Polanyi Potential Theory
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Polanyi Potential Theory
In physical chemistry, the Polanyi potential theory, also called Polanyi's potential theory of adsorption or Eucken–Polanyi potential theory, is a model of adsorption proposed independently by Michael Polanyi and Arnold Eucken. Under this model, adsorption can be measured through the Chemical equilibrium, equilibrium between the chemical potential of a gas near the surface and the chemical potential of the gas from a large distance away. In this model, the attraction largely due to Van der Waals forces of the gas to the surface is determined by the position of the gas particle from the surface, and that the gas behaves as an ideal gas until condensation where the gas exceeds its equilibrium vapor pressure. While the Henry adsorption constant, adsorption theory of William Henry (chemist), William Henry is more applicable in low pressure and the adsorption isotherm equation from BET theory, Brunauer–Emmett–Teller (BET) theory is more useful at from 0.05 to 0.35 , the Polanyi pot ...
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Physical Chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria. Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids). Some of the relationships that physical chemistry strives to understand include the effects of: # Intermolecular forces that act upon the physical properties of materials ( plasticity, tensile strength, surface tension in liquids). # Reaction kinetics on the rate of a reaction. # The identity of ions and the electrical conductivity of materials. # Surface science and electrochemistry of cell m ...
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Niels Bohr
Niels Henrik David Bohr (, ; ; 7 October 1885 – 18 November 1962) was a Danish theoretical physicist who made foundational contributions to understanding atomic structure and old quantum theory, quantum theory, for which he received the Nobel Prize in Physics in 1922. Bohr was also a philosopher and a promoter of scientific research. Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been supplanted by other models, its underlying principles remain valid. He conceived the principle of Complementarity (physics), complementarity: that items could be separately analysed in terms of contradictory properties, like behaving as a Wave–particle duality, wave or a stream of particles. The notion of complementarity dominated Bohr's thinking in both science and philoso ...
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Fritz London
Fritz Wolfgang London (March 7, 1900 – March 30, 1954) was a German born physicist and professor at Duke University. His fundamental contributions to the theories of chemical bonding and of intermolecular forces (London dispersion forces) are today considered classic and are discussed in standard textbooks of physical chemistry. With his brother Heinz London, he made a significant contribution to understanding electromagnetic properties of superconductors with the London equations and was nominated for the Nobel Prize in Chemistry on five separate occasions. Biography London was born in Breslau, German Empire, Germany (now Wrocław, Poland) as the son of Franz London (1863-1917). Being a Jew, London lost his position at the Humboldt University of Berlin, University of Berlin after Hitler's Nazi Party passed the Law for the Restoration of the Professional Civil Service, 1933 racial laws. He took visiting positions in England and France, and emigrated to the United States in 1939, ...
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Kaiser Wilhelm Institute For Physical Chemistry
The Kaiser Wilhelm Society for the Advancement of Science () was a German scientific institution established in the German Empire in 1911. Its functions were taken over by the Max Planck Society. The Kaiser Wilhelm Society was an umbrella organisation for many institutes, testing stations, and research units created under its authority. History Constitution The Kaiser Wilhelm Gesellschaft (KWG) was founded in 1911 as a research institution outside the university system in order to advance the interests of German state and capital through the development of scientific knowledge relevant to industrial and military application. The inaugural meeting was held on 11 January 1911. The constituent institutes were established in succession and placed under the guidance of prominent directors, whose ranks included the physicists and chemists Walther Bothe, Peter Debye, Albert Einstein, Fritz Haber and Otto Hahn; a board of trustees also provided guidance. Funding came from both bus ...
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Fritz Haber
Fritz Jakob Haber (; 9 December 1868 – 29 January 1934) was a German chemist who received the Nobel Prize in Chemistry in 1918 for his invention of the Haber process, a method used in industry to synthesize ammonia from nitrogen gas and hydrogen gas. This invention is important for the large-scale synthesis of fertilizers and Explosive material, explosives. It is estimated that a third of annual global food production uses ammonia from the Haber–Bosch process, and that this food supports nearly half the world's population. For this work, Haber has been called one of the most important scientists and industrial chemists in human history. Haber also, along with Max Born, proposed the Born–Haber cycle as a method for evaluating the lattice energy of an ionic solid. Haber, a known German nationalist, is also considered the "father of chemical warfare" for his years of pioneering work developing and Chlorine#Use as a weapon, weaponizing chlorine and other poisonous gases during ...
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Hungary In World War I
At the outbreak of World War I in August 1914, Hungary was part of the Dual Monarchy of Austria-Hungary. Although there are no significant battles specifically connected to Hungarian regiments, the troops suffered high losses throughout the war as the Empire suffered defeat after defeat. The result was the breakup of the Empire and eventually, Hungary suffered severe territorial losses by the closing Treaty of Trianon, Trianon Peace Treaty. The Empire at the outbreak of the war In 1914, Austria-Hungary was one of the great powers of Europe, with an area of 676,443 km2 and a population of 52 million, of which Hungary had 325,400 km2 with population of 21 million. By 1913, the combined length of the railway tracks of the Austrian Empire and Kingdom of Hungary reached 43,280 kilometres (26,890 miles). In Western Europe only Germany had more extended railway network (63,378 km, 39,381 mi); the Austro-Hungarian Empire was followed by France ( ...
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Austria-Hungary
Austria-Hungary, also referred to as the Austro-Hungarian Empire, the Dual Monarchy or the Habsburg Monarchy, was a multi-national constitutional monarchy in Central Europe#Before World War I, Central Europe between 1867 and 1918. A military and diplomatic alliance, it consisted of two sovereign states with a single monarch who was titled both the Emperor of Austria and the King of Hungary. Austria-Hungary constituted the last phase in the constitutional evolution of the Habsburg monarchy: it was formed with the Austro-Hungarian Compromise of 1867 in the aftermath of the Austro-Prussian War, following wars of independence by Hungary in opposition to Habsburg rule. It was dissolved shortly after Dissolution of Austria-Hungary#Dissolution, Hungary terminated the union with Austria in 1918 at the end of World War 1. One of Europe's major powers, Austria-Hungary was geographically the second-largest country in Europe (after Russian Empire, Russia) and the third-most populous (afte ...
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Nobel Prize In Chemistry
The Nobel Prize in Chemistry () is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outstanding contributions in chemistry, physics, literature, peace, and physiology or medicine. This award is administered by the Nobel Foundation and awarded by the Royal Swedish Academy of Sciences on proposal of the Nobel Committee for Chemistry, which consists of five members elected by the Academy. The award is presented in Stockholm at an annual ceremony on December 10th, the anniversary of Nobel's death. The first Nobel Prize in Chemistry was awarded in 1901 to Jacobus Henricus van 't Hoff, of the Netherlands, "for his discovery of the laws of chemical dynamics and osmotic pressure in solutions". From 1901 to 2024, the award has been bestowed on a total of 195 individuals. The 2024 Nobel Prize in Chemistry was awarded to Demis Hassabis ...
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Irving Langmuir
Irving Langmuir (; January 31, 1881 – August 16, 1957) was an American chemist, physicist, and metallurgical engineer. He was awarded the Nobel Prize in Chemistry in 1932 for his work in surface chemistry. Langmuir's most famous publication is the 1919 article "The Arrangement of Electrons in Atoms and Molecules" in which, building on Gilbert N. Lewis's cubical atom theory and Walther Kossel's chemical bonding theory, he outlined his "concentric theory of atomic structure". Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuir's presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at General Electric from 1909 to 1950, Langmuir advanced several fields of physics and chemistry, inventing the gas-filled incandescent lamp and the hydrogen welding technique. The Langmuir Laboratory for Atmospheric Research near Socorro, New Mexico, was named ...
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Langmuir Adsorption Model
The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes. This model even explains the effect of pressure; ''i.e.'', at these conditions the adsorbate's partial pressure p_A is related to its volume adsorbed onto a solid adsorbent. The adsorbent, as indicated in the figure, is assumed to be an ideal solid surface composed of a series of distinct sites capable of binding the adsorbate. The adsorbate binding is treated as a chemical reaction between the adsorbate gaseous molecule A_\text and an empty sorption site . This reaction yields an adsorbed species A_\text with an associated equilibrium constant K_\text: : A_ + S A_. From these basic hypotheses the mathematical formulation of the Langmuir adsorption isotherm can be derived in various independent and complementary ways: by the kinetics, the thermodynamics, and the statistical mech ...
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Willem Hendrik Keesom
Willem Hendrik Keesom () (21 June 1876, Texel – 3 March 1956, Leiden) was a Dutch physicist who, in 1926, invented a method to freeze liquid helium. He also developed the first mathematical description of dipole–dipole interactions in 1921. Thus, dipole–dipole interactions are also known as Keesom interactions. He was previously a student of Heike Kamerlingh Onnes, who had discovered superconductivity (a feat for which Kamerlingh Onnes received the 1913 Nobel Prize in Physics). He also discovered the lambda point transition specific-heat maximum between Helium-I and Helium-II in 1930. In 1924 he became member of the Royal Netherlands Academy of Arts and Sciences The Royal Netherlands Academy of Arts and Sciences (, KNAW) is an organization dedicated to the advancement of science and literature in the Netherlands. The academy is housed in the Trippenhuis in Amsterdam. In addition to various advisory a .... In 1966, the minor planet '' 9686 Keesom'' was named ...
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