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Free Induction Decay
In Fourier transform nuclear magnetic resonance spectroscopy, free induction decay (FID) is the observable NMR signal generated by non-equilibrium nuclear spin magnetization precessing about the magnetic field (conventionally along z). This non-equilibrium magnetization can be created generally by applying a pulse of radio-frequency close to the Larmor frequency of the nuclear spins. If the magnetization vector has a non-zero component in the xy plane, then the precessing magnetisation will induce a corresponding oscillating voltage in a detection coil surrounding the sample. This time-domain signal (a sinusoid) is typically digitised and then Fourier transformed in order to obtain a frequency spectrum of the NMR signal i.e. the NMR spectrum. The duration of the NMR signal is ultimately limited by T2 relaxation, but mutual interference of the different NMR frequencies present also causes the signal to be damped more quickly. When NMR frequencies are well-resolved, as is t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nmr Fid Good Shim EN
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. NMR ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectrum
A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors in visible light after passing through a prism. As scientific understanding of light advanced, it came to apply to the entire electromagnetic spectrum. It thereby became a mapping of a range of magnitudes (wavelengths) to a range of qualities, which are the perceived "colors of the rainbow" and other properties which correspond to wavelengths that lie outside of the visible light spectrum. Spectrum has since been applied by analogy to topics outside optics. Thus, one might talk about the " spectrum of political opinion", or the "spectrum of activity" of a drug, or the " autism spectrum". In these uses, values within a spectrum may not be associated with precisely quantifiable numbers or definitions. Such uses imply a broad range of co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Measurement In Quantum Mechanics
In quantum physics, a measurement is the testing or manipulation of a physical system to yield a numerical result. The predictions that quantum physics makes are in general probabilistic. The mathematical tools for making predictions about what measurement outcomes may occur were developed during the 20th century and make use of linear algebra and functional analysis. Quantum physics has proven to be an empirical success and to have wide-ranging applicability. However, on a more philosophical level, debates continue about the meaning of the measurement concept. Mathematical formalism "Observables" as self-adjoint operators In quantum mechanics, each physical system is associated with a Hilbert space, each element of which represents a possible state of the physical system. The approach codified by John von Neumann represents a measurement upon a physical system by a self-adjoint operator on that Hilbert space termed an "observable". These observables play the role of measurable ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Back Action (quantum)
In quantum mechanics, back action refers to the effect of a detector on a measurement. Ideally, a detector should have no influence on the quantity it is measuring. However, in quantum systems it is sometimes the case that back action by the detector is an inherent feature of the system, and not just a result of the detector being imperfect. Back action has important consequences for the measurement process, and is a significant factor in measurements near quantum limits, such as measurements approaching the Standard Quantum Limit A quantum limit in physics is a limit on measurement accuracy at quantum scales. Depending on the context, the limit may be absolute (such as the Heisenberg limit), or it may only apply when the experiment is conducted with naturally occurring qua ... (SQL). Back action is an area of active research. Recent experiments with nanomechanical systems have attempted to evade back action while making measurements. References Quantum mechanics { ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen-vacancy Center
The nitrogen-vacancy center (N-V center or NV center) is one of numerous point defects in diamond. Its most explored and useful property is its photoluminescence, which allows observers to read out its spin-state. The NV center's electron spin, localized at atomic scales, can be manipulated at room temperature by external factors such as magnetic, or electric fields, microwave radiation, or light, resulting in sharp resonances in the intensity of the photoluminescence. These resonances can be explained in terms of electron spin related phenomena such as quantum entanglement, spin–orbit interaction and Rabi oscillations, and analysed using advanced quantum optics theory. An individual NV center can be used as a basic unit for a quantum computer, a qubit, and used for quantum cryptography. Further potential applications in novel fields of electronics and sensing include spintronics, masers, and quantum sensors. If the charge is not specified the term "NV center" refers to the neg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Time-domain NMR
Time domain refers to the analysis of mathematical functions, physical signals or time series of economic or environmental data, with respect to time. In the time domain, the signal or function's value is known for all real numbers, for the case of continuous time, or at various separate instants in the case of discrete time. An oscilloscope is a tool commonly used to visualize real-world signals in the time domain. A time-domain graph shows how a signal changes with time, whereas a frequency-domain graph shows how much of the signal lies within each given frequency band over a range of frequencies. Though most precisely referring to time in physics, the term ''time domain'' may occasionally informally refer to position in space when dealing with spatial frequencies, as a substitute for the more precise term ''spatial domain''. Origin of term The use of the contrasting terms ''time domain'' and ''frequency domain'' developed in U.S. communication engineering in the late 1940 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Interference (wave Propagation)
In physics, interference is a phenomenon in which two waves combine by adding their displacement together at every single point in space and time, to form a resultant wave of greater, lower, or the same amplitude. Constructive and destructive interference result from the interaction of waves that are correlated or coherent with each other, either because they come from the same source or because they have the same or nearly the same frequency. Interference effects can be observed with all types of waves, for example, light, radio, acoustic, surface water waves, gravity waves, or matter waves. Etymology The word ''interference'' is derived from the Latin words ''inter'' which means "between" and ''fere'' which means "hit or strike", and was coined by Thomas Young in 1801. Mechanisms The principle of superposition of waves states that when two or more propagating waves of the same type are incident on the same point, the resultant amplitude at that point is equal to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Relaxation (NMR)
In MRI and NMR spectroscopy, an observable nuclear spin polarization (magnetization) is created by a homogeneous magnetic field. This field makes the magnetic dipole moments of the sample precess at the resonance (Larmor) frequency of the nuclei. At thermal equilibrium, nuclear spins precess randomly about the direction of the applied field. They become abruptly phase coherent when they are hit by radiofrequent (RF) pulses at the resonant frequency, created orthogonal to the field. The RF pulses cause the population of spin-states to be perturbed from their thermal equilibrium value. The generated transverse magnetization can then induce a signal in an RF coil that can be detected and amplified by an RF receiver. The return of the longitudinal component of the magnetization to its equilibrium value is termed ''spin-lattice'' relaxation while the loss of phase-coherence of the spins is termed ''spin-spin'' relaxation, which is manifest as an observed free induction decay (FID). ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fourier Transform
A Fourier transform (FT) is a mathematical transform that decomposes functions into frequency components, which are represented by the output of the transform as a function of frequency. Most commonly functions of time or space are transformed, which will output a function depending on temporal frequency or spatial frequency respectively. That process is also called ''analysis''. An example application would be decomposing the waveform of a musical chord into terms of the intensity of its constituent pitches. The term ''Fourier transform'' refers to both the frequency domain representation and the mathematical operation that associates the frequency domain representation to a function of space or time. The Fourier transform of a function is a complex-valued function representing the complex sinusoids that comprise the original function. For each frequency, the magnitude ( absolute value) of the complex value represents the amplitude of a constituent complex sinusoid wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Magnetic Resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Digitized
DigitizationTech Target. (2011, April). Definition: digitization. ''WhatIs.com''. Retrieved December 15, 2021, from https://whatis.techtarget.com/definition/digitization is the process of converting information into a digital (i.e. computer-readable) format.Collins Dictionary. (n.d.). Definition of 'digitize'. Retrieved December 15, 2021, from https://www.collinsdictionary.com/dictionary/english/digitize The result is the representation of an object, image, sound, document, or signal (usually an analog signal) obtained by generating a series of numbers that describe a discrete set of points or samples. The result is called ''digital representation'' or, more specifically, a ''digital image'', for the object, and ''digital form'', for the signal. In modern practice, the digitized data is in the form of binary numbers, which facilitates processing by digital computers and other operations, but digitizing simply means "the conversion of analog source material into a numerical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electromagnetic Induction
Electromagnetic or magnetic induction is the production of an electromotive force (emf) across an electrical conductor in a changing magnetic field. Michael Faraday is generally credited with the discovery of induction in 1831, and James Clerk Maxwell mathematically described it as Faraday's law of induction. Lenz's law describes the direction of the induced field. Faraday's law was later generalized to become the Maxwell–Faraday equation, one of the four Maxwell equations in his theory of electromagnetism. Electromagnetic induction has found many applications, including electrical components such as inductors and transformers, and devices such as electric motors and generators. History Electromagnetic induction was discovered by Michael Faraday, published in 1831. It was discovered independently by Joseph Henry in 1832. In Faraday's first experimental demonstration (August 29, 1831), he wrapped two wires around opposite sides of an iron ring or " torus" (an ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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