Frasch Process
The Frasch process is a method to extract sulfur from underground deposits by taking advantage of the low melting point of sulfur. It is the only industrial method of recovering sulfur from elemental deposits. Most of the world's sulfur was obtained this way until the late 20th century, when sulfur recovered from petroleum and gas sources became more commonplace (see Claus process). In the Frasch process, superheated water is pumped into the sulfur deposit; the sulfur melts and is extracted. The Frasch process is able to produce high-purity sulfur of about 99.5%. History In 1867, miners discovered sulfur in the caprock of a salt dome in Calcasieu Parish, Louisiana, but it was beneath quicksand, which prevented mining. In 1894 the German-born American chemist, Herman Frasch (1852–1914), devised his Frasch method of sulfur removal using pipes to bypass the quicksand. This replaced the inefficient and polluting Sicilian method. The process proved successful, on December 24 ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Mining
Mining is the Resource extraction, extraction of valuable geological materials and minerals from the surface of the Earth. Mining is required to obtain most materials that cannot be grown through agriculture, agricultural processes, or feasibly created Chemical synthesis, artificially in a laboratory or factory. Ores recovered by mining include Metal#Extraction, metals, coal, oil shale, gemstones, limestone, chalk mining, chalk, dimension stone, rock salt, potash, gravel, and clay. The ore must be a rock or mineral that contains valuable constituent, can be extracted or mined and sold for profit. Mining in a wider sense includes extraction of any non-renewable resource such as petroleum, natural gas, or even fossil water, water. Modern mining processes involve prospecting for ore bodies, analysis of the profit potential of a proposed mine, extraction of the desired materials, and final mine reclamation, reclamation or restoration of the land after the mine is closed. Mining ma ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Sulphur, Louisiana
Sulphur () is a city in Calcasieu Parish, Louisiana, United States. The population was 21,809 in 2020. Sulphur is part of the Lake Charles metropolitan statistical area. History Sulphur is named for the sulfur mines that were operated in the area in the 1900s. In 1867, Professor Eugene W. Hilgard, an experienced geologist who was prospecting for oil and other minerals, conducted exploratory borings in Calcasieu Parish, Louisiana and discovered sulfur in the caprock of a salt dome. However, the sulfur was beneath several hundred feet of muck and quicksand containing deadly hydrogen sulfide gas, which made mining extremely hazardous. Repeated unsuccessful attempts to sink conventional mining shafts in the 1870s and 1880s resulted in the loss of many lives. In 1890, the German immigrant Herman Frasch invented and patented the Frasch Process of mining sulfur, using concentric pipes to pump superheated water into the ground, liquefy the mineral, and force the liquid to the surf ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Texas Gulf Sulphur Company
The Texas Gulf Sulphur Company was one of the largest sulfur mining companies in the world from 1919 to 1981. By 1925 the company controlled 40% of the U.S. sulfur market. It was formed in 1909 and acquired in 1981, after expanding across the United States from Texas into Mexico, Canada, and Ethiopia. SEC v. Texas Gulf Sulphur Co in 1981 was the first insider trading case on the federal level in the country. History Founding and early mines (1909-1959) The Gulf Sulphur Company was formed on December 23, 1909, by a group of investors from St. Louis and Texas.Kutney, G. (2007). Sulfur: History, Technology, Applications & Industry. ChemTec Publishing; 2 edition. . The company was formed to exploit the newly discovered sulfur deposit in the Big Hill salt dome near Matagorda, Texas, using the Frasch process. With the Frasch method, the underground sulphur deposit has superheated water pumped into it, with the sulfur then extracted when it melts. The patent to the system, by Herman Fr ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Freeport Sulphur Company
Freeport-McMoRan Inc., often called Freeport, is an American mining company based in the Freeport-McMoRan Center, in Phoenix, Arizona. The company is the world's largest producer of molybdenum, a major copper producer and operates the world's largest gold mine, the Grasberg mine in Papua, Indonesia. History Freeport Sulphur Company was founded July 12, 1912, by the eldest son of Svante Magnus "E.M." Swenson, banker Eric Pierson Swenson, with a group of investors, to develop sulfur mining at Bryan Mound salt dome, along the US Gulf Coast.''Poor's'' ''Poor's Government and Municipal Supplement'', Poor's Publishing Company, 1922, p. 760. was also established in Nov. 1912 to house worker ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Superheated Water
Superheated water is liquid water under pressure at temperatures between the usual boiling point, and the critical temperature, . It is also known as "subcritical water" or "pressurized hot water". Superheated water is stable because of overpressure that raises the boiling point, or by heating it in a sealed vessel with a headspace, where the liquid water is in equilibrium with vapour at the saturated vapor pressure. This is distinct from the use of the term superheating to refer to water at atmospheric pressure above its normal boiling point, which has not boiled due to a lack of nucleation sites (sometimes experienced by heating liquids in a microwave). Many of water's anomalous properties are due to very strong hydrogen bonding. Over the superheated temperature range the hydrogen bonds break, changing the properties more than usually expected by increasing temperature alone. Water becomes less polar and behaves more like an organic solvent such as methanol or ethanol. Solubil ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Sulfur Cycle
The sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (CHNOPS), being a constituent of many proteins and cofactor (biochemistry), cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. The global sulfur cycle involves the transformations of sulfur species through different oxidation states, which play an important role in both geological and biological processes. Steps of the sulfur cycle are: * Mineralization of Organosulfur compounds, organic sulfur into inorganic forms, such as hydrogen sulfide (H2S), elemental sulfur, as well as sulfide minerals. * Oxidation of hydrogen sulfide, sulfide, and elemental sulfur (S) to sulfate (). * Reduction of sulfate to sulfide. * Incorporation of sulfide into organic compounds (including metal-containing derivatives). * Disproportionation ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the human body produces small amounts of this sulfide and its mineral salts, and uses it as a signalling molecule. Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen, such as in swamps and sewers; this process is commonly known as anaerobic digestio ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk. Gypsum also Crystallization, crystallizes as translucent crystals of selenite (mineral), selenite. It forms as an evaporite mineral and as a Mineral hydration, hydration product of anhydrite. The Mohs scale of mineral hardness defines gypsum as hardness value 2 based on Scratch hardness, scratch hardness comparison. Fine-grained white or lightly tinted forms of gypsum known as alabaster have been used for sculpture by many cultures including Ancient Egypt, Mesopotamia, Ancient Rome, the Byzantine Empire, and the Nottingham alabasters of Medieval England. Etymology and history The word ''wikt:gypsum, gypsum'' is derived from the Greek language, Greek word (), "plaster". Because the quarry, quarries of the Montmartre district of P ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Anhydrite
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium ( celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around under normal atmospheric conditions. Anhydrite is common ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Permeability (earth Sciences)
In fluid mechanics, materials science and Earth sciences, the permeability of porous media (often, a rock or soil) is a measure of the ability for fluids (gas or liquid) to flow through the media; it is commonly symbolized as ''k''. Fluids can more easily flow through a material with high permeability than one with low permeability. The permeability of a medium is related to the '' porosity'', but also to the shapes of the pores in the medium and their level of connectedness. Fluid flows can also be influenced in different lithological settings by brittle deformation of rocks in fault zones; the mechanisms by which this occurs are the subject of fault zone hydrogeology. Permeability is also affected by the pressure inside a material. The SI unit for permeability is the square metre (m2). A practical unit for permeability is the '' darcy'' (d), or more commonly the ''millidarcy'' (md) The name honors the French Engineer Henry Darcy who first described the flow of wat ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Brazoria County, Texas
Brazoria County ( ) is a county in the U.S. state of Texas. As of the 2020 census, the population of the county was 372,031. The county seat is Angleton. Brazoria County is included in the Houston-The Woodlands-Sugar Land metropolitan statistical area. It is located in the Gulf Coast region of Texas. Regionally, parts of the county are within the extreme southernmost fringe of the regions locally known as Southeast Texas. Brazoria County is among a number of counties that are part of the region known as the Texas Coastal Bend. Its county seat is Angleton, and its largest city is Pearland. Brazoria County, like Brazos County farther upriver, takes its name from the Brazos River. It served as the first settlement area for Anglo-Texas, when the Old Three Hundred emigrated from the United States in 1821. The county also includes what was once Columbia and Velasco, Texas, early capital cities of the Republic of Texas. The highest point in Brazoria County is Shelton's Sha ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Gulf Coast
The Gulf Coast of the United States, also known as the Gulf South or the South Coast, is the coastline along the Southern United States where they meet the Gulf of Mexico. The coastal states that have a shoreline on the Gulf of Mexico are Texas, Louisiana, Mississippi, Alabama, and Florida, and these are known as the ''Gulf States''. The economy of the Gulf Coast area is dominated by industries related to energy, petrochemicals, fishing, aerospace, agriculture, and tourism. The large cities of the region are (from west to east) Brownsville, Texas, Brownsville, Corpus Christi, Texas, Corpus Christi, Houston, Galveston, Texas, Galveston, Beaumont, Texas, Beaumont, Lake Charles, Louisiana, Lake Charles, Lafayette, Louisiana, Lafayette, Baton Rouge, Louisiana, Baton Rouge, New Orleans, Gulfport, Mississippi, Gulfport, Biloxi, Mississippi, Biloxi, Mobile, Alabama, Mobile, Pensacola, Florida, Pensacola, Panama City, Florida, Panama City, St. Petersburg, Florida, St. Petersburg, and ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |