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Iodine Monoxide
Iodine monoxide is a binary inorganic compound of iodine and oxygen with the chemical formula IO•. A free radical, this compound is the simplest of many iodine oxides. It is similar to the oxygen monofluoride, chlorine monoxide and bromine monoxide radicals. Synthesis Iodine monoxide can be obtained by the reaction between iodine and oxygen: : Chemical properties Iodine monoxide decomposes to its prime elements: : Iodine monoxide reacts with nitric oxide: : Atmosphere Atmospheric iodine atoms (e.g. from iodomethane) can react with ozone to produce the iodine monoxide radical: : This process can contribute to ozone depletion Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar .... References {{Iodine compounds Iodine compounds Diatomic molecules Oxides Free radicals ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Institute Of Problems Of Chemical Physics
The Institute of Problems of Chemical Physics (IPCP)See the web sitInstitute of Problems of Chemical Physics RAS () of the Russian Academy of Sciences (RAS) consists of 10 scientific departments and about 100 laboratories each one held by an independent research groups. IPCP was established in 1956 as branch of the Moscow ''Institute of Chemical Physics.'' See also *Mathematical chemistry *Aizik Isaakovich Vol'pert Notes References *. "''The Institute of Chemical Physics. Historical essays''" (English translation of the title) is an historical book on the Institute of Problems of Chemical Physics, written by Fedor Ivanovich Dubovitskii, one of his founders and leading directors for many years. It gives many useful details on the lives and the achievements of many scientists who worked there, including Aizik Isaakovich Vol'pert. *. "''Institute of Problems of Chemical Physics. Fifty years in the trenches''" (English translation of the title) is a brief historical sketch of ...
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Diatomic Molecules
Diatomic molecules () are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen () or oxygen (), then it is said to be homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide () or nitric oxide (), the molecule is said to be heteronuclear. The bond in a homonuclear diatomic molecule is non-polar. The only chemical elements that form stable homonuclear diatomic molecules at standard temperature and pressure (STP) (or at typical laboratory conditions of 1 bar and 25 °C) are the gases hydrogen (), nitrogen (), oxygen (), fluorine (), and chlorine (), and the liquid bromine (). The noble gases (helium, neon, argon, krypton, xenon, and radon) are also gases at STP, but they are monatomic. The homonuclear diatomic gases and noble gases together are called "elemental gases" or "molecular gases", to distinguish them from ...
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Iodine Compounds
Iodine compounds are compounds containing the element iodine. Iodine can form compounds using multiple oxidation states. Iodine is quite reactive, but it is much less reactive than the other halogens. For example, while chlorine gas will halogenate carbon monoxide, nitric oxide, and sulfur dioxide (to phosgene, nitrosyl chloride, and sulfuryl chloride respectively), iodine will not do so. Furthermore, iodination of metals tends to result in lower oxidation states than chlorination or bromination; for example, rhenium metal reacts with chlorine to form rhenium hexachloride, but with bromine it forms only rhenium pentabromide and iodine can achieve only rhenium tetraiodide.Greenwood and Earnshaw, pp. 800–4 By the same token, however, since iodine has the lowest ionisation energy among the halogens and is the most easily oxidised of them, it has a more significant cationic chemistry and its higher oxidation states are rather more stable than those of bromine and chlorine, for exampl ...
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Ozone Depletion
Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar regions. The latter phenomenon is referred to as the #Ozone hole and its causes, ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events. The main causes of ozone depletion and the ozone hole are manufactured chemicals, especially manufactured halocarbon refrigerants, solvents, propellants, and foam-blowing agents (chlorofluorocarbons (CFCs), HCFCs, Haloalkanes, halons), referred to as ''ozone-depleting substances'' (ODS). These compounds are transported into the stratosphere by Turbulence, turbulent mixing after being emitted from the surface, mixing much faster than the molecules can settle. Once in the stratosphere, they release atoms from the halogen group through photod ...
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Ozone
Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lower atmosphere to (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the atmosphere, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation. Ozone's odor is reminiscent of chlorine, and detectable by many people at concentrations of as little as in air. Ozone's O3 chemical structure, structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetism, diamagnetic. At standard temperature and pressure, ozone is a pale blue gas that condenses at cryogenic ...
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Iodomethane
Iodomethane, also called methyl iodide, and commonly abbreviated "MeI", is the chemical compound with the formula CH3I. It is a dense, colorless, volatile liquid. In terms of chemical structure, it is related to methane by replacement of one hydrogen atom by an atom of iodine. It is naturally emitted in small amounts by rice plantations. It is also produced in vast quantities estimated to be greater than 214,000 tons annually by algae and kelp in the world's temperate oceans, and in lesser amounts on land by terrestrial fungi and bacteria. It is used in organic synthesis as a source of methyl groups. Preparation and handling Iodomethane is formed via the exothermic reaction that occurs when iodine is added to a mixture of methanol with red phosphorus. The iodinating reagent is phosphorus triiodide that is formed ''in situ:'' :3 CH3OH + PI3 → 3 CH3I + H2PO3H Alternatively, it is prepared from the reaction of dimethyl sulfate with potassium iodide in the presence of c ...
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Russian Academy Of Sciences
The Russian Academy of Sciences (RAS; ''Rossíyskaya akadémiya naúk'') consists of the national academy of Russia; a network of scientific research institutes from across the Russian Federation; and additional scientific and social units such as libraries, publishing units, and hospitals. Peter the Great established the academy (then the St. Petersburg Academy of Sciences) in 1724 with guidance from Gottfried Wilhelm Leibniz, Gottfried Leibniz. From its establishment, the academy benefitted from a slate of foreign scholars as professors; the academy then gained its first clear set of goals from the 1747 Charter. The academy functioned as a university and research center throughout the mid-18th century until the university was dissolved, leaving research as the main pillar of the institution. The rest of the 18th century continuing on through the 19th century consisted of many published academic works from Academy scholars and a few Academy name changes, ending as The Imperial ...
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Bromine Monoxide Radical
Bromine monoxide is a binary inorganic compound of bromine and oxygen with the chemical formula BrO. A free radical, this compound is the simplest of many bromine oxides. The compound is capable of influencing atmospheric chemical processes. Naturally, BrO can be found in volcanic plumes. BrO is similar to the oxygen monofluoride, chlorine monoxide and iodine monoxide radicals. Chemical properties The compound is very effective as a catalyst of the ozone destruction. The chemical reaction of BrO and chlorine dioxide (OClO) results in ozone depletion Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar ... in the stratosphere. References {{Bromine compounds Bromine compounds Diatomic molecules Oxides Free radicals ...
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Iodine
Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a violet gas at . The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek , meaning 'violet'. Iodine occurs in many oxidation states, including iodide (I−), iodate (), and the various periodate anions. As the heaviest essential mineral nutrient, iodine is required for the synthesis of thyroid hormones. Iodine deficiency affects about two billion people and is the leading preventable cause of intellectual disabilities. The dominant producers of iodine today are Chile and Japan. Due to its high atomic number and ease of attachment to organic compounds, it has also found favour as a non-toxic radiocontrast material. Because of the spec ...
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Chlorine Monoxide
Chlorine monoxide is a chemical radical with the chemical formula ClO•. It plays an important role in the process of ozone depletion. In the stratosphere, chlorine atoms react with ozone molecules to form chlorine monoxide and oxygen. :Cl• + O3 → ClO• + O2 This reaction causes the depletion of the ozone layer. The resulting ClO• radicals can further react: : ClO• + O• → Cl• + O2 regenerating the chlorine radical. In this way, the overall reaction for the decomposition of ozone is catalyzed by chlorine, as ultimately chlorine remains unchanged. The overall reaction is: :O• + O3 → 2 O2 There has been a significant impact of the use of CFCs on the upper stratosphere, although many countries have agreed to ban the use of CFCs. The nonreactive nature of CFCs allows them to pass into the stratosphere, where they undergo photo-dissociation to form Cl radicals. These then readily form chlorine monoxide, and this cycle can continue until two radicals react to f ...
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Oxygen Monofluoride
Oxygen monofluoride is an unstable binary inorganic compound radical of fluorine and oxygen with the chemical formula OF. This is the simplest of many oxygen fluorides. Synthesis *OF is a radical that can be formed by thermal of photolytic decomposition of . : *A reaction of fluorine and ozone: : Atmosphere Oxygen- and fluorine-containing radicals like and OF occur in the atmosphere. These, along with other halogen radicals, have been implicated in the destruction of ozone in the atmosphere. However, the oxygen monofluoride radicals are assumed to not play as big a role in the ozone depletion because free fluorine atoms in the atmosphere are believed to react with methane to produce hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ... which precipitates in rain ...
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