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Methyl Nitrate
Methyl nitrate is the methyl ester of nitric acid and has the chemical formula CH3NO3. It is a colourless explosive volatile liquid. Synthesis It can be produced by the condensation of nitric acid and methanol: :CH3OH + HNO3 → CH3NO3 + H2O A newer method uses methyl iodide and silver nitrate: : CH3I + AgNO3 → CH3NO3 + AgI Methyl nitrate can be produced on a laboratory or industrial scale either through the distillation of a mixture of methanol and nitric acid, or by the nitration of methanol by a mixture of sulfuric and nitric acids. The first procedure is not preferred due to the great explosion danger presented by the methyl nitrate vapour. The second procedure is essentially identical to that of making nitroglycerin. However, the process is usually run at a slightly higher temperature and the mixture is stirred mechanically on an industrial scale instead of with compressed air. Electrolytic production methods have been reported involving electrolyzing sodium acet ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ester
In chemistry, an ester is a compound derived from an acid (either organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group () of that acid is replaced by an organyl group (R). These compounds contain a distinctive functional group. Analogues derived from oxygen replaced by other chalcogens belong to the ester category as well. According to some authors, organyl derivatives of acidic hydrogen of other acids are esters as well (e.g. amides), but not according to the IUPAC. Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. Lactones are cyclic carboxylic esters; naturally occurring lactones are mainly 5- and 6-membered ring lactones. Lactones contribute to the aroma of fruits, butter, cheese, vegetables like celery and other foods. Esters can be formed from oxoacids (e.g. esters of acetic acid, carbonic acid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds about 1 km/sec and differ from deflagrations which have subsonic flame speeds about 1 m/sec. Detonation may form from an explosion of fuel-oxidizer mixture. Compared with deflagration, detonation doesn't need to have an external oxidizer. Oxidizers and fuel mix when deflagration occurs. Detonation is more destructive than deflagrations. In detonation, the flame front travels through the air-fuel faster than sound; while in deflagration, the flame front travels through the air-fuel slower than sound. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. TNT, dynamite, and C4 are examples of high power explosives that detonate. The detonation velocity, velocity of detonation in solid an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gas Electron Diffraction
Gas electron diffraction (GED) is one of the applications of electron diffraction techniques. The target of this method is the determination of the structure of gaseous molecules, i.e., the geometrical arrangement of the atoms from which a molecule is built up. GED is one of two experimental methods (besides microwave spectroscopy) to determine the structure of free molecules, undistorted by intermolecular forces, which are omnipresent in the solid and liquid state. The determination of accurate molecular structures by GED studies is fundamental for an understanding of structural chemistry. Introduction Diffraction occurs because the wavelength of electrons accelerated by a potential of a few thousand volts is of the same order of magnitude as internuclear distances in molecules. The principle is the same as that of other electron diffraction methods such as LEED and RHEED, but the obtainable diffraction pattern is considerably weaker than those of LEED and RHEED because the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Early New High German
Early New High German (ENHG) is a term for the period in the history of the German language generally defined, following Wilhelm Scherer, as the period 1350 to 1650, developing from Middle High German and into New High German. The term is the standard translation of the German (Frnhd., Fnhd.), introduced by Scherer. The term ''Early Modern High German'' is also occasionally used for this period (but the abbreviation EMHG is generally used for '' Early Middle High German''). Periodisation The start and end dates of ENHG are, like all linguistic periodisations, somewhat arbitrary. In spite of many alternative suggestions, Scherer's dates still command widespread acceptance. Linguistically, the mid-14th century is marked by the phonological changes to the vowel system that characterise the modern standard language; the mid-17th sees the loss of status for regional forms of language, and the triumph of German over Latin as the dominant, and then sole, language for public discour ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Augsburg
Augsburg ( , ; ; ) is a city in the Bavaria, Bavarian part of Swabia, Germany, around west of the Bavarian capital Munich. It is a College town, university town and the regional seat of the Swabia (administrative region), Swabia with a well preserved Altstadt (historical city centre). Augsburg is an Urban districts of Germany, urban district and home to the institutions of the Augsburg (district), Landkreis Augsburg. It is the List of cities in Bavaria by population, third-largest city in Bavaria (after Munich and Nuremberg), with a population of 304,000 and 885,000 in its metropolitan area. After Neuss, Trier, Worms, Germany, Worms, Cologne and Xanten, Augsburg is one of Germany's oldest cities, founded in 15 BC by the Romans as Augsburg#Early history, Augusta Vindelicorum and named after the Roman emperor Augustus. It was a Free Imperial City from 1276 to 1803 and the home of the patrician (post-Roman Europe), patrician Fugger and Welser families that dominated European ban ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dresden
Dresden (; ; Upper Saxon German, Upper Saxon: ''Dräsdn''; , ) is the capital city of the States of Germany, German state of Saxony and its second most populous city after Leipzig. It is the List of cities in Germany by population, 12th most populous city of Germany, the fourth largest by area (after Berlin, Hamburg, and Cologne), and the third-most populous city in the area of former East Germany, after Berlin and Leipzig. Dresden's urban area comprises the towns of Freital, Pirna, Radebeul, Meissen, Coswig, Saxony, Coswig, Radeberg, and Heidenau and has around 790,000 inhabitants. The Dresden metropolitan area has approximately 1.34 million inhabitants. Dresden is the second largest city on the River Elbe after Hamburg. Most of the city's population lives in the Dresden Basin, Elbe Valley, but a large, albeit very sparsely populated, area of the city east of the Elbe lies in the West Lusatian Hill Country and Uplands (the westernmost part of the Sudetes) and thus in Lusatia. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
German Language
German (, ) is a West Germanic language in the Indo-European language family, mainly spoken in Western Europe, Western and Central Europe. It is the majority and Official language, official (or co-official) language in Germany, Austria, Switzerland, and Liechtenstein. It is also an official language of Luxembourg, German-speaking Community of Belgium, Belgium and the Italian autonomous province of South Tyrol, as well as a recognized national language in Namibia. There are also notable German-speaking communities in other parts of Europe, including: Poland (Upper Silesia), the Czech Republic (North Bohemia), Denmark (South Jutland County, North Schleswig), Slovakia (Krahule), Germans of Romania, Romania, Hungary (Sopron), and France (European Collectivity of Alsace, Alsace). Overseas, sizeable communities of German-speakers are found in the Americas. German is one of the global language system, major languages of the world, with nearly 80 million native speakers and over 130 mi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reichstag Fire
The Reichstag fire (, ) was an arson attack on the Reichstag building, home of the German parliament in Berlin, on Monday, 27 February 1933, precisely four weeks after Adolf Hitler was sworn in as Chancellor of Germany. Marinus van der Lubbe, a Dutch council communist, was the culprit; the Nazis attributed the fire to a group of Communist agitators, used it as a pretext to claim that Communists were plotting against the German government, and induced President Paul von Hindenburg to issue the Reichstag Fire Decree suspending civil liberties and pursue a "ruthless confrontation" with the Communists. This made the fire pivotal in the establishment of Nazi Germany. The first report of the fire came shortly after 9:00p.m., when a Berlin fire station received an alarm call. By the time police and firefighters arrived, the structure was engulfed in flames. The police conducted a thorough search inside the building and found Van der Lubbe, who was arrested. After the Fire Decree ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
De Gruyter
Walter de Gruyter GmbH, known as De Gruyter (), is a German scholarly publishing house specializing in academic literature. History The roots of the company go back to 1749 when Frederick the Great granted the Königliche Realschule in Berlin the royal privilege to open a bookstore and "to publish good and useful books". In 1800, the store was taken over by Georg Reimer (1776–1842), operating as the ''Reimer'sche Buchhandlung'' from 1817, while the school's press eventually became the ''Georg Reimer Verlag''. From 1816, Reimer used a representative palace at Wilhelmstraße 73 in Berlin for his family and the publishing house, whereby the wings contained his print shop and press. The building later served as the Palace of the Reich President. Born in Ruhrort in 1862, Walter de Gruyter took a position with Reimer Verlag in 1894. By 1897, at the age of 35, he had become sole proprietor of the hundred-year-old company then known for publishing the works of German romantic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Evaporation
Evaporation is a type of vaporization that occurs on the Interface (chemistry), surface of a liquid as it changes into the gas phase. A high concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. When the molecules of the liquid collide, they transfer energy to each other based on how they collide. When a molecule near the surface absorbs enough energy to overcome the vapor pressure, it will escape and enter the surrounding air as a gas. When evaporation occurs, the energy removed from the vaporized liquid will reduce the temperature of the liquid, resulting in evaporative cooling. On average, only a fraction of the molecules in a liquid have enough heat energy to escape from the liquid. The evaporation will continue until an equilibrium is reached when the evaporation of the liquid is equal to its condensation. In an enclosed environment, a liquid will evaporate unt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
World War II
World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the world's countries participated, with many nations mobilising all resources in pursuit of total war. Tanks in World War II, Tanks and Air warfare of World War II, aircraft played major roles, enabling the strategic bombing of cities and delivery of the Atomic bombings of Hiroshima and Nagasaki, first and only nuclear weapons ever used in war. World War II is the List of wars by death toll, deadliest conflict in history, causing World War II casualties, the death of 70 to 85 million people, more than half of whom were civilians. Millions died in genocides, including the Holocaust, and by massacres, starvation, and disease. After the Allied victory, Allied-occupied Germany, Germany, Allied-occupied Austria, Austria, Occupation of Japan, Japan, a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nazi Germany
Nazi Germany, officially known as the German Reich and later the Greater German Reich, was the German Reich, German state between 1933 and 1945, when Adolf Hitler and the Nazi Party controlled the country, transforming it into a Totalitarianism, totalitarian dictatorship. The Third Reich, meaning "Third Realm" or "Third Empire", referred to the Nazi claim that Nazi Germany was the successor to the earlier Holy Roman Empire (800–1806) and German Empire (1871–1918). The Third Reich, which the Nazis referred to as the Thousand-Year Reich, ended in May 1945, after 12 years, when the Allies of World War II, Allies defeated Germany and entered the capital, Berlin, End of World War II in Europe, ending World War II in Europe. After Hitler was appointed Chancellor of Germany in 1933, the Nazi Party began to eliminate political opposition and consolidate power. A 1934 German referendum confirmed Hitler as sole ''Führer'' (leader). Power was centralised in Hitler's person, an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
