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Precipitate-free Zone
In materials science, a precipitate-free zone (PFZ) refers to microscopic localized regions around grain boundaries that are free of precipitates (solid impurities forced outwards from the grain during crystallization). It is a common phenomenon that arises in polycrystalline materials (crystalline materials with stochastically-oriented grains) where heterogeneous nucleation of precipitates is the dominant nucleation mechanism. This is because grain boundaries are high-energy surfaces that act as sinks for vacancies, causing regions adjacent to a grain boundary to be devoid of vacancies. As it is energetically favorable for heterogeneous nucleation to occur preferentially around defect-rich sites such as vacancies, nucleation of precipitates is impeded in the vacancy-free regions immediately adjacent to grain boundaries History Pioneering studies on the theory and experimental observation of PFZs were made in the 1960s. Effect on material properties PFZs are detrimental to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wikipedia PFZ
Wikipedia is a free content, free Online content, online encyclopedia that is written and maintained by a community of volunteers, known as Wikipedians, through open collaboration and the wiki software MediaWiki. Founded by Jimmy Wales and Larry Sanger in 2001, Wikipedia has been hosted since 2003 by the Wikimedia Foundation, an American 501(c)(3) organization, nonprofit organization funded mainly by donations from readers. Wikipedia is the largest and most-read reference work in history. Initially available only in English language, English, Wikipedia exists list of Wikipedias, in over 340 languages. The English Wikipedia, with over million Article (publishing), articles, remains the largest of the editions, which together comprise more than articles and attract more than 1.5 billion unique device visits and 13 million edits per month (about 5edits per second on average) . , over 25% of Wikipedia's web traffic, traffic comes from the United States, while Jap ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacancy Defect
In crystallography, a vacancy is a type of point defect in a crystal where an atom is missing from one of the lattice sites.Ehrhart, P. (1991) "Properties and interactions of atomic defects in metals and alloys", chapter 2, p. 88 in ''Landolt-Börnstein, New Series III'', Vol. 25, Springer, Berlin Crystals inherently possess imperfections, sometimes referred to as crystallographic defects. Vacancies occur naturally in all crystalline materials. At any given temperature, up to the melting point of the material, there is an equilibrium concentration (ratio of vacant lattice sites to those containing atoms). At the melting point of some metals the ratio can be approximately 1:1000. This temperature dependence can be modelled by :N_ = N \exp\left(\frac\right) where is the vacancy concentration, is the energy required for vacancy formation, is the Boltzmann constant, is the absolute temperature, and is the concentration of atomic sites i.e. : N = \frac where is density, t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table), it occurs naturally only in combination with other elements and almost always has an oxidation state of +2. It reacts readily with air to form a thin Passivation (chemistry), passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium Salt (chemistry), salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight magnesium alloy, alloys that contain aluminium. In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three Helium nucleus, helium nuclei to a carbon nucleus. When such stars explo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Undercooling
Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid below its freezing point without it becoming a solid. Per the established international definition, supercooling means ''‘cooling a substance below the normal freezing point without solidification’.'' IIR International Dictionary of Refrigeration, http://dictionary.iifiir.org/search.php ASHRAE Terminology, https://www.ashrae.org/technical-resources/free-resources/ashrae-terminology While it can be achieved by different physical means, the postponed solidification is most often due to the absence of seed crystals or nuclei around which a crystal structure can form. The supercooling of water can be achieved without any special techniques other than chemical demineralization, down to . Supercooled water can occur naturally, for example in the atmosphere, animals or plants. This phenomenon was first identified in 1724 by Daniel Gabriel Fahrenheit, while developing Fahrenheit scale. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quenching
In materials science, quenching is the rapid cooling of a workpiece in water, gas, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as phase transformations, from occurring. It does this by reducing the window of time during which these undesired reactions are both thermodynamically favorable and kinetically accessible; for instance, quenching can reduce the crystal grain size of both metallic and plastic materials, increasing their hardness. In metallurgy, quenching is most commonly used to harden steel by inducing a martensite transformation, where the steel must be rapidly cooled through its eutectoid point, the temperature at which austenite becomes unstable. Rapid cooling prevents the formation of cementite structure, instead forcibly dissolving carbon atoms in the ferrite lattice. In steel alloyed with metals such as nickel and manganese, the eutectoid t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stress Corrosion Cracking
Stress corrosion cracking (SCC) is the growth of crack formation in a corrosive environment. It can lead to unexpected and sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. SCC is highly chemically specific in that certain alloys are likely to undergo SCC only when exposed to a small number of chemical environments. The chemical environment that causes SCC for a given alloy is often one which is only mildly corrosive to the metal. Hence, metal parts with severe SCC can appear bright and shiny, while being filled with microscopic cracks. This factor makes it common for SCC to go undetected prior to failure. SCC often progresses rapidly, and is more common among alloys than pure metals. The specific environment is of crucial importance, and only very small concentrations of certain highly active chemicals are needed to produce catastrophic cracking, often leading to devastating and unexpected failure. The stresse ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pitting Corrosion
Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic (oxidation reaction) while an unknown but potentially vast area becomes cathodic (reduction reaction), leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions. Another term arises, pitting factor, which is defined as the ratio of the depth of the deepest pit (resulting due to corrosion) to the average penetration, which can be calculated based on the weight loss. Development and kinetics of pitting According to Frankel (1998) who performed a review on pitting corrosion, it develops in three successive steps: (or nucleation) by breakdown of the passive film protecting the metal surface from oxidation, (2) growth of metastable pits (growing up to the micron scale and then repassivat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dislocation
In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to slide over each other at low stress levels and is known as ''glide'' or Slip (materials science), slip. The crystalline order is restored on either side of a ''glide dislocation'' but the atoms on one side have moved by one position. The crystalline order is not fully restored with a ''partial dislocation''. A dislocation defines the boundary between ''slipped'' and ''unslipped'' regions of material and as a result, must either form a complete loop, intersect other dislocations or defects, or extend to the edges of the crystal. A dislocation can be characterised by the distance and direction of movement it causes to atoms which is defined by the Burgers vector. Plasticity (physics), Plastic deformation of a material occurs by the creation and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Energetically Favorable
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy is expressed as G(p,T) = U + pV - TS = H - TS where: * U is the internal energy of the system * H is the enthalpy of the system * S is the entropy of the system * T is the temperature of the system * V is the volume of the system * p is the pressure of the system (which must be equal to that of the surroundings for mechanical equilibrium). The Gibbs free energy change (, measured in joules in SI) is the ''maximum'' amount of non-volume expansion work that can be extracted from a closed system (one that can exchange heat and work with i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleation
In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) significantly below 0°C, it will tend to Freezing, freeze into ice, but volumes of water cooled only a few degrees below 0°C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay. Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Materials Science
Materials science is an interdisciplinary field of researching and discovering materials. Materials engineering is an engineering field of finding uses for materials in other fields and industries. The intellectual origins of materials science stem from the Age of Enlightenment, when researchers began to use analytical thinking from chemistry, physics, and engineering to understand ancient, phenomenological observations in metallurgy and mineralogy. Materials science still incorporates elements of physics, chemistry, and engineering. As such, the field was long considered by academic institutions as a sub-field of these related fields. Beginning in the 1940s, materials science began to be more widely recognized as a specific and distinct field of science and engineering, and major technical universities around the world created dedicated schools for its study. Materials scientists emphasize understanding how the history of a material (''processing'') influences its struc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stochastic
Stochastic (; ) is the property of being well-described by a random probability distribution. ''Stochasticity'' and ''randomness'' are technically distinct concepts: the former refers to a modeling approach, while the latter describes phenomena; in everyday conversation, however, these terms are often used interchangeably. In probability theory, the formal concept of a '' stochastic process'' is also referred to as a ''random process''. Stochasticity is used in many different fields, including image processing, signal processing, computer science, information theory, telecommunications, chemistry, ecology, neuroscience, physics, and cryptography. It is also used in finance (e.g., stochastic oscillator), due to seemingly random changes in the different markets within the financial sector and in medicine, linguistics, music, media, colour theory, botany, manufacturing and geomorphology. Etymology The word ''stochastic'' in English was originally used as an adjective with the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
