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Polythionic Acid
Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula Sn(SO3H)2 (''n'' + 2 > 2). Trithionic acid (H2S3O6), tetrathionic acid (H2S4O6) are simple examples. They are the conjugate acids of polythionates. The compounds of ''n'' 2− + 2 HCl :: SCl2 + 2 → 3SS3SO3sup>2− + 2 HCl Anhydrous polythionic acids can be formed in diethyl ether solution by the following three general ways: : HSnSO3H + SO3 → H2S''n''+2O6 (''n'' = 1, 2 ... 8) : H2Sn + 2 SO3 → H2S''n''+2O6 (''n'' = 1, 2 ... 8) : 2 HSnSO3H + I2 → H2S2''n''+2O6 + 2 HI (''n'' = 1, 2 ... 6) Polythionic acids with a small number of sulfur atoms in the chain (''n'' = 3, 4, 5, 6) are the most stable. Polythionic acids are stable only in aqueous solutions, and are rapidly destroyed at higher concentrations with the release of sulfur, sulfur dioxide and - sometimes - sulfuric acid. Acid salts of polythionic acids do not exist. Polythionate ions are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chain Transfer
In polymer chemistry, chain transfer is a polymerization reaction by which the activity of a growing polymer chain is transferred to another molecule: \ce^\bullet + \ce^\bullet where • is the active center, P is the initial polymer chain, X is the end group, and R is the substituent to which the active center is transferred. Chain transfer reactions reduce the average molecular weight of the final polymer. Chain transfer can be either introduced deliberately into a polymerization (by use of a ''chain transfer agent'') or it may be an unavoidable side-reaction with various components of the polymerization. Chain transfer reactions occur in most forms of addition polymerization including radical polymerization, ring-opening polymerization, coordination polymerization, and cationic polymerization, as well as anionic polymerization. Types Chain transfer reactions are usually categorized by the nature of the molecule that reacts with the growing chain. * Transfer to cha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur Oxoacids
Sulfur oxoacids are chemical compounds that contain sulfur, oxygen, and hydrogen. The best known and most important industrially used is sulfuric acid. Sulfur has several oxoacids; however, some of these are known only from their salts (these are shown in italics in the table below). The acids that have been characterised contain a variety of structural features, for example: *tetrahedral sulfur when coordinated to oxygen *terminal and bridging oxygen atoms *terminal peroxo groups *terminal S=S *chains of (−S−)''n'' See also *Chlorosulfuric acid *Fluorosulfuric acid *Nitrosylsulfuric acid *Peroxydisulfuric acid *Sulfinic acids *Sulfonic acids References External links *{{MeSH name, Sulfur+Acids Sulfur oxoacids along with other acids containing sulfur Sulfur oxoacids, Sulfur compounds Chalcogen oxoacids ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prediction Of Volcanic Activity
Prediction of volcanic activity, and volcanic eruption forecasting, is an interdisciplinary monitoring and research effort to predict the time and severity of a volcano's eruption. Of particular importance is the prediction of hazardous eruptions that could lead to catastrophic loss of life, property, and disruption of human activities. Risk and uncertainty are central to forecasting and prediction, which are not necessarily the same thing in the context of volcanoes, where opinions have often played a role, and the prediction in time (forecasting) for an individual volcano is different from predicting eruption characteristics for apparently similar volcanoes. Both forecasting and prediction have processes based on past and present data. Seismic waves (seismicity) General principles of volcano seismology * Seismic activity (earthquakes and tremors) always occurs as volcanoes awaken and prepare to erupt and are a very important link to eruptions. Some volcanoes normally have co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Volcanic Crater Lake
A volcanic crater lake is a lake in a volcanic crater, crater that was formed by explosive eruption, explosive activity or a caldera, collapse during a types of volcanic eruptions, volcanic eruption. Formation Lakes in calderas fill large craters formed by the collapse of a volcano during an eruption. Lakes in maars fill medium-sized craters where an eruption deposited debris around a vent. Crater lakes form as the created depression, within the Rim (craters), crater rim, is filled by water. The water may come from Precipitation (meteorology), precipitation, groundwater circulation (often Hot Spring, hydrothermal fluids in the case of volcanic craters) or melted ice. Its level rises until an equilibrium is reached between the rates of incoming and outgoing water. Sources of water loss singly or together may include evaporation, subsurface seepage, and, in places, surface leakage or overflow when the lake level reaches the lowest point on its rim. At such a saddle location, the u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfites
Sulfites or sulphites are chemical compound, compounds that contain the sulfite ion (IUPAC nomenclature of inorganic chemistry, systematic name: sulfate(IV) ion), . The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive, its salts are widely used. Sulfites are substances that naturally occur in some foods and the human body. They are also used as regulated food additives. When in food or drink, sulfites are often lumped together with sulfur dioxide.SeREGULATION (EU) No 1169/2011 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL/ref> Structure The structure of the sulfite anion can be described with three equivalent resonance structures. In each resonance structure, the sulfur atom is double-bonded to one oxygen atom with a formal charge of zero (neutral), and sulfur is singly bonded to the other two oxygen atoms, which each carry a formal charge of −1, together accounting for the −2 charge on the anion. There is also a non-bonded lone ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amalgam (chemistry)
An amalgam is an alloy of mercury (element), mercury with another metal. It may be a liquid, a soft paste or a solid, depending upon the proportion of mercury. These alloys are formed through metallic bonding, with the electrostatic attractive force of the conduction electrons working to bind all the positively charged metal ions together into a Crystal structure, crystal lattice structure. Almost all metals can form amalgams with mercury, the notable exceptions being iron, platinum, tungsten, and tantalum. Gold-mercury amalgam is used in the Gold extraction, extraction of gold from ore, and Amalgam (dentistry), dental amalgams are made with metals such as silver, copper, indium, tin and zinc. Important amalgams Zinc amalgam Zinc amalgam finds use in organic synthesis (e.g., for the Clemmensen reduction). It is the reducing agent in the Jones reductor, used in analytical chemistry. Formerly the zinc plates of dry battery (electric), batteries were amalgamated with a small amo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedral arrangement. The symmetry of the isolated anion is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid. The tetrahedral ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Dichromate
Potassium dichromate is the inorganic compound with the formula . An orange solid, it is used in diverse laboratory and industrial applications. As with all hexavalent chromium compounds, it is chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in laboratories because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.Gerd Anger, Jost Halstenberg, Klaus Hochgeschwender, Christoph Scherhag, Ulrich Korallus, Herbert Knopf, Peter Schmidt, Manfred Ohlinger, "Chromium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. Production Potassium dichromate is usually prepared by the reaction of sodium dichromate and potassium chloride. Alternatively, it can be also obtained from potassium chromate by roasting chromite ore with potassium hydroxide: : Structure The solid crystallizes as two polymorphs. These salts are soluble in water, and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Permanganate
Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and ions to give an intensely pink to purple solution. Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also as a medication for dermatitis, for cleaning wounds, and general disinfection. It is commonly used as a biocide for water treatment purposes. It is on the World Health Organization's List of Essential Medicines. In 2000, worldwide production was estimated at 30,000 tons. Properties Potassium permanganate is the potassium salt of the tetrahedral transition metal oxo complex permanganate, in which four ligands are bound to a manganese(VII) center. Structure forms orthorhombic crystals with constants: ''a'' = 910.5 pm, ''b'' = 572.0 pm, ''c'' = 742.5 pm. The overall motif is similar to that for barium sulfate, with which it forms solid so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diethyl Ether
Diethyl ether, or simply ether, is an organic compound with the chemical formula , sometimes abbreviated as . It is a colourless, highly Volatility (chemistry), volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It belongs to the ether class of organic compounds. It is a common solvent and was formerly used as a general anesthetic. Production Most diethyl ether is produced as a byproduct of the vapor-phase Hydration reaction, hydration of ethylene to make ethanol. This process uses solid-supported phosphoric acid Catalysis, catalysts and can be adjusted to make more ether if the need arises: Vapor-phase Dehydration reaction, dehydration of ethanol over some Aluminium oxide, alumina catalysts can give diethyl ether yields of up to 95%. : Diethyl ether can be prepared both in laboratories and on an industrial scale by the acid ether synthesis. Uses The dominant use of diethyl ether is as a solvent. One particular application is in the production of cell ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
