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Microbial Electrosynthesis
Microbial electrosynthesis (MES) is a form of microbial electrocatalysis in which electrons are supplied to living microorganisms via a cathode in an electrochemical cell by applying an electric current. The electrons are then used by the microorganisms to reduce carbon dioxide to yield industrially relevant products. The electric current would ideally be produced by a renewable source of power. This process is the opposite to that employed in a microbial fuel cell, in which microorganisms transfer electrons from the oxidation of compounds to an anode to generate an electric current. Comparison to microbial electrolysis cells Microbial electrosynthesis (MES) is related to microbial electrolysis cells (MEC). Both use the interactions of microorganisms with a cathode to reduce chemical compounds. In MECs, an electrical power source is used to augment the electrical potential produced by the microorganisms consuming a source of chemical energy such as acetic acid. The combined potenti ...
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Cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. Conventional current describes the direction in which positive charges move. Electrons, which are the carriers of current in most electrical systems, have a negative electrical charge, so the movement of electrons is ''opposite'' to that of the conventional current flow: this means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity ...
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Electrocatalysis
An electrocatalyst is a catalyst that participates in electrochemical reactions. Electrocatalysts are a specific form of catalysts that function at electrode surfaces or, most commonly, may be the electrode surface itself. An electrocatalyst can be heterogeneous such as a platinized electrode. Homogeneous electrocatalysts, which are soluble, assist in transferring electrons between the electrode and reactants, and/or facilitate an intermediate chemical transformation described by an overall half reaction. Major challenges in electrocatalysts focus on fuel cells. Background and theory An electrocatalyst lowers the activation energy required for an electrochemical reaction. Some electrocatalysts change the potential at which oxidation and reduction processes occur. In other cases, an electrocatalyst can impart selectivity by favoring specific chemical interaction at an electrode surface. Given that electrochemical reactions occur when electrons are passed from one chemical sp ...
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Biotechnology
Biotechnology is a multidisciplinary field that involves the integration of natural sciences and Engineering Science, engineering sciences in order to achieve the application of organisms and parts thereof for products and services. Specialists in the field are known as biotechnologists. The term ''biotechnology'' was first used by Károly Ereky in 1919 to refer to the production of products from raw materials with the aid of living organisms. The core principle of biotechnology involves harnessing biological systems and organisms, such as bacteria, yeast, and plants, to perform specific tasks or produce valuable substances. Biotechnology had a significant impact on many areas of society, from medicine to agriculture to environmental science. One of the key techniques used in biotechnology is genetic engineering, which allows scientists to modify the genetic makeup of organisms to achieve desired outcomes. This can involve inserting genes from one organism into another, and con ...
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Microbial Fuel Cell
Microbial fuel cell (MFC) is a type of bioelectrochemical fuel cell system also known as micro fuel cell that generates electric current by diverting electrons produced from the microbial oxidation of reduced compounds (also known as fuel or electron donor) on the anode to oxidized compounds such as oxygen (also known as oxidizing agent or electron acceptor) on the cathode through an external electrical circuit. MFCs produce electricity by using the electrons derived from biochemical reactions catalyzed by bacteria.MFCs can be grouped into two general categories: mediated and unmediated. The first MFCs, demonstrated in the early 20th century, used a mediator: a chemical that transfers electrons from the bacteria in the cell to the anode. Unmediated MFCs emerged in the 1970s; in this type of MFC the bacteria typically have electrochemically active redox proteins such as cytochromes on their outer membrane that can transfer electrons directly to the anode. In the 21st century MFC ...
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Glossary Of Fuel Cell Terms
The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few. A ; Activation loss : See overpotential ; Adsorption : Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a film of molecules or atoms (the adsorbate). ; Alkali : In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. ; Alkali anion exchange membrane : An alkali anion exchange membrane (AAEM) is a semipermeable membrane generally made from ionomers and designed to conduct anions while being impermeable to gases such as oxygen or hydrogen. ; Alkaline fuel cell : Alkaline fuel cell (AFC) also known as the Bacon fuel cell. ; Alloy : An alloy is a solid solution or homogeneous mix ...
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Electromethanogenesis
Electromethanogenesis is a form of electrofuel production where methane is produced by direct biological conversion of electrical current and carbon dioxide. Methane producing technologies garnered interest from the scientific community prior to 2000, but electromethanogenesis did not become a significant area of interest until 2008. Publications concerning catalytic methanation increased from 44 to over 130 between 2008 and 2017. Electromethanogenesis has drawn more research due to its proposed applications. The production of methane from electrical current may provide an approach to renewable energy storage. Electrical current produced from renewable energy sources may, through electromethanogenesis, be converted into methane which may then be used as a biofuel. It may also be a useful method for the capture of carbon dioxide which may be used for air purification. In nature, methane formation occurs biotically and abiotically. Abiogenic methane is produced on a smaller scale a ...
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Electrohydrogenesis
Electrohydrogenesis or biocatalyzed electrolysis is the name given to a process for generating hydrogen gas from organic matter being decomposition, decomposed by bacteria. This process uses a modified fuel cell to contain the organic matter and water. A small amount, 0.2–0.8 Volt, V of electricity is used, the original article reports an overall energy efficiency of 288% can be achieved (this is computed relative to the amount of electricity used, waste heat lowers the overall efficiency). This work was reported by Cheng and Logan. See also *Biohydrogen *Electrochemical reduction of carbon dioxide *Electromethanogenesis *Fermentative hydrogen production *Microbial fuel cell References External linksBiocatalyzed electrolysis
Hydrogen production Environmental engineering Biotechnology {{biology-stub ...
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Electrofuels
Electrofuels, also known as e-fuels, are a class of synthetic fuels which function as drop-in replacement fuels for internal combustion engines. They are manufactured using captured carbon dioxide or carbon monoxide, together with hydrogen obtained from water splitting. Electrolysis is possible with both traditional fossil fuel energy sources, as well as low-carbon electricity sources such as wind, solar and nuclear power. The process uses carbon dioxide in manufacturing and releases around the same amount of carbon dioxide into the air when the fuel is burned, for an overall low carbon footprint. Electrofuels are thus an option for reducing greenhouse gas emissions from transport, particularly for long-distance freight, marine, and air transport. The primary targets are methanol, and diesel, but include other alcohols and carbon-containing gases such as methane and butane. Characterization Electrofuels are hydrocarbons that are artificially synthesized from hydrogen and carb ...
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Speciality Chemicals
Specialty chemicals (also called specialties or effect chemicals) are particular chemical products that provide a wide variety of effects on which many other industry sectors rely. Some of the categories of speciality chemicals are adhesives, agrichemicals, Cleaning agent, cleaning materials, colors, Cosmetics ingredients, cosmetic additives, construction chemicals, elastomers, Flavoring, flavors, food additives, fragrances, industrial gases, lubricants, paints, polymers, surfactants, and textile auxiliaries. Other industrial sectors such as Automobile industry, automotive, Aerospace manufacturer, aerospace, Food manufacturing, food, cosmetics, agriculture, Manufacturing industry, manufacturing, and textiles are highly dependent on such products. Speciality chemicals are materials used on the basis of their performance or function. Consequently, in addition to "effect" chemicals they are sometimes referred to as "performance" chemicals or "formulation" chemicals. They can be unique ...
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Electric Current
An electric current is a flow of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is defined as the net rate of flow of electric charge through a surface. The moving particles are called charge carriers, which may be one of several types of particles, depending on the Electrical conductor, conductor. In electric circuits the charge carriers are often electrons moving through a wire. In semiconductors they can be electrons or Electron hole, holes. In an Electrolyte#Electrochemistry, electrolyte the charge carriers are ions, while in Plasma (physics), plasma, an Ionization, ionized gas, they are ions and electrons. In the International System of Units (SI), electric current is expressed in Unit of measurement, units of ampere (sometimes called an "amp", symbol A), which is equivalent to one coulomb per second. The ampere is an SI base unit and electric current is a ISQ base quantity, base quantity in the International System of Qua ...
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Hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the chemical formula, formula , called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas (dihydrogen) and in molecular forms, such as in water and organic compounds. The most common isotope of hydrogen (H) consists of one proton, one electron, and no neutrons. Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovere ...
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Hydrogen Ion
A hydrogen ion is created when a hydrogen atom loses or gains an electron. A positively charged hydrogen ion (or proton) can readily combine with other particles and therefore is only seen isolated when it is in a gaseous state or a nearly particle-free space. Due to its extremely high charge density of approximately 2×1010 times that of a sodium ion, the bare hydrogen ion cannot exist freely in solution as it readily hydrates, i.e., bonds quickly. The hydrogen ion is recommended by International Union of Pure and Applied Chemistry, IUPAC as a general term for all ions of hydrogen and its isotopes. Depending on the electric charge, charge of the ion, two different classes can be distinguished: positively charged ions (hydrons) and negatively charged (hydride) ions. Cation (positively charged) A hydrogen atom is made up of a nucleus with charge +1, and a single electron. Therefore, the only positively charged ion possible has charge +1. It is noted H+. Depending on the isoto ...
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