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Ethylene Glycol Dinitrate
Ethylene glycol dinitrate, abbreviated EGDN and NGC, also known as Nitroglycol, is a colorless, oily, explosive liquid obtained by nitrating ethylene glycol. It is similar to nitroglycerine in both manufacture and properties, though it is more volatile and less viscous. Unlike nitroglycerine, the chemical has a perfect oxygen balance, meaning that its ideal exothermic decomposition would completely convert it to low energy carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ..., water, and nitrogen gas, with no excess unreacted substances, without needing to react with anything else. History and production Pure EGDN was first produced by the Belgian chemist Louis Henry (1834–1913) in 1870 by dropping a small amount of ethylene glycol into a mixture of nitric acid, nitr ...
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Metre Per Second
The metre per second is the unit of both speed (a scalar (physics), scalar quantity) and velocity (a Vector (mathematics and physics), vector quantity, which has direction and magnitude) in the International System of Units (SI), equal to the speed of a body covering a distance of one metre in a time of one second. According to the definition of metre, is exactly \frac of the speed of light. The International System of Units, SI unit symbols are m/s, m·s−1, m s−1, or . Conversions is equivalent to: : = 3.6 kilometres per hour, km/h (exactly) : ≈ 3.2808 feet per second (approximately) : ≈ 2.2369 miles per hour (approximately) : ≈ 1.9438 knot (unit), knots (approximately) 1 feet per second, foot per second = (exactly) 1 miles per hour, mile per hour = (exactly) 1 kilometres per hour, km/h = (exactly) Relation to other measures The benz, named in honour of Karl Benz, has been proposed as a name for one metre per second. Although it has seen some suppor ...
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Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utilize its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous ...
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Xylitol Pentanitrate
Xylitol pentanitrate (XPN) is a nitrated ester primary explosive first synthesized in 1891 by Gabriel Bertrand. Law enforcement has taken an interest in XPN along with erythritol tetranitrate (ETN) and pentaerythritol tetranitrate (PETN) due to their ease of synthesis, which makes them accessible to amateur chemists and terrorists. Properties At room temperature XPN exists as a white crystalline solid. When heated to 163 °C, liquid xylitol pentanitrate begins to crackle and produce a dark vapour. When decomposed, a gram of XPN produces 200 mL of gas, which makes it a high performance explosive. Rotter impact analysis of XPN found a figure of insensitiveness of 25 (RDX = 80). XPN displayed a similar sensitivity to static discharge to ETN and PETN. Synthesis Xylitol pentanitrate is formed by nitration of xylitol pentaacetate. Nowadays, fuming nitric acid and glacial acetic acid is often used, but Bertrand originally employed a cheaper nitrating agent, the mixture of ...
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Erythritol Tetranitrate
Erythritol tetranitrate (ETN) is an explosive compound chemically similar to PETN, though it is thought to be slightly more sensitive to friction and impact. Like many nitrate esters, ETN acts as a vasodilator, and was the active ingredient in the original "sustained release" tablets, made under a process patent in the early 1950s, called " nitroglyn". Ingesting ETN or prolonged skin contact can lead to absorption and what is known as a "nitro headache". History ETN was discovered by John Stenhouse in 1849 by nitrating erythritol he recently discovered. He described its explosive properties but suggested an incorrect formula due to atomic weights not yet being accurately determined. Its vasodilator properties have been researched since 1895. DuPont researched the explosive after the war, getting a patent in 1928, but it was never commercialized due to the difficulty of erythritol synthesis. Only due to genetically-engineered yeasts in the 1990s did it become possible for the ...
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Methyl Nitrate
Methyl nitrate is the methyl ester of nitric acid and has the chemical formula CH3NO3. It is a colourless explosive volatile liquid. Synthesis It can be produced by the condensation of nitric acid and methanol: :CH3OH + HNO3 → CH3NO3 + H2O A newer method uses methyl iodide and silver nitrate: : CH3I + AgNO3 → CH3NO3 + AgI Methyl nitrate can be produced on a laboratory or industrial scale either through the distillation of a mixture of methanol and nitric acid, or by the nitration of methanol by a mixture of sulfuric and nitric acids. The first procedure is not preferred due to the great explosion danger presented by the methyl nitrate vapour. The second procedure is essentially identical to that of making nitroglycerin. However, the process is usually run at a slightly higher temperature and the mixture is stirred mechanically on an industrial scale instead of with compressed air. Electrolytic production methods have been reported involving electrolyzing sodium acet ...
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Vasodilator
Vasodilation, also known as vasorelaxation, is the widening of blood vessels. It results from relaxation of smooth muscle cells within the vessel walls, in particular in the large veins, large arteries, and smaller arterioles. Blood vessel walls are composed of endothelial tissue and a basal membrane lining the lumen of the vessel, concentric smooth muscle layers on top of endothelial tissue, and an adventitia over the smooth muscle layers. Relaxation of the smooth muscle layer allows the blood vessel to dilate, as it is held in a semi-constricted state by sympathetic nervous system activity. Vasodilation is the opposite of vasoconstriction, which is the narrowing of blood vessels. When blood vessels dilate, the flow of blood is increased due to a decrease in vascular resistance and increase in cardiac output. Vascular resistance is the amount of force circulating blood must overcome in order to allow perfusion of body tissues. Narrow vessels create more vascular resistan ...
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Polyol
In organic chemistry, a polyol is an organic compound containing multiple hydroxyl groups (). The term "polyol" can have slightly different meanings depending on whether it is used in food science or polymer chemistry. Polyols containing two, three and four hydroxyl groups are diols, triols, and tetrols, respectively. Classification Polyols may be classified according to their chemistry. Some of these chemistries are polyether, polyester, polycarbonate and also acrylic polyols. Polyether polyols may be further subdivided and classified as polyethylene oxide or polyethylene glycol (PEG), polypropylene glycol (PPG) and Polytetrahydrofuran or PTMEG. These have 2, 3 and 4 carbons respectively per oxygen atom in the repeat unit. Polycaprolactone polyols are also commercially available. There is also an increasing trend to use biobased (and hence renewable) polyols. Uses Polyether polyols have numerous uses. As an example, polyurethane foam is a big user of polyether polyols. ...
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Nitroglycerin
Nitroglycerin (NG) (alternative spelling nitroglycerine), also known as trinitroglycerol (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless or pale yellow, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is a nitrate ester rather than a nitro compound, but the traditional name is retained. Discovered in 1846 by Ascanio Sobrero, nitroglycerin has been used as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. It is combined with nitrocellulose to form double-based smokeless powder, used as a propellant in artillery and firearms since the 1880s. As is the case for many other explosives, nitroglycerin becomes more and more prone to exploding (i.e. spontaneous decomposition) as the temper ...
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DMDNB
DMDNB, or also DMNB, chemically 2,3-dimethyl-2,3-dinitrobutane, is a volatile organic compound used as a detection taggant for explosives, mostly in the United States where it is virtually the only such taggant in use. Dogs are very sensitive to it and can detect as little as 0.5 parts per billion in the air, as can specialised ion mobility spectrometers. Its presence allows more reliable explosive detection Explosive detection is a non-destructive inspection process to determine whether a container contains explosive material. Explosive detection is commonly used at airports, ports and for border control. Detection tools Colorimetrics & automated .... References Explosive chemicals {{DEFAULTSORT:Dmdnb Nitro compounds Explosive detection ...
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Explosive Detection
Explosive detection is a non-destructive inspection process to determine whether a container contains explosive material. Explosive detection is commonly used at airports, ports and for border control. Detection tools Colorimetrics & automated colorimetrics The use of colorimetric test kits for explosive detection is one of the most simple methods for officers, and widely used method for the detection of explosives. Colorimetric detection of explosives involves applying a chemical reagent to an unknown material or sample and observing a color reaction. Common color reactions are known and indicate to the user if there is an explosive material present and in many cases the group of explosives from which the material is derived. The major groups of explosives are nitroaromatic, nitrate ester, and nitramine explosives, as well as inorganic nitrate-based explosives. Other groups include chlorates and peroxides which are not nitro based explosives. Since explosives usually contai ...
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Semtex
Semtex is a general-purpose plastic explosive containing RDX and PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, originally under the name B 1 and then under the "Semtex" designation since 1964, labeled as ''SEMTEX 1A'', since 1967 as ''SEMTEX H'', and since 1987 as ''SEMTEX 10''. Originally developed for Czechoslovak military use and export, Semtex eventually became popular with armed groups and insurgents because, prior to the 2000s, it was extremely difficult to detect, as in the case of Pan Am Flight 103. Composition The composition of the two most common variants differ according to their use. The 1A (or 10) variant is used for mining, and is based mostly on crystalline PETN. The versions 1AP and 2P are formed as hexagonal booster charges; a special assembly of PETN and wax inside the charge assures high reliability for detonating cord or detonator. The H (or SE) variant ...
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Plastic Explosive
Plastic explosive is a soft and hand-moldable solid form of explosive material. Within the field of explosives engineering, plastic explosives are also known as putty explosives or blastics. Plastic explosives are especially suited for explosive demolition. Common plastic explosives include Semtex and C-4 (explosive), C-4. The first manufactured plastic explosive was gelignite in 1875, invented by Alfred Nobel. Usage Plastic explosives are especially suited for explosive demolition of obstacles and fortifications by combat engineers as they can be easily formed into ideal shapes for cutting structural members and have a high enough velocity of detonation and density for metal cutting work. An early use of plastic explosives was in the warhead of the Mortar (weapon)#Spigot mortar, Petard demolition mortar of the British Armoured Vehicle Royal Engineers (AVRE) which was used to destroy concrete fortifications encountered during Operation Overlord (D-Day). The original use of ...
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