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Herbert S. Gutowsky
Herbert Sander Gutowsky (November 8, 1919 – January 13, 2000) was an American chemist who was a professor of chemistry at the University of Illinois Urbana-Champaign. Gutowsky was the first to apply nuclear magnetic resonance (NMR) methods to the field of chemistry. He used nuclear magnetic resonance spectroscopy to determine the structure of molecules. His pioneering work developed experimental control of NMR as a scientific instrument, connected experimental observations with theoretical models, and made NMR one of the most effective analytical tools for analysis of molecular structure and dynamics in liquids, solids, and gases, used in chemical and medical research, His work was relevant to the solving of problems in chemistry, biochemistry, and materials science, and has influenced many of the subfields of more recent NMR spectroscopy. Birth and education Herbert Sander Gutowsky was born on November 8, 1919, one of seven children of Otto and Hattie Meyer Gutowsky of Br ...
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Bridgman, Michigan
Bridgman is a city in Berrien County in the U.S. state of Michigan. The population was 2,096 at the time of the 2020 census. History There was a place in this area known as Plummer's Pier. In 1856 lumbermen founded Charlotteville in this area. Bridgman itself begins with the village of that name platted by George C. Bridgman in 1870. It was centered on a railroad station opened that year. The Bridgman post office, with ZIP code 49106 opened with the name "Laketon" on November 11, 1862. The name changed to Bridgman on April 9, 1874. Bridgman later expanded by annexing the area that had previously been Charlotteville. The town is famous for being the location of the 1922 Bridgman Convention, a clandestine communist planning meeting in 1922 that was broken up by Federal Bureau of Investigation agents and local authorities. Geography According to the United States Census Bureau, the city has a total area of , of which is land and is water. Demographics 2010 census As of th ...
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Kenneth Pitzer
Kenneth Sanborn Pitzer (January 6, 1914 – December 26, 1997) was an American physical and theoretical chemist, educator, and university president. He was described as "one of the most influential physical chemists of his era" whose work "spanned almost all of the important fields of physical chemistry: thermodynamics, statistical mechanics, molecular structure, quantum mechanics, spectroscopy, chemical bonding, relativistic chemical effects, properties of concentrated aqueous salt solutions, kinetics, and conformational analysis." Biography Pitzer received his B.S. in 1935 from the California Institute of Technology and his Ph.D. from the University of California, Berkeley in 1937. Upon graduation, he was appointed to the faculty of UC Berkeley's chemistry department and was eventually promoted to professor. From 1951 to 1960, he served as dean of the College of Chemistry. Pitzer was the third president of Rice University from 1961 until 1968 and sixth president of Stanfo ...
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Fourier Transform Microwave Spectroscopy
Fourier may refer to: * Fourier (surname), French surname Mathematics *Fourier series, a weighted sum of sinusoids having a common period, the result of Fourier analysis of a periodic function *Fourier analysis, the description of functions as sums of sinusoids *Fourier transform, the type of linear canonical transform that is the generalization of the Fourier series *Fourier operator, the kernel of the Fredholm integral of the first kind that defines the continuous Fourier transform *Fourier inversion theorem, any one of several theorems by which Fourier inversion recovers a function from its Fourier transform *Short-time Fourier transform or short-term Fourier transform (STFT), a Fourier transform during a short term of time, used in the area of signal analysis *Fractional Fourier transform (FRFT), a linear transformation generalizing the Fourier transform, used in the area of harmonic analysis *Discrete-time Fourier transform (DTFT), the reverse of the Fourier series, a special ...
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American Physical Society
The American Physical Society (APS) is a not-for-profit membership organization of professionals in physics and related disciplines, comprising nearly fifty divisions, sections, and other units. Its mission is the advancement and diffusion of knowledge of physics. It publishes more than a dozen scientific journals, including the prestigious '' Physical Review'' and ''Physical Review Letters'', and organizes more than twenty science meetings each year. It is a member society of the American Institute of Physics. Since January 2021, it is led by chief executive officer Jonathan Bagger. History The American Physical Society was founded on May 20, 1899, when thirty-six physicists gathered at Columbia University for that purpose. They proclaimed the mission of the new Society to be "to advance and diffuse the knowledge of physics", and in one way or another the APS has been at that task ever since. In the early years, virtually the sole activity of the APS was to hold scientific m ...
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Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fie ...
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Radio Frequency
Radio frequency (RF) is the oscillation rate of an alternating electric current or voltage or of a magnetic, electric or electromagnetic field or mechanical system in the frequency range from around to around . This is roughly between the upper limit of audio frequencies that humans can hear (though these are not electromagnetic) and the lower limit of infrared frequencies, and also encompasses the microwave range. These are the frequencies at which energy from an oscillating current can radiate off a conductor into space as radio waves, so they are used in radio technology, among other uses. Different sources specify different upper and lower bounds for the frequency range. Electric current Electric currents that oscillate at radio frequencies (RF currents) have special properties not shared by direct current or lower audio frequency alternating current, such as the 50 or 60 Hz current used in electrical power distribution. * Energy from RF currents in conduct ...
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Infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those of red light (the longest waves in the visible spectrum), so IR is invisible to the human eye. IR is generally (according to ISO, CIE) understood to include wavelengths from around to . IR is commonly divided between longer-wavelength thermal IR, emitted from terrestrial sources, and shorter-wavelength IR or near-IR, part of the solar spectrum. Longer IR wavelengths (30–100 μm) are sometimes included as part of the terahertz radiation band. Almost all black-body radiation from objects near room temperature is in the IR band. As a form of EMR, IR carries energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon. It was long known that fires e ...
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Solid-state Physics
Solid-state physics is the study of rigid matter, or solids, through methods such as solid-state chemistry, quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the large-scale properties of solid materials result from their atomic-scale properties. Thus, solid-state physics forms a theoretical basis of materials science. Along with solid-state chemistry, it also has direct applications in the technology of transistors and semiconductors. Background Solid materials are formed from densely packed atoms, which interact intensely. These interactions produce the mechanical (e.g. hardness and Elasticity (physics), elasticity), Heat conduction, thermal, Electrical conduction, electrical, Magnetism, magnetic and Crystal optics, optical properties of solids. Depending on the material involved and the conditions in which it was formed, the atoms may be arranged in a regular, geometric patt ...
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Molecular Structure
Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom. Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. The angles between bonds that an atom forms depend only weakly on the rest of a molecule, i.e. they can be understood as approximately local and hence transferable properties. Determination The molecular geometry can be determined by various spectroscopic methods and diffraction methods. IR, microwave and Raman spectroscopy can give information about the molecule geometry from the details of the vibrational and rotational absorbance detected by these techniques. X-ray crystallography, neutron diffraction and electron diffraction can ...
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George Pake
George E. Pake (April 1, 1924 – March 4, 2004) was a physicist, academic, and research executive primarily known for helping found Xerox PARC. Early life Pake was raised in Kent, Ohio. His father was an English instructor at Kent State University. His mother was a schoolteacher. Pake was exempted from service in the U.S. Armed Forces during World War II due to scoliosis. He earned bachelor's and master's degrees from the Carnegie Institute of Technology and his doctorate in physics at Harvard University in 1948. Career Much of his early research at Harvard University focused on the topic of nuclear magnetic resonance (NMR) spectroscopy. There, he discovered the multiplet structure produced by the dipolar coupling of two nuclear spins. In his honor, this multiplet is now known as the Pake doublet and forms the basis for NMR-based inter-atomic distance measurements and molecular structure determination. After four years as a physics professor at Washington Univ ...
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Nuclear Magnetic Moment
The nuclear magnetic moment is the magnetic moment of an atomic nucleus and arises from the spin of the protons and neutrons. It is mainly a magnetic dipole moment; the quadrupole moment does cause some small shifts in the hyperfine structure as well. All nuclei that have nonzero spin also have a nonzero magnetic moment and vice versa, although the connection between the two quantities is not straightforward or easy to calculate. The nuclear magnetic moment varies from isotope to isotope of an element. For a nucleus of which the numbers of protons and of neutrons are ''both'' even in its ground state (i.e. lowest energy state), the nuclear spin and magnetic moment are both always zero. In cases with odd numbers of either or both protons and neutrons, the nucleus often has nonzero spin and magnetic moment. The nuclear magnetic moment is not sum of nucleon magnetic moments, this property being assigned to the tensorial character of the nuclear force, such as in the case of the ...
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Nuclear Physics
Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies the atom as a whole, including its electrons. Discoveries in nuclear physics have led to applications in many fields such as nuclear power, nuclear weapons, nuclear medicine and magnetic resonance imaging, industrial and agricultural isotopes, ion implantation in materials engineering, and radiocarbon dating in geology and archaeology. Such applications are studied in the field of nuclear engineering. Particle physics evolved out of nuclear physics and the two fields are typically taught in close association. Nuclear astrophysics, the application of nuclear physics to astrophysics, is crucial in explaining the inner workings of stars and the origin of the chemical elements. History The history of nuclear physics as a discipline ...
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