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GC Ion Detector
Many gas chromatograph detectors are ion detectors with varying methods of ionizing the components eluting from the gas chromatograph's column. An ion detector is analogous to a capacitor or vacuum tube. It can be envisioned as two metal grids separated by air with inverse charges placed on them. An electric potential difference (voltage) exists between the two grids. After components are ionized in the detector, they enter the region between the two grids, causing current to pass from one to the other. This current is amplified and is the signal generated by the detector. The higher the concentration of the component, the more ions are generated, and the greater the current. Some early FIDs actually used two metal grids as their ion detectors. However, more efficient designs have been developed, so few current ion-type detectors use two metal grids. But the principle is the same, and it can be easiest to think of the detector in this manner. Types of Ion Detectors *Flam ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gas Chromatograph
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separati ... for separating and analyzing compounds that can be vaporized without Chemical decomposition, decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. In preparative chromatography, GC can be used to prepare pure compounds from a mixture. Gas chromatography is also sometimes known as vapor-phase chromatography (VPC), or gas–liquid partition chromatography (GLPC). These alternative names, as well as their respective abbreviations, are frequently used in scientific literature. Gas chromatography is the process of separating compounds in a mixture by injecting a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Capacitor
A capacitor is a device that stores electrical energy in an electric field by virtue of accumulating electric charges on two close surfaces insulated from each other. It is a passive electronic component with two terminals. The effect of a capacitor is known as capacitance. While some capacitance exists between any two electrical conductors in proximity in a circuit, a capacitor is a component designed to add capacitance to a circuit. The capacitor was originally known as the condenser, a term still encountered in a few compound names, such as the '' condenser microphone''. The physical form and construction of practical capacitors vary widely and many types of capacitor are in common use. Most capacitors contain at least two electrical conductors often in the form of metallic plates or surfaces separated by a dielectric medium. A conductor may be a foil, thin film, sintered bead of metal, or an electrolyte. The nonconducting dielectric acts to increase the capacitor's ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum Tube
A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric voltage, potential difference has been applied. The type known as a thermionic tube or thermionic valve utilizes thermionic emission of electrons from a hot cathode for fundamental electronic functions such as signal amplifier, amplification and current rectifier, rectification. Non-thermionic types such as a vacuum phototube, however, achieve electron emission through the photoelectric effect, and are used for such purposes as the detection of light intensities. In both types, the electrons are accelerated from the cathode to the anode by the electric field in the tube. The simplest vacuum tube, the diode (i.e. Fleming valve), invented in 1904 by John Ambrose Fleming, contains only a heated electron-emitting cathode and an anode. Electrons can only flow in one direction through the device—fro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Voltage
Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to move a test charge between the two points. In the International System of Units, the derived unit for voltage is named '' volt''. The voltage between points can be caused by the build-up of electric charge (e.g., a capacitor), and from an electromotive force (e.g., electromagnetic induction in generator, inductors, and transformers). On a macroscopic scale, a potential difference can be caused by electrochemical processes (e.g., cells and batteries), the pressure-induced piezoelectric effect, and the thermoelectric effect. A voltmeter can be used to measure the voltage between two points in a system. Often a common reference potential such as the ground of the system is used as one of the points. A voltage can represent eith ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flame Ionization Detector
A flame ionization detector (FID) is a scientific instrument that measures analytes in a gas stream. It is frequently used as a detector in gas chromatography. The measurement of ion per unit time make this a mass sensitive instrument. Standalone FIDs can also be used in applications such as landfill gas monitoring, fugitive emissions monitoring and internal combustion engine emissions measurement in stationary or portable instruments. History The first flame ionization detectors were developed simultaneously and independently in 1957 by McWilliam and Dewar at Imperial Chemical Industries of Australia and New Zealand (ICIANZ, see Orica history) Central Research Laboratory, Ascot Vale, Melbourne, Australia. and by Harley and Pretorius at the University of Pretoria in Pretoria, South Africa. In 1959, Perkin Elmer Corp. included a flame ionization detector in its Vapor Fractometer. Operating principle The operation of the FID is based on the detection of ions formed dur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Capture Detector
An electron capture detector (ECD) is a device for detecting atoms and molecules in a gas through the attachment of electrons via electron capture ionization. The device was invented in 1957 by James Lovelock and is used in gas chromatography to detect trace amounts of chemical compounds in a sample. Gas chromatograph detector The electron capture detector is used for detecting electron-absorbing components (high electronegativity) such as halogenated compounds in the output stream of a gas chromatograph. The ECD uses a radioactive beta particle (electron) emitter in conjunction with a so-called makeup gas flowing through the detector chamber. The electron emitter typically consists of a metal foil holding 10 millicuries (370 M Bq) of the radionuclide . Usually, nitrogen is used as makeup gas, because it exhibits a low excitation energy, so it is easy to remove an electron from a nitrogen molecule. The electrons emitted from the electron emitter collide with the molecules of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beta Radiation
A beta particle, also called beta ray or beta radiation (symbol β), is a high-energy, high-speed electron or positron emitted by the radioactive decay of an atomic nucleus during the process of beta decay. There are two forms of beta decay, β− decay and β+ decay, which produce electrons and positrons respectively. Beta particles with an energy of 0.5 MeV have a range of about one metre in air; the distance is dependent on the particle energy. Beta particles are a type of ionizing radiation and for radiation protection purposes are regarded as being more ionising than gamma rays, but less ionising than alpha particles. The higher the ionising effect, the greater the damage to living tissue, but also the lower the penetrating power of the radiation. Beta decay modes β− decay (electron emission) An unstable atomic nucleus with an excess of neutrons may undergo β− decay, where a neutron is converted into a proton, an electron, and an electron antineutrino (the an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photo-ionization Detector
A photoionization detector or PID is a type of gas detector. Typical photoionization detectors measure volatile organic compounds and other gases in concentrations from sub parts per billion to 10 000 parts per million (ppm). The photoionization detector is an efficient and inexpensive detector for many gas and vapor analytes. PIDs produce instantaneous readings, operate continuously, and are commonly used as detectors for gas chromatography or as hand-held portable instruments. Hand-held, battery-operated versions are widely used in military, industrial, and confined working facilities for health and safety. Their primary use is for monitoring possible worker exposure to volatile organic compounds (VOCs) such as solvents, fuels, degreasers, plastics & their precursors, heat transfer fluids, lubricants, etc. during manufacturing processes and waste handling. Portable PIDs are used for monitoring: * Industrial hygiene and safety * Environmental contamination and remediation * Haza ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
UV Light
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight, and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack the energy to ionize atoms, it can cause chemical reactions and causes many substances to glow or fluoresce. Consequently, the chemical and biological effects of UV are greater than simple heating effects, and many practical applications of UV radiation derive from its interactions with organic molecules. Short-wave ultraviolet light damages DNA and sterilizes surfaces with which it comes into contact. For ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helium Ionization Detector
A helium ionization detector (HID) is a type of detector used in gas chromatography. Principle HID connected to a GC has the great advantage to use helium as both the carrier gas and the ionization gas. HID is an ion detector which uses a radioactive source, typically β-emitters, to create metastable helium species. The radioactive source ionizes helium atoms by bombarding them with emissions. The metastable helium species have an energy of up to 19.8 eV. These metastable helium species can ionize all compounds with the exception of neon which has a bigger ionization potential of 21.56 eV. As components elute from the GC's column they collide with the metastable helium ions, which then ionize the components. The ions produce an electric current, which is the signal In signal processing, a signal is a function that conveys information about a phenomenon. Any quantity that can vary over space or time can be used as a signal to share messages between observers. The '' IEEE ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Discharge Ionization Detector
A discharge ionization detector (DID) is a type of detector used in gas chromatography. Principle A DID is an ion detector which uses a high-voltage electric discharge to produce ions. The detector uses an electrical discharge in helium to generate high energy UV photons and metastable helium which ionizes all compounds except helium.http://www.cesstech.com.my/data/products/Gas/Gas_Chromatograph_GowMac%20Brochure/Gow-Mac%20590.pdf The ions produce an electric current, which is the signal output of the detector. The greater the concentration of the component, the more ions are produced, and the greater the current. Application DIDs are sensitive to a broad range of components. In Air Separation plants they are used to detect the components CO; CH2; C+; N2; O2 in Argon product in ppm range. DIDs are non-destructive detectors. They do not destroy/consume the components they detect. Therefore, they can be used before other detectors in multiple-detector configurat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Spark
An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an ionized, electrically conductive channel through a normally-insulating medium, often air or other gases or gas mixtures. Michael Faraday described this phenomenon as "the beautiful flash of light attending the discharge of common electricity". The rapid transition from a non-conducting to a conductive state produces a brief emission of light and a sharp crack or snapping sound. A spark is created when the applied electric field exceeds the dielectric breakdown strength of the intervening medium. For air, the breakdown strength is about 30 kV/cm at sea level. Experimentally, this figure tends to differ depending upon humidity, atmospheric pressure, shape of electrodes (needle and ground-plane, hemispherical etc.) and the corresponding spacing between them and even the type of waveform, whether sinusoidal or cosine-rectangular. At the beginning stages, free electron ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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