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Pauli Equation
In quantum mechanics, the Pauli equation or Schrödinger–Pauli equation is the formulation of the Schrödinger equation for spin-1/2 particles, which takes into account the interaction of the particle's spin with an external electromagnetic field. It is the non- relativistic limit of the Dirac equation and can be used where particles are moving at speeds much less than the speed of light, so that relativistic effects can be neglected. It was formulated by Wolfgang Pauli in 1927. In its linearized form it is known as Lévy-Leblond equation. Equation For a particle of mass m and electric charge q, in an electromagnetic field described by the magnetic vector potential \mathbf and the electric scalar potential \phi, the Pauli equation reads: Here \boldsymbol = (\sigma_x, \sigma_y, \sigma_z) are the Pauli operators collected into a vector for convenience, and \mathbf = -i\hbar \nabla is the momentum operator in position representation. The state of the system, , \psi\ran ...
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Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ...
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Column Vector
In linear algebra, a column vector with elements is an m \times 1 matrix consisting of a single column of entries, for example, \boldsymbol = \begin x_1 \\ x_2 \\ \vdots \\ x_m \end. Similarly, a row vector is a 1 \times n matrix for some , consisting of a single row of entries, \boldsymbol a = \begin a_1 & a_2 & \dots & a_n \end. (Throughout this article, boldface is used for both row and column vectors.) The transpose (indicated by ) of any row vector is a column vector, and the transpose of any column vector is a row vector: \begin x_1 \; x_2 \; \dots \; x_m \end^ = \begin x_1 \\ x_2 \\ \vdots \\ x_m \end and \begin x_1 \\ x_2 \\ \vdots \\ x_m \end^ = \begin x_1 \; x_2 \; \dots \; x_m \end. The set of all row vectors with entries in a given field (such as the real numbers) forms an -dimensional vector space; similarly, the set of all column vectors with entries forms an -dimensional vector space. The space of row vectors with entries can be regarded as the dual sp ...
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Zeeman Effect
The Zeeman effect () is the splitting of a spectral line into several components in the presence of a static magnetic field. It is caused by the interaction of the magnetic field with the magnetic moment of the atomic electron associated with its Angular momentum, orbital motion and Spin (physics), spin; this interaction shifts some orbital energies more than others, resulting in the split spectrum. The effect is named after the Netherlands, Dutch physicist Pieter Zeeman, who discovered it in 1896 and received a Nobel Prize in Physics for this discovery. It is analogous to the Stark effect, the splitting of a spectral line into several components in the presence of an electric field. Also, similar to the Stark effect, transitions between different components have, in general, different intensities, with some being entirely forbidden (in the dipole approximation), as governed by the selection rules. Since the distance between the Zeeman sub-levels is a function of magnetic field ...
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G-factor (physics)
A ''g''-factor (also called ''g'' value) is a dimensionless quantity that characterizes the magnetic moment and angular momentum of an atom, a particle or the nucleus. It is the ratio of the magnetic moment (or, equivalently, the gyromagnetic ratio) of a particle to that expected of a classical particle of the same charge and angular momentum. In nuclear physics, the nuclear magneton replaces the classically expected magnetic moment (or gyromagnetic ratio) in the definition. The two definitions coincide for the proton. Definition Dirac particle The spin magnetic moment of a charged, spin-1/2 particle that does not possess any internal structure (a Dirac particle) is given by \boldsymbol \mu = g \mathbf S , where ''μ'' is the spin magnetic moment of the particle, ''g'' is the ''g''-factor of the particle, ''e'' is the elementary charge, ''m'' is the mass of the particle, and S is the spin angular momentum of the particle (with magnitude ''ħ''/2 for Dirac particles). B ...
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Angular Momentum
Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total angular momentum of a closed system remains constant. Angular momentum has both a direction (geometry), direction and a magnitude, and both are conserved. Bicycle and motorcycle dynamics, Bicycles and motorcycles, flying discs, Rifling, rifled bullets, and gyroscopes owe their useful properties to conservation of angular momentum. Conservation of angular momentum is also why hurricanes form spirals and neutron stars have high rotational rates. In general, conservation limits the possible motion of a system, but it does not uniquely determine it. The three-dimensional angular momentum for a point particle is classically represented as a pseudovector , the cross product of the particle's position vector (relative to some origin) and its mo ...
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Position Operator
In quantum mechanics, the position operator is the operator that corresponds to the position observable of a particle. When the position operator is considered with a wide enough domain (e.g. the space of tempered distributions), its eigenvalues are the possible position vectors of the particle. In one dimension, if by the symbol , x \rangle we denote the unitary eigenvector of the position operator corresponding to the eigenvalue x, then, , x \rangle represents the state of the particle in which we know with certainty to find the particle itself at position x. Therefore, denoting the position operator by the symbol X we can write X, x\rangle = x , x\rangle, for every real position x. One possible realization of the unitary state with position x is the Dirac delta (function) distribution centered at the position x, often denoted by \delta_x. In quantum mechanics, the ordered (continuous) family of all Dirac distributions, i.e. the family \delta = (\delta_x)_, is called ...
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Landau Quantization
In quantum mechanics, the energies of Cyclotron motion#Cyclotron resonance, cyclotron orbits of charged particles in a uniform magnetic field are quantized to discrete values, thus known as Landau levels. These levels are Degenerate energy level, degenerate, with the number of electrons per level directly proportional to the strength of the applied magnetic field. It is named after the Soviet physicist Lev Landau. Landau quantization contributes towards magnetic susceptibility of metals, known as Landau diamagnetism. Under strong magnetic fields, Landau quantization leads to oscillations in electronic properties of materials as a function of the applied magnetic field known as the De Haas–Van Alphen effect, De Haas–Van Alphen and Shubnikov–de Haas effects. Landau quantization is a key ingredient in explanation of the Quantum Hall effect, integer quantum Hall effect. Derivation Consider a system of non-interacting particles with charge and spin confined to an area in th ...
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Canonical Momentum
In mathematics and classical mechanics, canonical coordinates are sets of coordinates on phase space which can be used to describe a physical system at any given point in time. Canonical coordinates are used in the Hamiltonian formulation of classical mechanics. A closely related concept also appears in quantum mechanics; see the Stone–von Neumann theorem and canonical commutation relations for details. As Hamiltonian mechanics are generalized by symplectic geometry and canonical transformations are generalized by contact transformations, so the 19th century definition of canonical coordinates in classical mechanics may be generalized to a more abstract 20th century definition of coordinates on the cotangent bundle of a manifold (the mathematical notion of phase space). Definition in classical mechanics In classical mechanics, canonical coordinates are coordinates q^i and p_i in phase space that are used in the Hamiltonian formalism. The canonical coordinates satisfy the ...
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Kinetic Momentum
In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If is an object's mass and is its velocity (also a vector quantity), then the object's momentum (from Latin '' pellere'' "push, drive") is: \mathbf = m \mathbf. In the International System of Units (SI), the unit of measurement of momentum is the kilogram metre per second (kg⋅m/s), which is dimensionally equivalent to the newton-second. Newton's second law of motion states that the rate of change of a body's momentum is equal to the net force acting on it. Momentum depends on the frame of reference, but in any inertial frame of reference, it is a ''conserved'' quantity, meaning that if a closed system is not affected by external forces, its total momentum does not change. Momentum is also conserved in special relativity (with a modifi ...
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Minimal Coupling
In analytical mechanics and quantum field theory, minimal coupling refers to a coupling between fields which involves only the charge distribution and not higher multipole moments of the charge distribution. This minimal coupling is in contrast to, for example, Pauli coupling, which includes the magnetic moment of an electron directly in the Lagrangian. Electrodynamics In electrodynamics, minimal coupling is adequate to account for all electromagnetic interactions. Higher moments of particles are consequences of minimal coupling and non-zero spin. Non-relativistic charged particle in an electromagnetic field In Cartesian coordinates, the Lagrangian of a non-relativistic classical particle in an electromagnetic field is (in SI Units): : \mathcal = \sum_i \tfrac m \dot_i^2 + \sum_i q \dot_i A_i - q \varphi where is the electric charge of the particle, is the electric scalar potential, and the , , are the components of the magnetic vector potential that may all explicitly ...
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Momentum
In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If is an object's mass and is its velocity (also a vector quantity), then the object's momentum (from Latin '' pellere'' "push, drive") is: \mathbf = m \mathbf. In the International System of Units (SI), the unit of measurement of momentum is the kilogram metre per second (kg⋅m/s), which is dimensionally equivalent to the newton-second. Newton's second law of motion states that the rate of change of a body's momentum is equal to the net force acting on it. Momentum depends on the frame of reference, but in any inertial frame of reference, it is a ''conserved'' quantity, meaning that if a closed system is not affected by external forces, its total momentum does not change. Momentum is also conserved in special relativity (with a mo ...
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