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Ethynyl Radical
The ethynyl radical (systematically named λ3-ethyne and hydridodicarbon(''C''—''C'')) is an organic compound with the chemical formula C≡CH (also written CHor ). It is a simple molecule that does not occur naturally on Earth but is abundant in the interstellar medium. It was first observed by electron spin resonance isolated in a solid argon matrix at liquid helium temperatures in 1963 by Cochran and coworkers at the Johns Hopkins Applied Physics Laboratory. It was first observed in the gas phase by Tucker and coworkers in November 1973 toward the Orion Nebula, using the NRAO 11-meter radio telescope. It has since been detected in a large variety of interstellar environments, including dense molecular clouds, bok globules, star forming regions, the shells around carbon-rich evolved stars, and even in other galaxies. Astronomical importance Observations of C2H can yield a large number of insights into the chemical and physical conditions where it is located. First, the re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Compound
Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-containing compounds such as alkanes (e.g. methane ) and its derivatives are universally considered organic, but many others are sometimes considered inorganic, such as certain compounds of carbon with nitrogen and oxygen (e.g. cyanide ion , hydrogen cyanide , chloroformic acid , carbon dioxide , and carbonate ion ). Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, and even ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fractionation
Fractionation is a separation process in which a certain quantity of a mixture (of gasses, solids, liquids, enzymes, or isotopes, or a suspension) is divided during a phase transition, into a number of smaller quantities (fractions) in which the composition varies according to a gradient. Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run. This property sets it apart from other separation techniques. Fractionation is widely employed in many branches of science and technology. Mixtures of liquids and gasses are separated by fractional distillation by difference in boiling point. Fractionation of components also takes place in column chromatography by a difference in affinity between statio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Monoxide
Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest oxocarbon, carbon oxide. In coordination complexes, the carbon monoxide ligand is called ''metal carbonyl, carbonyl''. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds. Numerous environmental and biological sources generate carbon monoxide. In industry, carbon monoxide is important in the production of many compounds, including drugs, fragrances, and fuels. Indoors CO is one of the most acutely toxic contaminants affecting indoor air quality. CO may be emitted from tobacco smoke and generated from malfunctioning fuel-burning stoves (wood, kerosene, natural gas, propane) and fuel-burning heating systems (wood, oil, n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Propynylidyne
Propynylidyne is a chemical compound that has been identified in interstellar space. Structure Linear (''l''-C3H) μD=3.551 Debye 2Π electronic ground state Simulated spectrum A rotational spectrum of the 2Π electronic ground state of ''l''-C3H can be made using the PGopher software (a Program for Simulating Rotational Structure, C. M. Western, University of Bristol, http://pgopher.chm.bris.ac.uk) and molecular constants extracted from the literature. These constants include μ=3.551 Debye and others provided by Yamamoto et al. 1990, given in units of MHz: B=11189.052, D=0.0051365, ASO=432834.31, γ=-48.57, p=-7.0842, and q=-13.057. A selection rule of ΔJ=0,1 was applied, with S=0.5. The resulting simulation for the rotational spectrum of C3H at a temperature of 30 K agree well with observations. The simulated spectrum is shown in the figure at right with the approximate atmospheric transmission overplotted in blue. All of the strongest simulated lines wit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vinyl Radical
Vinyl may refer to: Chemistry * Polyvinyl chloride (PVC), a particular vinyl polymer * Vinyl cation, a type of carbocation * Vinyl group, a broad class of organic molecules in chemistry * Vinyl polymer, a group of polymers derived from vinyl monomers Materials * PVC clothing, a fabric * Vinyl composition tile, a type of floor tiling * Vinyl siding, an exterior building cladding Music * Vinyl records, phonograph records made with polyvinyl chloride * Vinyl Group, an Australian music technology company * ''Vinyl'' (Dramarama album), 1991 * ''Vinyl'' (William Michael Morgan album), 2016 * ''Vinyl'' (EP), by Dramarama * Vinyl Solution, a record label * "Vinyl", a song by Kira Kosarin Film * ''Vinyl'' (1965 film), directed by Andy Warhol * ''Vinyl'' (2000 film), a documentary directed by Alan Zweig * ''Vinyl'' (2012 film), directed by Sara Sugarman about a 2004 musical hoax involving UK band, The Alarm Sports * Vinyl BC Vinyl Basketball Club, also known as Vinyl BC, i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Circumstellar Envelope
A circumstellar envelope (CSE) is a part of a star that has a roughly spherical shape and is not gravitationally bound to the star core. Usually circumstellar envelopes are formed from the dense stellar wind, or they are present before the formation of the star. Circumstellar envelopes of old stars ( Mira variables and OH/IR stars) eventually evolve into protoplanetary nebulae, and circumstellar envelopes of young stellar objects evolve into circumstellar discs. Types of circumstellar envelopes * Circumstellar envelopes of AGB stars * Circumstellar envelopes around young stellar objects See also * Circumstellar dust * Common envelopes * Stellar evolution Stellar evolution is the process by which a star changes over the course of time. Depending on the mass of the star, its lifetime can range from a few million years for the most massive to trillions of years for the least massive, which is consi ... References External links The Structure and Evolution of En ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stellar Wind
A stellar wind is a flow of gas ejected from the stellar atmosphere, upper atmosphere of a star. It is distinguished from the bipolar outflows characteristic of young stars by being less collimated, although stellar winds are not generally spherically symmetric. Different stellar classification, types of stars have different types of stellar winds. Post-main sequence, main-sequence stars nearing the ends of their lives often eject large quantities of mass in massive ( \scriptstyle \dot > 10^ solar masses per year), slow (v = 10 km/s) winds. These include red giants and Red supergiant, supergiants, and asymptotic giant branch stars. These winds are understood to be driven by radiation pressure on Cosmic dust, dust condensing in the upper atmosphere of the stars. Young T Tauri stars often have very powerful stellar winds. Massive stars of stellar classification, types O star, O and B V star, B have stellar winds with lower mass loss rates (\scriptstyle \dot 1–2000 km ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Glow Discharge
A glow discharge is a Plasma (physics), plasma formed by the passage of electric current through a gas. It is often created by applying a voltage between two electrodes in a glass tube containing a low-pressure gas. When the voltage exceeds a value called the striking voltage, the gas ionization becomes self-sustaining, and the tube glows with a colored light. The color depends on the gas used. Glow discharges are used as a source of light in devices such as neon lights, Cold cathode fluorescent lamp, cold cathode fluorescent lamps and plasma display, plasma-screen televisions. Analyzing the light produced with spectroscopy can reveal information about the atomic interactions in the gas, so glow discharges are used in plasma physics and analytical chemistry. They are also used in the surface treatment technique called sputtering. Electrical conduction in gas Conduction in a gas requires charge carriers, which can be either electrons or ions. Charge carriers come from ionizing ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photolysis
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments. Here, “light” is broadly defined as radiation spanning the vacuum ultraviolet (VUV), ultraviolet (UV), visible, and infrared (IR) regions of the electromagnetic spectrum. To break covalent bonds, photon energies corresponding to visible, UV, or VUV light are typically required, whereas IR photons may be sufficiently energetic to detach ligands from coordination complexes or to fragment supramolecular complexes. Photolysis in photosynthesis Photolysis is part of the light-dependent reaction, light phase, photochemical phase, or Hill reaction of photosynthesis. The general reaction of photosynthetic photolysis can be given in terms of photons as: :\ce + 2 \text \longri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyano Radical
The cyano radical (or cyanido radical) is a radical with molecular formula CN, sometimes written •CN. The cyano radical was one of the first detected molecules in the interstellar medium, in 1938. Its detection and analysis was influential in astrochemistry. The discovery was confirmed with a coudé spectrograph, which was made famous and credible due to this detection. ·CN has been observed in both diffuse clouds and dense clouds. Usually, CN is detected in regions with hydrogen cyanide, hydrogen isocyanide, and HCNH+, since it is involved in the creation and destruction of these species (see also ''Cyanogen''). Physical properties Bonding in the cyano radical can be described as a combination of two resonance structures: the structure with the unpaired electron on the carbon is the minor contributor, while the structure with the unpaired electron on the nitrogen (the isocyano radical) is the major contributor. The charge separation in the isocyano radical is similar to that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zeeman Effect
The Zeeman effect () is the splitting of a spectral line into several components in the presence of a static magnetic field. It is caused by the interaction of the magnetic field with the magnetic moment of the atomic electron associated with its Angular momentum, orbital motion and Spin (physics), spin; this interaction shifts some orbital energies more than others, resulting in the split spectrum. The effect is named after the Netherlands, Dutch physicist Pieter Zeeman, who discovered it in 1896 and received a Nobel Prize in Physics for this discovery. It is analogous to the Stark effect, the splitting of a spectral line into several components in the presence of an electric field. Also, similar to the Stark effect, transitions between different components have, in general, different intensities, with some being entirely forbidden (in the dipole approximation), as governed by the selection rules. Since the distance between the Zeeman sub-levels is a function of magnetic field ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
