|
Phthalic Acid
In organic chemistry, phthalic acid is an aromatic dicarboxylic acid, with formula and structure . Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. Production Phthalic acid is produced by the catalytic oxidation of naphthalene or ''ortho-''xylene directly to phthalic anhydride and a subsequent hydrolysis of the anhydride. Phthalic acid was first obtained by French chemist Auguste Laurent in 1836 by oxidizing naphthalene tetrachloride. Believing the resulting substance to be a naphthalene derivative, he named it "naphthalic acid". After the Swiss chemist Jean Charles Galissard de Marignac determined its correct formula, Laurent gave it its present name. Manufacturing methods in the nineteenth century included oxidation of naphthalene tetrach ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terephthalic Acid
Terephthalic acid is an organic compound with formula C6H4(CO2H)2. This white solid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles. Several million tons are produced annually. The common name is derived from the turpentine-producing tree ''Pistacia terebinthus'' and phthalic acid. Terephthalic acid is also used in the production of PBT plastic (polybutylene terephthalate). History Terephthalic acid was first isolated (from turpentine) by the French chemist Amédée Cailliot (1805–1884) in 1846. Terephthalic acid became industrially important after World War II. Terephthalic acid was produced by oxidation of ''p''-xylene with 30-40% nitric acid. Air oxidation of ''p''-xylene gives ''p''-toluic acid, which resists further air-oxidation. Esterification of ''p''-toluic acid to methyl p-toluate (CH3C6H4CO2CH3) opens the way for further oxidation to monomethyl terephthalate. In the Dynamit−Nobel process t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carboxylic Acid
In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an Substituent, R-group. The general formula of a carboxylic acid is often written as or , sometimes as with R referring to an organyl group (e.g., alkyl, alkenyl, aryl), or hydrogen, or other groups. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion. Examples and nomenclature Carboxylic acids are commonly identified by their trivial names. They often have the suffix ''-ic acid''. IUPAC-recommended names also exist; in this system, carboxylic acids have an ''-oic acid'' suffix. For example, butyric acid () is butanoic acid by IUPAC guidelines. For nomenclature of complex molecules containing a carboxylic acid, the carboxyl can be considered position one of the parent chain even if there are other substituents, such as 3-chloropropanoic acid. Alternately, it can be named ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzenedicarboxylic Acid
Benzenedicarboxylic acid is a group of Chemical compound, chemical compounds which are Carboxy group, dicarboxylic Derivative (chemistry), derivatives of benzene. Benzenedicarboxylic acid comes in three Isomer, isomers: *Phthalic acid (1,2-benzenedicarboxylic acid) *Isophthalic acid (1,3-benzenedicarboxylic acid) *Terephthalic acid (1,4-benzenedicarboxylic acid) All isomers share the molecular weight 166.13 g/mol and the chemical formula C8H6O4. {{chemistry index Benzoic acids Dicarboxylic acids ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Permanganate
Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and ions to give an intensely pink to purple solution. Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also as a medication for dermatitis, for cleaning wounds, and general disinfection. It is commonly used as a biocide for water treatment purposes. It is on the World Health Organization's List of Essential Medicines. In 2000, worldwide production was estimated at 30,000 tons. Properties Potassium permanganate is the potassium salt of the tetrahedral transition metal oxo complex permanganate, in which four ligands are bound to a manganese(VII) center. Structure forms orthorhombic crystals with constants: ''a'' = 910.5 pm, ''b'' = 572.0 pm, ''c'' = 742.5 pm. The overall motif is similar to that for barium sulfate, with which it forms solid so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mercury(II) Sulfate
Mercury(II) sulfate, commonly called Mercury sulfate, mercuric sulfate, is the chemical compound Mercury (element), HgSulfur, SOxygen, O4. It is an odorless salt that forms white granules or crystalline powder. In water, it separates into an insoluble basic sulfate with a yellow color and sulfuric acid. Structure The anhydrous compound features Hg2+ in a highly distorted tetrahedral HgO4 environment. Two Hg-O distances are 2.22 Å and the others are 2.28 and 2.42 Å. In the monohydrate, Hg2+ adopts a linear coordination geometry with Hg-O (sulfate) and Hg-O (water) bond lengths of 2.179 and 2.228 Å, respectively. Four weaker bonds are also observed with Hg---O distances >2.5 Å. History In 1932, the Japanese chemical company Chisso Corporation began using mercury sulfate as the catalyst for the production of acetaldehyde from acetylene and water. Though it was unknown at the time, methylmercury is formed as a side product of this reaction. Exposure and consumption of the me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fuming Sulfuric Acid
Oleum (Latin ''oleum'', meaning oil), or fuming sulfuric acid, is a term referring to solutions of various compositions of sulfur trioxide in sulfuric acid, or sometimes more specifically to disulfuric acid (also known as pyrosulfuric acid). Oleums can be described by the formula ''y''SO3·H2O where ''y'' is the total molar mass of sulfur trioxide content. The value of ''y'' can be varied, to include different oleums. They can also be described by the formula H2SO4·''x''SO3 where ''x'' is now defined as the molar free sulfur trioxide content. Oleum is generally assessed according to the free SO3 content by mass. It can also be expressed as a percentage of sulfuric acid strength; for oleum concentrations, that would be over 100%. For example, 10% oleum can also be expressed as H2SO4·''0.13611''SO3, ''1.13611''SO3·H2O or 102.25% sulfuric acid. The conversion between % acid and % oleum is: :\%\,\text = 100 + \frac \times \%\,\text For ''x'' = 1 and ''y'' = 2 the empirical formula ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jean Charles Galissard De Marignac
Jean Charles Galissard de Marignac (24 April 1817 – 15 April 1894) was a Swiss chemist whose work with atomic weights suggested the possibility of isotopes and the packing fraction of nuclei. His study of the rare earth elements led to his discovery of ytterbium in 1878 and co-discovery of gadolinium in 1880. He was considered "one of the great chemists of the nineteenth century", particularly in the area of inorganic chemistry. On 13 September 2011, the site of his laboratory at the University of Geneva was designated a historical chemical landmark of Switzerland. Life and work Jean Charles Galissard de Marignac was born in Geneva on 24 April 1817, to Jacob Galissard de Marignac, a judge, and Susanne Le Royer, a sister of well-known chemist and physiologist Elie Le Royer. Le Royer's pharmacy was in the same building as their home. Marignac attended the École polytechnique in Paris with the intention of becoming a mining engineer. From 1837 to 1839, he studied ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Switzerland
Switzerland, officially the Swiss Confederation, is a landlocked country located in west-central Europe. It is bordered by Italy to the south, France to the west, Germany to the north, and Austria and Liechtenstein to the east. Switzerland is geographically divided among the Swiss Plateau, the Swiss Alps, Alps and the Jura Mountains, Jura; the Alps occupy the greater part of the territory, whereas most of the country's Demographics of Switzerland, 9 million people are concentrated on the plateau, which hosts List of cities in Switzerland, its largest cities and economic centres, including Zurich, Geneva, and Lausanne. Switzerland is a federal republic composed of Cantons of Switzerland, 26 cantons, with federal authorities based in Bern. It has four main linguistic and cultural regions: German, French, Italian and Romansh language, Romansh. Although most Swiss are German-speaking, national identity is fairly cohesive, being rooted in a common historical background, shared ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. The oxidation and reduction processes occur simultaneously in the chemical reaction. There are two classes of redox reactions: * Electron-transfer – Only one (usually) electron flows from the atom, ion, or molecule being oxidized to the atom, ion, or molecule that is reduced. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * Atom transfer – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously, the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Auguste Laurent
Auguste Laurent (14 November 1807 – 15 April 1853) was a French chemist who helped in the founding of organic chemistry with his discoveries of trichloroethylene, anthracene, phthalic acid, and carbolic acid. He devised a systematic nomenclature for organic chemistry based on structural grouping of atoms within molecules to determine how the molecules combine in organic reactions. He studied under Jean-Baptiste Dumas as a laboratory assistant. At that time, the weight of carbon was considered to be 6. Laurent thought that a weight of 12 was more logical, and started drawing structures on that basis. He published his work in conjunction with Charles Frédéric Gerhardt. Shunned by Dumas, he eked out a living teaching in the mineral engineering lab - where he taught a young Louis Pasteur how to crystalize tartaric acid. Laurent died in Paris from tuberculosis. Alexander Williamson in England read Laurent's writing, leading to the Williamson Ether Synthesis that confirmed t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of matter and its properties. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms. Chemists carefully measure substance proportions, chemical reaction rates, and other chemical properties. In Commonwealth English, pharmacists are often called chemists. Chemists use their knowledge to learn the composition and properties of unfamiliar substances, as well as to reproduce and synthesize large quantities of useful naturally occurring substances and create new artificial substances and useful processes. Chemists may specialize in any number of Chemistry#Subdisciplines, subdisciplines of chemistry. Materials science, Materials scientists and metallurgists sha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
