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Helium-3 Surface Spin Echo
Helium-3 surface spin echo (HeSE) is an inelastic scattering technique in surface science that has been used to measure microscopic dynamics at well-defined surfaces in ultra-high vacuum. The information available from HeSE complements and extends that available from other inelastic scattering techniques such as neutron spin echo and traditional helium-4 atom scattering (HAS). Principles The experimental principles of the HeSE experiment are analogous to those of neutron spin echo, differing in details such as the nature of the probe/sample interactions that give rise to scattering. In outline, a polarized 3He beam is created by a supersonic expansion followed by a spin-filtering stage (polariser). The helium scatters from the experimental sample and is detected at the end of the beamline after another spin-filtering stage (analyser). Before and after the scattering process, the beam passes through magnetic fields that precess the probe spins in the usual sense of a spin echo ex ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helium-3
Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is the only stable isotope of any element with more protons than neutrons. Helium-3 was discovered in 1939. Helium-3 occurs as a primordial nuclide, escaping from Earth's crust into its atmosphere and into outer space over millions of years. Helium-3 is also thought to be a natural nucleogenic and cosmogenic nuclide, one produced when lithium is bombarded by natural neutrons, which can be released by spontaneous fission and by nuclear reactions with cosmic rays. Some of the helium-3 found in the terrestrial atmosphere is also an artifact of atmospheric and underwater nuclear weapons testing. Much speculation has been made over the possibility of helium-3 as a future energy source. Unlike most nuclear fusion reactions, the fusion of heli ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Science
Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid– gas interfaces, solid– vacuum interfaces, and liquid– gas interfaces. It includes the fields of '' surface chemistry'' and ''surface physics''. Some related practical applications are classed as surface engineering. The science encompasses concepts such as heterogeneous catalysis, semiconductor device fabrication, fuel cells, self-assembled monolayers, and adhesives. Surface science is closely related to interface and colloid science. Interfacial chemistry and physics are common subjects for both. The methods are different. In addition, interface and colloid science studies macroscopic phenomena that occur in heterogeneous systems due to peculiarities of interfaces. History The field of surface chemistry started with heterogeneous catalysis pioneered by Paul Sabatier on hydrogenation and Fritz Haber on the Ha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ultra-high Vacuum
Ultra-high vacuum (UHV) is the vacuum regime characterised by pressures lower than about . UHV conditions are created by pumping the gas out of a UHV chamber. At these low pressures the mean free path of a gas molecule is greater than approximately 40 km, so the gas is in free molecular flow, and gas molecules will collide with the chamber walls many times before colliding with each other. Almost all molecular interactions therefore take place on various surfaces in the chamber. UHV conditions are integral to scientific research. Surface science experiments often require a chemically clean sample surface with the absence of any unwanted adsorbates. Surface analysis tools such as X-ray photoelectron spectroscopy and low energy ion scattering require UHV conditions for the transmission of electron or ion beams. For the same reason, beam pipes in particle accelerators such as the Large Hadron Collider are kept at UHV. Overview Maintaining UHV conditions requires the use of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Neutron Spin Echo
Neutron spin echo spectroscopy is an inelastic neutron scattering technique invented by Ferenc Mezei in the 1970s, and developed in collaboration with John Hayter. In recognition of his work and in other areas, Mezei was awarded the first Walter Haelg Prize in 1999. In magnetic resonance, a spin echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. The spin echo spectrometer possesses an extremely high energy resolution (roughly one part in 100,000). Additionally, it measures the density-density correlation (or intermediate scattering function) F(Q,t) as a function of momentum transfer Q and time. Other neutron scattering techniques measure the dynamic structure factor S(Q,ω), which can be converted to F(Q,t) by a Fourier transform, which may be difficult in practice. For weak inelastic features S(Q,ω) is better suited, however, for (slow) relaxations the natural representation is given by F(Q,t). Because of its extraord ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helium Atom Scattering
Helium atom scattering (HAS) is a surface analysis technique used in materials science. HAS provides information about the surface structure and lattice dynamics of a material by measuring the diffracted atoms from a monochromatic helium beam incident on the sample. History The first recorded He diffraction experiment was completed in 1930 by Estermann and Stern on the (100) crystal face of lithium fluoride. This experimentally established the feasibility of atom diffraction when the de Broglie wavelength, λ, of the impinging atoms is on the order of the interatomic spacing of the material. At the time, the major limit to the experimental resolution of this method was due to the large velocity spread of the helium beam. It wasn't until the development of high pressure nozzle sources capable of producing intense and strongly monochromatic beams in the 1970s that HAS gained popularity for probing surface structure. Interest in studying the collision of rarefied gases with soli ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin Echo
In magnetic resonance, a spin echo or Hahn echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. Modern nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) make use of this effect. The NMR signal observed following an initial excitation pulse decays with time due to both spin relaxation and any ''inhomogeneous'' effects which cause spins in the sample to precess at different rates. The first of these, relaxation, leads to an irreversible loss of magnetisation. But the inhomogeneous dephasing can be removed by applying a 180° ''inversion'' pulse that inverts the magnetisation vectors. Examples of inhomogeneous effects include a magnetic field gradient and a distribution of chemical shifts. If the inversion pulse is applied after a period ''t'' of dephasing, the inhomogeneous evolution will rephase to form an echo at time 2''t''. In simple cases, the intensity of the echo relative to the initial signal is given by ''e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intermediate Scattering Function
In condensed matter physics, the dynamic structure factor (or dynamical structure factor) is a mathematical function that contains information about inter-particle correlations and their time evolution. It is a generalization of the structure factor that considers correlations in both space ''and'' time. Experimentally, it can be accessed most directly by inelastic neutron scattering or X-ray Raman scattering. The dynamic structure factor is most often denoted S(\vec,\omega), where \vec (sometimes \vec) is a wave vector (or wave number for isotropic materials), and \omega a frequency (sometimes stated as energy, \hbar\omega). It is defined as: :S(\vec,\omega) \equiv \frac\int_^ F(\vec,t)\exp(i\omega t)\,dt Here F(\vec,t), is called the intermediate scattering function and can be measured by neutron spin echo spectroscopy. The intermediate scattering function is the spatial Fourier transform of the van Hove function G(\vec,t): :F(\vec,t) \equiv \int G(\vec,t)\exp (-i\vec\cdot\vec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffraction
Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a secondary source of the propagating wave. Italian scientist Francesco Maria Grimaldi coined the word ''diffraction'' and was the first to record accurate observations of the phenomenon in 1660. In classical physics, the diffraction phenomenon is described by the Huygens–Fresnel principle that treats each point in a propagating wavefront as a collection of individual spherical wavelets. The characteristic bending pattern is most pronounced when a wave from a coherent source (such as a laser) encounters a slit/aperture that is comparable in size to its wavelength, as shown in the inserted image. This is due to the addition, or interference, of different points on the wavefront (or, equivalently, each wavelet) that travel by paths of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Selective Adsorption
In surface science, selective adsorption is the effect when minima associated with bound-state resonances occur in specular intensity in atom-surface scattering. In crystal growth, selective adsorption refers to the phenomenon where adsorbing molecules attach preferentially to certain crystal faces. An example of selective adsorption can be demonstrated in the growth of Rochelle salt crystals. If copper ions are added to solution during the growth process, some crystal faces will slow down as copper apparently becomes a barrier to adsorption. However, by then adding sodium hydroxide to the solution, the preferred crystal faces will change once again. Discovery Pronounced intensity minima were first observed in 1930 by Theodor Estermann, Otto Frisch Otto Robert Frisch FRS (1 October 1904 – 22 September 1979) was an Austrian-born British physicist who worked on nuclear physics. With Lise Meitner he advanced the first theoretical explanation of nuclear fission (coining the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Diffusion
Surface diffusion is a general process involving the motion of adatoms, molecules, and atomic clusters (adparticles) at solid material surfaces.Oura, Lifshits, Saranin, Zotov, and Katayama 2003, p. 325 The process can generally be thought of in terms of particles jumping between adjacent adsorption sites on a surface, as in figure 1. Just as in bulk diffusion, this motion is typically a thermally promoted process with rates increasing with increasing temperature. Many systems display diffusion behavior that deviates from the conventional model of nearest-neighbor jumps. Tunneling diffusion is a particularly interesting example of an unconventional mechanism wherein hydrogen has been shown to diffuse on clean metal surfaces via the quantum tunneling effect. Various analytical tools may be used to elucidate surface diffusion mechanisms and rates, the most important of which are field ion microscopy and scanning tunneling microscopy.Oura, Lifshits, Saranin, Zotov, and Katayama 2003, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Phonon
In solid state physics, a surface phonon is the quantum of a lattice vibration mode associated with a solid surface. Similar to the ordinary lattice vibrations in a bulk solid (whose quanta are simply called phonons), the nature of surface vibrations depends on details of periodicity and symmetry of a crystal structure. Surface vibrations are however distinct from the bulk vibrations, as they arise from the abrupt termination of a crystal structure at the surface of a solid. Knowledge of surface phonon dispersion gives important information related to the amount of surface relaxation, the existence and distance between an adsorbate and the surface, and information regarding presence, quantity, and type of defects existing on the surface.J. Szeftel, "Surface phonon dispersion, using electron energy loss spectroscopy," ''Surface Science'', 152/153 (1985) 797–810, In modern semiconductor research, surface vibrations are of interest as they can couple with electrons and thereby af ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scientific Techniques
A scientific technique is any systematic way of obtaining information about a scientific nature or to obtain a desired material or product. Scientific techniques can be divided in many different groups, e.g.: # Preparative techniques ## Synthesis techniques, e.g. the use of Grignard reagents in organic chemistry ## Growth techniques, e.g. crystal growth or cell cultures in biology ## Purification techniques e.g. those in chemistry # Measurement techniques ## Analysis techniques, e.g. ones that reveal atomic or molecular composition. ## Characterization techniques, e.g. ones that measure a certain property of a material. ## Imaging techniques, e.g. microscopy In some cases these methods have evolved into instrumental techniques that require expensive equipment. This is particularly true in sciences like physics, chemistry, and astronomy. It is customary to abbreviate the names of techniques into acronyms, although this does not hold for all of them. Particularly the advent of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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