Neptunium(IV) Oxalate
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Neptunium(IV) Oxalate
Neptunium (IV) oxalate is an inorganic compound, a salt of neptunium and oxalic acid with the chemical formula Np(CO). The compound is slightly soluble in water, forms crystalline hydrates—green crystals. Synthesis Neptunium(IV) oxalate is formed by the oxalic acid precipitation of neptunium (IV) solutions: :: Physical properties Neptunium(IV) oxalate forms a crystalline hydrate of the composition Np(C2O4)2 • 6H2O with green crystals. It is insoluble in acetone, and slightly soluble in water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv .... Chemical properties Neptunium(IV) oxalate decomposes on heating: ::\mathsf Applications Neptunium(IV) oxalate is used as an intermediate product in the purification of neptunium. References {{Oxalates Neptunium compounds Oxalates ...
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Thorium Oxalate
Thorium oxalate is the inorganic compound with the formula Th(C2O4)2(H2O)4. It is a white insoluble solid prepared by the reaction of thorium(IV) salts with oxalic acid. The material is a coordination polymer. Each Th(IV) center is bound to 10 oxygen centers: eight provided by the bridging oxalates and two by a pair of aquo ligand In chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant Chemical species, species in aqueous solutions of many metal Salt (chemistry), salts, such as meta ...s. Two additional waters of hydration are observed in the lattice. The solubility product (Ksp) of thorium oxalate is 5.0110−25.Taishi Kobayashi, Takayuki Sasaki, Ikuji Takagi, Hirotake Moriyama (2009''Solubility of Thorium(IV) in the Presence of Oxalic and Malonic Acids''Journal of Nuclear Science and Technology, Vol. 46, No. 11, p. 1085–1090 The density of anhydrous thorium oxalate is 4.637 g/cm3. R ...
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Springer Science & Business Media
Springer Science+Business Media, commonly known as Springer, is a German multinational publishing company of books, e-books and peer-reviewed journals in science, humanities, technical and medical (STM) publishing. Originally founded in 1842 in Berlin, it expanded internationally in the 1960s, and through mergers in the 1990s and a sale to venture capitalists it fused with Wolters Kluwer and eventually became part of Springer Nature in 2015. Springer has major offices in Berlin, Heidelberg, Dordrecht, and New York City. History Julius Springer founded Springer-Verlag in Berlin in 1842 and his son Ferdinand Springer grew it from a small firm of 4 employees into Germany's then second-largest academic publisher with 65 staff in 1872.Chronology
". Springer Science+Business Media.
In 1964, Springer expanded its business internationally, ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Neptunium
Neptunium is a chemical element; it has chemical symbol, symbol Np and atomic number 93. A radioactivity, radioactive actinide metal, neptunium is the first transuranic element. It is named after Neptune, the planet beyond Uranus in the Solar System, which uranium is named after. A neptunium atom has 93 protons and 93 electrons, of which seven are valence electrons. Neptunium metal is silvery and tarnishes when exposed to air. The element occurs in three allotrope, allotropic forms and it normally exhibits five oxidation states, ranging from +3 to +7. Like all actinides, it is Radioactive decay, radioactive, radiation poisoning, poisonous, pyrophoricity, pyrophoric, and capable of accumulating in bones, which makes the handling of neptunium dangerous. Although many false claims of its discovery were made over the years, the element was first synthesized by Edwin McMillan and Philip H. Abelson at the Berkeley Radiation Laboratory in 1940. Since then, most neptunium has been and still ...
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Oxalic Acid
Oxalic acid is an organic acid with the systematic name ethanedioic acid and chemical formula , also written as or or . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name is derived from early investigators who isolated oxalic acid from flowering plants of the genus '' Oxalis'', commonly known as wood-sorrels. It occurs naturally in many foods. Excessive ingestion of oxalic acid or prolonged skin contact can be dangerous. Oxalic acid is a much stronger acid than acetic acid. It is a reducing agent and its conjugate bases hydrogen oxalate () and oxalate () are chelating agents for metal cations. It is used as a cleaning agent, especially for the removal of rust, because it forms a water-soluble ferric iron complex, the ferrioxalate ion. Oxalic acid typically occurs as the dihydrate with the formula . History The preparation of salts of oxalic acid from plants had been known since at least 1745, when ...
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Springer-Verlag
Springer Science+Business Media, commonly known as Springer, is a German multinational publishing company of books, e-books and peer-reviewed journals in science, humanities, technical and medical (STM) publishing. Originally founded in 1842 in Berlin, it expanded internationally in the 1960s, and through mergers in the 1990s and a sale to venture capitalists it fused with Wolters Kluwer and eventually became part of Springer Nature in 2015. Springer has major offices in Berlin, Heidelberg, Dordrecht, and New York City. History Julius Springer founded Springer-Verlag in Berlin in 1842 and his son Ferdinand Springer grew it from a small firm of 4 employees into Germany's then second-largest academic publisher with 65 staff in 1872.Chronology
". Springer Science+Business Media.
In 1964, Springer expanded its business internationally, ...
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Acetone
Acetone (2-propanone or dimethyl ketone) is an organic compound with the chemical formula, formula . It is the simplest and smallest ketone (). It is a colorless, highly Volatile organic compound, volatile, and flammable liquid with a characteristic pungent odor. Acetone is miscibility, miscible with properties of water, water and serves as an important organic solvent in industry, home, and laboratory. About 6.7 million tonnes were produced worldwide in 2010, mainly for use as a solvent and for production of methyl methacrylate and bisphenol A, which are precursors to widely used plastics.Acetone
World Petrochemicals report, January 2010
Stylianos Sifniades, Alan B. Levy, "Acetone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. It is a common building block in organic chemistry. ...
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Water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy or organic micronutrients. Its chemical formula, , indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. In liquid form, is also called "water" at standard temperature and pressure. Because Earth's environment is relatively close to water's triple point, water exists on Earth as a solid, a liquid, and a gas. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice ...
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Savannah River Laboratory
The Savannah River National Laboratory (SRNL) is a multi-program national laboratory for the U.S. Department of Energy’s (DOE) Office of Environmental Management. SRNL is located at the Savannah River Site (SRS) near Jackson, South Carolina. It was founded in 1951, as the Savannah River Laboratory as a research, development and manufacturing center for tritium production from lithium. The intended end use of the tritium was in nuclear fusion weapons (such as hydrogen bomb), as well as in thermonuclear fusion reactors for civilian use. Plutonium production and research was a second main activity in the lab at that time. Since the end of the Cold War, the laboratory expanded its civilian research. Savannah River Laboratory was certified as a national laboratory on May 7, 2004. SRNL research topics include environmental remediation, technologies for the hydrogen economy, handling of hazardous materials and technologies for prevention of nuclear proliferation, vitrification of n ...
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Neptunium Compounds
Neptunium compounds are compounds containing the element neptunium (Np). Neptunium has five ionic oxidation states ranging from +3 to +7 when forming chemical compounds, which can be simultaneously observed in solutions. It is the heaviest actinide that can lose all its valence electrons in a stable compound. The most stable state in solution is +5, but the valence +4 is preferred in solid neptunium compounds. Neptunium metal is very reactive. Ions of neptunium are prone to hydrolysis and formation of coordination compounds. Solution chemistry When it is in an aqueous solution, neptunium can exist in any of its five possible oxidation states (+3 to +7) and each of these show a characteristic color.Np(II), (III) and (IV) have been observed, see The stability of each oxidation state is strongly dependent on various factors, such as the presence of oxidizing agent, oxidizing or reducing agents, pH of the solution, presence of coordination complex-forming ligands, and even the co ...
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