any other ion that has the same charge. The velocity of the ion depends on the mass-to-charge ratio (heavier ions of the same charge reach lower speeds, although ions with higher charge will also increase in velocity). The time that it subsequently takes for the ion to reach a detector at a known distance is measured. This time will depend on the velocity of the ion, and therefore is a measure of its mass-to-charge ratio. From this ratio and known experimental parameters, one can identify the ion. Theory The potential energy of a charged particle in an electric field is related to the charge of the particle and to the strength of the electric field: where ''E''p is potential energy, ''q'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum Pump
A vacuum pump is a type of pump device that draws gas particles from a sealed volume in order to leave behind a partial vacuum. The first vacuum pump was invented in 1650 by Otto von Guericke, and was preceded by the suction pump, which dates to antiquity. History Early pumps The predecessor to the vacuum pump was the suction pump. Dual-action suction pumps were found in the city of Pompeii. Arabic engineer Al-Jazari later described dual-action suction pumps as part of water-raising machines in the 13th century. He also said that a suction pump was used in siphons to discharge Greek fire. The suction pump later appeared in medieval Europe from the 15th century. Donald Routledge Hill (1996), ''A History of Engineering in Classical and Medieval Times'', Routledge, pp. 143 & 150-2 Donald Routledge Hill, "Mechanical Engineering in the Medieval Near East", ''Scientific American'', May 1991, pp. 64-69 (cf. Donald Routledge HillMechanical Engineering By the 17th century, water ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
PTR Mass Spectrometer With Quadrupol Mass Analyzer, Schematics
PTR can refer to: * Particle transfer roller, for cleaning motion picture film * Peak-to-trough ratio, a parameter in pharmacokinetics * Petir LRT station (LRT station abbreviation), Singapore * PetroChina (NYSE: PTR) * Photothermal Ratio, light/temperature ratio for a plant * Physical transmission right in the electricity market * Physikalisch-Technische Reichsanstalt, later Physikalisch-Technische Bundesanstalt, a German research institute * Pitrilysin, an enzyme * Planar ternary ring in algebra * Pool Test Reactor, Canada * Proton-transfer-reaction mass spectrometry, used in chemical analysis * PTR rifle, made by PTR Industries, Inc., US * A type of DNS record in computer networking * Pointer in computer programming (e.g. the PTR keyword in x86 assembly language) * Palanivel Thiagarajan, an Indian politician * Puerto Rico, ITU country code * Public Test Realm, a server in ''Overwatch'' where updates are tested by developers for player feedback * PaRappa the Rapper ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Academic Journal
An academic journal (or scholarly journal or scientific journal) is a periodical publication in which Scholarly method, scholarship relating to a particular academic discipline is published. They serve as permanent and transparent forums for the dissemination, scrutiny, and discussion of research. Unlike professional magazines or Trade magazine, trade magazines, the articles are mostly written by researchers rather than staff writers employed by the journal. They nearly universally require peer review for Research Article, research articles or other scrutiny from contemporaries competent and established in their respective fields. Academic journals trace their origins back to the 17th century. , it is estimated that over 28,100 active academic journals are in publication, with scopes ranging from the general sciences, as seen in journals like ''Science (journal), Science'' and ''Nature (journal), Nature'', to highly specialized fields. These journals publish a variety of articles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calibration
In measurement technology and metrology, calibration is the comparison of measurement values delivered by a device under test with those of a calibration standard of known accuracy. Such a standard could be another measurement device of known accuracy, a device generating the quantity to be measured such as a voltage, a sound tone, or a physical artifact, such as a meter ruler. The outcome of the comparison can result in one of the following: * no significant error being noted on the device under test * a significant error being noted but no adjustment made * an adjustment made to correct the error to an acceptable level Strictly speaking, the term "calibration" means just the act of comparison and does not include any subsequent adjustment. The calibration standard is normally traceable to a national or international standard held by a metrology body. BIPM Definition The formal definition of calibration by the International Bureau of Weights and Measures (BIPM) is the foll ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Concentration
In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', '' molar concentration'', '' number concentration'', and '' volume concentration''. The concentration can refer to any kind of chemical mixture, but most frequently refers to solutes and solvents in solutions. The molar (amount) concentration has variants, such as normal concentration and osmotic concentration. Dilution is reduction of concentration, e.g. by adding solvent to a solution. The verb to concentrate means to increase concentration, the opposite of dilute. Etymology ''Concentration-'', ''concentratio'', action or an act of coming together at a single place, bringing to a common center, was used in post-classical Latin in 1550 or earlier, similar terms attested in Italian (1589), Spanish (1589), English (1606), French (1632). Qualitative description Often in informal, non- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reaction Rate Constant
In chemical kinetics, a reaction rate constant or reaction rate coefficient () is a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants. For a reaction between reactants A and B to form a product C, where :A and B are reactants :C is a product :''a'', ''b'', and ''c'' are stoichiometric coefficients, the reaction rate is often found to have the form: r = k mathrmm mathrm Here is the reaction rate constant that depends on temperature, and and are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution. (For a reaction taking place at a boundary, one would use moles of A or B per unit area instead.) The exponents ''m'' and ''n'' are called partial orders of reaction and are ''not'' generally equal to the stoichiometric coefficients ''a'' and ''b''. Instead they depend on the reacti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Buffer Gas
Buffer may refer to: Science * Buffer gas, an inert or nonflammable gas * Buffer solution, a solution used to prevent changes in pH * Lysis buffer, in cell biology * Metal ion buffer * Mineral redox buffer, in geology Technology and engineering * Buffer (GIS), a zone around a map feature * Buffer (optical fiber), a component of a fiber optic cable * Buffer (rail transport), a device that cushions impacts between vehicles * Buffer amplifier, an isolating circuit used in electronics or telecommunications * Buffer stop, a device that keeps rail vehicles on tracks * Buffer wheel, a device used to smooth a workpiece's surface * Digital buffer, an electronic circuit used to isolate the input from the output * Floor buffer, an appliance used to polish hard floors * Optical buffer, a device that stores optically transmitted data * Recoil buffer, a firearm component * Seismic buffers, protect structures against the effects of earthquakes Computing * Buffer (application), a software applic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
