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Prigogine's Theorem Of Minimum Entropy Production
Prigogine's theorem is a theorem of non-equilibrium thermodynamics, originally formulated by Ilya Prigogine. The formulation of Prigogine's theorem is: According to this theorem, the stationary state of a linear non-equilibrium system (under conditions that prevent the achievement of an equilibrium state) corresponds to the minimum entropy production. If there are no such obstacles, then the production of entropy reaches its absolute minimum - zero. A linear system means the fulfillment of linear phenomenological relationships between thermodynamic flows and driving forces. The coefficients of proportionality in the relationships between flows and driving forces are called phenomenological coefficients. The theorem was proved by Prigogine in 1947 from the Onsager relations. Prigogine's theorem is valid if the kinetic coefficients in the Onsager relations are constant (do not depend on driving forces and flows); for real systems, it is valid only approximately, so the minimum ent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Non-equilibrium Thermodynamics
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions. Almost all systems found in nature are not in thermodynamic equilibrium, for they are changing or can be triggered to change over time, and are continuously and discontinuously subject to flux of matter and energy to and from other systems and to chemical reactions. Some systems and processes are, however, in a useful sense, near enough to thermodynamic equilibrium to allow description with useful accuracy by currently known non-equilibrium thermodynamics. Nevertheless, many natural systems and processes will always remain far beyond the scope ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ilya Prigogine
Viscount Ilya Romanovich Prigogine (; russian: Илья́ Рома́нович Приго́жин; 28 May 2003) was a physical chemist and Nobel laureate noted for his work on dissipative structures, complex systems, and irreversibility. Biography Prigogine was born in Moscow a few months before the Russian Revolution of 1917, into a Jewish family. His father, Ruvim Abramovich Prigogine, was a chemical engineer at the Imperial Moscow Technical School; his mother, Yulia Vikhman, was a pianist. Because the family was critical of the new Soviet system, they left Russia in 1921. They first went to Germany and in 1929, to Belgium, where Prigogine received Belgian nationality in 1949. His brother Alexandre (1913–1991) became an ornithologist. Prigogine studied chemistry at the Free University of Brussels, where in 1950, he became professor. In 1959, he was appointed director of the International Solvay Institute in Brussels, Belgium. In that year, he also started teaching at ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Onsager Relations
In thermodynamics, the Onsager reciprocal relations express the equality of certain ratios between flows and forces in thermodynamic systems out of equilibrium, but where a notion of local equilibrium exists. "Reciprocal relations" occur between different pairs of forces and flows in a variety of physical systems. For example, consider fluid systems described in terms of temperature, matter density, and pressure. In this class of systems, it is known that temperature differences lead to heat flows from the warmer to the colder parts of the system; similarly, pressure differences will lead to matter flow from high-pressure to low-pressure regions. What is remarkable is the observation that, when both pressure and temperature vary, temperature differences at constant pressure can cause matter flow (as in convection) and pressure differences at constant temperature can cause heat flow. Perhaps surprisingly, the heat flow per unit of pressure difference and the density (matter) flo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fourier's Law
Conduction is the process by which heat is transferred from the hotter end to the colder end of an object. The ability of the object to conduct heat is known as its ''thermal conductivity'', and is denoted . Heat spontaneously flows along a temperature gradient (i.e. from a hotter body to a colder body). For example, heat is conducted from the hotplate of an electric stove to the bottom of a saucepan in contact with it. In the absence of an opposing external driving energy source, within a body or between bodies, temperature differences decay over time, and thermal equilibrium is approached, temperature becoming more uniform. In conduction, the heat flow is within and through the body itself. In contrast, in heat transfer by thermal radiation, the transfer is often between bodies, which may be separated spatially. Heat can also be transferred by a combination of conduction and radiation. In solids, conduction is mediated by the combination of vibrations and collisions of mole ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fick's Law
Fick's laws of diffusion describe diffusion and were derived by Adolf Fick in 1855. They can be used to solve for the diffusion coefficient, . Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation. A diffusion process that obeys Fick's laws is called normal or Fickian diffusion; otherwise, it is called anomalous diffusion or non-Fickian diffusion. History In 1855, physiologist Adolf Fick first reported* * his now well-known laws governing the transport of mass through diffusive means. Fick's work was inspired by the earlier experiments of Thomas Graham, which fell short of proposing the fundamental laws for which Fick would become famous. Fick's law is analogous to the relationships discovered at the same epoch by other eminent scientists: Darcy's law (hydraulic flow), Ohm's law (charge transport), and Fourier's Law (heat transport). Fick's experiments (modeled on Graham's) dealt with measuring the concentrations and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Equilibrium
In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. This state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but they are equal. Thus, there are no net changes in the concentrations of the reactants and products. Such a state is known as dynamic equilibrium. Historical introduction The concept of chemical equilibrium was developed in 1803, after Berthollet found that some chemical reactions are reversible. For any reaction mixture to exist at equilibrium, the rates of the forward and backward (reverse) reactions must be equal. In the following chemical equation, arrows point both ways to indicate equilibrium. A and B are reactant chemical species, S and T a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Theorems
In mathematics, a theorem is a statement that has been proved, or can be proved. The ''proof'' of a theorem is a logical argument that uses the inference rules of a deductive system to establish that the theorem is a logical consequence of the axioms and previously proved theorems. In the mainstream of mathematics, the axioms and the inference rules are commonly left implicit, and, in this case, they are almost always those of Zermelo–Fraenkel set theory with the axiom of choice, or of a less powerful theory, such as Peano arithmetic. A notable exception is Wiles's proof of Fermat's Last Theorem, which involves the Grothendieck universes whose existence requires the addition of a new axiom to the set theory. Generally, an assertion that is explicitly called a theorem is a proved result that is not an immediate consequence of other known theorems. Moreover, many authors qualify as ''theorems'' only the most important results, and use the terms ''lemma'', ''proposition'' and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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