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Pesticide Toxicity To Bees
Pesticides vary in their effects on bees. Contact pesticides are usually sprayed on plants and can kill bees when they crawl over sprayed surfaces of plants or other areas around it. Systemic pesticides, on the other hand, are usually incorporated into the soil or onto seeds and move up into the stem, leaves, nectar, and pollen of plants. Of contact pesticides, dust and wettable powder pesticides tend to be more hazardous to bees than solutions or emulsifiable concentrates. When a bee comes in contact with pesticides while foraging, the bee may die immediately without returning to the hive. In this case, the queen bee, brood, and nurse bees are not contaminated and the colony survives. Alternatively, the bee may come into contact with an insecticide and transport it back to the colony in contaminated pollen or nectar or on its body, potentially causing widespread colony death. Actual damage to bee populations is a function of toxicity and exposure of the compound, in combination w ...
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Carbaryl
Carbaryl (1-naphthyl methylcarbamate) is a chemical in the carbamate family used chiefly as an insecticide. It is a white crystalline solid previously sold under the brand name Sevin, which was a trademark of the Bayer Company. Union Carbide discovered carbaryl and introduced it commercially in 1958. Bayer purchased Aventis CropScience in 2002, a company that included Union Carbide pesticide operations. Carbaryl was the third-most-used insecticide in the United States for home gardens, commercial agriculture, and forestry and rangeland protection. As a veterinary drug, it is known as carbaril ( INN). Production Carbaryl is often inexpensively produced by direct reaction of methyl isocyanate with 1-naphthol. :C10H7OH + CH3NCO → C10H7OC(O)NHCH3 Alternatively, 1-naphthol can be treated with excess phosgene to produce 1- naphthyl chloroformate, which is then converted to carbaryl by reaction with methylamine. The former process was used in the chemical plant that caused the ...
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European Union
The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The union has a total area of and an estimated population of over 449million as of 2024. The EU is often described as a ''sui generis'' political entity combining characteristics of both a federation and a confederation. Containing 5.5% of the world population in 2023, EU member states generated a nominal gross domestic product (GDP) of around €17.935 trillion in 2024, accounting for approximately one sixth of global economic output. Its cornerstone, the European Union Customs Union, Customs Union, paved the way to establishing European Single Market, an internal single market based on standardised European Union law, legal framework and legislation that applies in all member states in those matters, and only those matters, where the states ...
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Azinphos-methyl
Azinphos-methyl (Guthion) (also spelled azinophos-methyl) is a broad spectrum organophosphate insecticide manufactured by Bayer CropScience, Gowan Co., and Makhteshim Agan. Like other pesticides in this class, it owes its insecticidal properties (and human toxicity) to the fact that it is an acetylcholinesterase inhibitor (the same mechanism is responsible for the toxic effects of the V-series nerve agent chemical weapons). It is classified as an extremely hazardous substance in the United States as defined in Section 302 of the U.S. Emergency Planning and Community Right-to-Know Act (42 U.S.C. 11002), and is subject to strict reporting requirements by facilities which produce, store, or use it in significant quantities. History and uses Azinphos-methyl is a neurotoxin derived from nerve agents developed during World War II. It was first registered in the US in 1959 as an insecticide and is also used as active ingredient in organophosphate (OP) pesticides. It is not registered ...
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Organophosphate
In organic chemistry, organophosphates (also known as phosphate esters, or OPEs) are a class of organophosphorus compounds with the general structure , a central phosphate molecule with alkyl or aromatic substituents. They can be considered as esters of phosphoric acid. Organophosphates are best known for their use as pesticides. Like most functional groups, organophosphates occur in a diverse range of forms, with important examples including key biomolecules such as DNA, RNA and ATP, as well as many insecticides, herbicides, nerve agents and flame retardants. OPEs have been widely used in various products as flame retardants, plasticizers, and performance additives to engine oil. The low cost of production and compatibility to diverse polymers made OPEs to be widely used in industry including textile, furniture, electronics as plasticizers and flame retardants. These compounds are added to the final product physically rather than by chemical bond. Due to this, OPEs leak in ...
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Acephate
Acephate is an organophosphate foliar and soil insecticide of moderate persistence with residual systemic activity of about 10–15 days at the recommended use rate. It is used primarily for control of aphids, including resistant species, in vegetables (e.g. potatoes, carrots, greenhouse tomatoes, and lettuce) and in horticulture (e.g. on roses and greenhouse ornamentals). It also controls leaf miners, caterpillars, sawflies, thrips, and spider mites in the previously stated crops as well as turf, and forestry. By direct application to mounds, it is effective in destroying imported fire ants. Acephate is sold as a soluble powder, as emulsifiable concentrates, as pressurized aerosol, and in tree injection systems and granular formulations. As of 2012, the EPA no longer allows the usage of acephate on green beans grown in the United States. Toxicology It is considered non- phytotoxic on many crop plants. Acephate and its primary metabolite, methamidophos, are toxic to ''Heliothis ...
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Baygon
Baygon is a pesticide brand produced by S. C. Johnson & Son. It is an insecticide used for extermination and control of household pests such as crickets, roaches, ants, carpenter ants, spiders, silverfish and mosquitoes. In 1975, Baygon introduced Australia’s first surface spray for killing cockroaches, ticks and other crawling insects. Baygon was introduced by the German chemical manufacturer Bayer in 1967. In 2003, Bayer sold the brand to S. C. Johnson & Son. As part of the agreement, the active ingredients used in the pesticides are still manufactured by Bayer and supplied non-exclusively to SC Johnson. Composition Baygon products contain the pyrethroids cyfluthrin, transfluthrin, cypermethrin, prallethrin and the carbamate propoxur and organophosphorus chlorpyrifos, as active ingredients. In the concentrations used in consumer product insecticides, pyrethroids may also have insect repellent properties and are generally harmless to human beings in low doses but can har ...
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Propoxur
Propoxur (Baygon) is a carbamate non-systemic insecticide, produced from catechol, and was introduced in 1959. It has a fast knockdown and long residual effect, and is used against turf, forestry, and household pests and fleas. It is also used in pest control for domestic animals, ''Anopheles'' mosquitoes, ants, gypsy moths, and other agricultural pests.Budavari, 1996a It can also be used as a molluscicide.EXTOXNET Extension Toxicology Network. Pesticide Information Profile. Propoxur.
June 1996.
Several U.S. states have petitioned the US Environmental Protection Agency, Environmental Protection Agency (EPA) to use propoxur against Cimex, bedbug infestations, but the EPA has been reluctant to approve indoor use because of its potential toxicity to children after chronic expos ...
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Pirimicarb
Pirimicarb is a selective carbamate insecticide used to control aphids on vegetable, cereal and orchard crops by inhibiting acetylcholinesterase activity but does not affect useful predators such as ladybirds that eat them. It was originally developed by Imperial Chemical Industries Ltd., now Syngenta, at their Jealott's Hill Jealott's Hill is a village in the county of Berkshire, England, within the civil parish of Warfield. The settlement is on the A3095 road approximately north of Bracknell. The nearest railway station is in . History The name of the hill is re ... site and first marketed in 1969, four years after its discovery. References External links * Acetylcholinesterase inhibitors Carbamate insecticides Aminopyrimidines Aromatic carbamates Dimethylamino compounds {{alkanederivative-stub ...
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Mexacarbate
Mexacarbate is a carbamate pesticide developed by Alexander Shulgin and marketed in 1961 by Dow Chemical Company under the trade name Zectran. As of 2009, mexacarbate is considered obsolete or discontinued, according to the World Health Organization. It is notable for being the first biodegradable Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegrada ... pesticide. References Alexander Shulgin Carbamate insecticides Phenol esters {{Ether-stub ...
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Methiocarb
Methiocarb is a carbamate pesticide (an acetylcholinesterase inhibitor) which is used as an insecticide, bird repellent, acaricide and molluscicide since the 1960s. Methiocarb has contact and stomach action on mites and neurotoxic effects on molluscs. Seeds treated with methiocarb also affect birds. Other names for methiocarb are mesurol and mercaptodimethur. Due to its toxicity, methiocarb approval as a plant protection product has been withdrawn by the EU effective 2020. Structure and reactivity The carbamate functional group in methiocarb can be cleaved by cholinesterase to result in the carbamate, which binds to the cholinesterase, and the phenol. Synthesis Methiocarb (3) is synthesised by Bayer from 4-methylthio-3,5-xylenol (1) and methyl isocyanate (2). The xylenol (1) will act as the nucleophile in this reaction attacking the partially positively charged carbon in the isocyanate (2). Mechanism of action Methiocarb acts by acetylcholinesterase inhibition. The pro ...
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Methomyl
Methomyl is a carbamate insecticide introduced in 1966. It is highly toxic to humans, livestock, pets, and wildlife. The EU imposed a pesticide residue limit of 0,01 mg/kg for all fruit and vegetables. Methomyl is a common active ingredient in commercial fly bait, for which the label instructions in the United States warn that "It is a violation of Federal Law to use this product in a manner inconsistent with its labeling." "Off-label" uses and other uses not specifically targeted at problem insects are illegal, dangerous, and ill-advised. Use Methomyl is a broad-spectrum insecticide that is used to kill Economic entomology#Harmful insects, insect pests. Methomyl is registered for commercial/professional use under certain conditions on sites including field, vegetable, and orchard crops; turf (sod farms only); livestock quarters; commercial premises; and refuse containers. Products containing 1% Methomyl are available to the general public for retail sale, but more potent formu ...
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