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Diathermal Wall
In thermodynamics, a diathermal wall between two thermodynamic systems allows heat transfer but does not allow transfer of matter across it. The diathermal wall is important because, in thermodynamics, it is customary to assume ''a priori'', for a closed system, the physical existence of transfer of energy across a wall that is impermeable to matter but is not adiabatic, transfer which is called transfer of energy as heat, though it is not customary to label this assumption separately as an axiom or numbered law. Definitions of transfer of heat In theoretical thermodynamics, respected authors vary in their approaches to the definition of quantity of heat transferred. There are two main streams of thinking. One is from a primarily empirical viewpoint (which will here be referred to as the thermodynamic stream), to define heat transfer as occurring only by specified macroscopic mechanisms; loosely speaking, this approach is historically older. The other (which will here be referre ...
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Thermodynamics
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ...
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Max Planck
Max Karl Ernst Ludwig Planck (; ; 23 April 1858 – 4 October 1947) was a German Theoretical physics, theoretical physicist whose discovery of energy quantum, quanta won him the Nobel Prize in Physics in 1918. Planck made many substantial contributions to theoretical physics, but his fame as a physicist rests primarily on his role as the originator of Quantum mechanics, quantum theory and one of the founders of modern physics, which revolutionized understanding of atomic and Subatomic particle, subatomic processes. He is known for the Planck constant, which is of foundational importance for quantum physics, and which he used to derive a set of Unit of measurement, units, today called Planck units, expressed only in terms of fundamental physical constants. Planck was twice president of the German scientific institution Kaiser Wilhelm Society. In 1948, it was renamed the Max Planck Society (Max-Planck-Gesellschaft) and nowadays includes 83 institutions representing a wide range ...
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John Gamble Kirkwood
John "Jack" Gamble Kirkwood (May 30, 1907, Gotebo, Oklahoma – August 9, 1959, New Haven, Connecticut) was a noted chemist and physicist, holding faculty positions at Cornell University, the University of Chicago, California Institute of Technology, and Yale University. Early life and background Kirkwood was born in Gotebo, Oklahoma, the oldest child of John Millard and Lillian Gamble Kirkwood. His father was educated as an attorney and was a distributor for the Goodyear Corporation in the state of Kansas. In addition to Jack Kirkwood, there were two younger sisters: Caroline (1910) and Margaret (1921). In 1909, the family moved to Wichita, Kansas. In the 1920s the family traveled to Pasadena, California to escape Midwestern winters. Education While in Pasadena, Kirkwood, age 15, audited chemistry classes at Caltech. Showing remarkable talent in mathematics and chemistry, Kirkwood was persuaded by A. A. Noyes to enroll at Caltech before finishing his high school educati ...
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Elsevier
Elsevier ( ) is a Dutch academic publishing company specializing in scientific, technical, and medical content. Its products include journals such as ''The Lancet'', ''Cell (journal), Cell'', the ScienceDirect collection of electronic journals, ''Trends (journals), Trends'', the ''Current Opinion (Elsevier), Current Opinion'' series, the online citation database Scopus, the SciVal tool for measuring research performance, the ClinicalKey search engine for clinicians, and the ClinicalPath evidence-based cancer care service. Elsevier's products and services include digital tools for Data management platform, data management, instruction, research analytics, and assessment. Elsevier is part of the RELX Group, known until 2015 as Reed Elsevier, a publicly traded company. According to RELX reports, in 2022 Elsevier published more than 600,000 articles annually in over 2,800 journals. As of 2018, its archives contained over 17 million documents and 40,000 Ebook, e-books, with over one b ...
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George H
George may refer to: Names * George (given name) * George (surname) People * George (singer), American-Canadian singer George Nozuka, known by the mononym George * George Papagheorghe, also known as Jorge / GEØRGE * George, stage name of Giorgio Moroder * George, son of Andrew I of Hungary Places South Africa * George, South Africa, a city ** George Airport United States * George, Iowa, a city * George, Missouri, a ghost town * George, Washington, a city * George County, Mississippi * George Air Force Base, a former U.S. Air Force base located in California Computing * George (algebraic compiler) also known as 'Laning and Zierler system', an algebraic compiler by Laning and Zierler in 1952 * GEORGE (computer), early computer built by Argonne National Laboratory in 1957 * GEORGE (operating system), a range of operating systems (George 1–4) for the ICT 1900 range of computers in the 1960s * GEORGE (programming language), an autocode system invented by Charles L ...
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Max Born
Max Born (; 11 December 1882 – 5 January 1970) was a German-British theoretical physicist who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics, and supervised the work of a number of notable physicists in the 1920s and 1930s. Born shared the 1954 Nobel Prize in Physics with Walther Bothe "for his fundamental research in quantum mechanics, especially in the statistical interpretation of the wave function". Born entered the University of Göttingen in 1904, where he met the three renowned mathematicians Felix Klein, David Hilbert, and Hermann Minkowski. He wrote his PhD thesis on the subject of the stability of elastic wires and tapes, winning the university's Philosophy Faculty Prize. In 1905, he began researching special relativity with Minkowski, and subsequently wrote his habilitation thesis on the Thomson model of the atom. A chance meeting with Fritz Haber in Berlin in 1918 led to discussion of how an io ...
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Thermodynamic Equilibrium
Thermodynamic equilibrium is a notion of thermodynamics with axiomatic status referring to an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of mass nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, not only is there an absence of macroscopic change, but there is an “absence of any ''tendency'' toward change on a macroscopic scale.” Systems in mutual thermodynamic equilibrium are simultaneously in mutual thermal, mechanical, chemical, and radiative equilibria. Systems can be in one kind of mutual equilibrium, while not in others. In thermodynamic equilibrium, all kinds of equilibrium hold at once and indefinitely, unless disturbed by a thermodynamic operation. In a macroscopic equilibrium, perfectly or almost perfectly ba ...
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Emissivity
The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is not visible to human eyes. A portion of the thermal radiation from very hot objects (see photograph) is easily visible to the eye. The emissivity of a surface depends on its chemical composition and geometrical structure. Quantitatively, it is the ratio of the thermal radiation from a surface to the radiation from an black body, ideal black surface at the same temperature as given by the Stefan–Boltzmann law. (A comparison with Planck's law is used if one is concerned with particular wavelengths of thermal radiation.) The ratio varies from 0 to 1. The surface of a perfect black body (with an emissivity of 1) emits thermal radiation at the rate of approximately 448 watts per square metre (W/m) at a room temperature of . Objects have emi ...
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Kirchhoff's Law Of Thermal Radiation
In heat transfer, Kirchhoff's law of thermal radiation refers to wavelength-specific radiative emission and absorption by a material body in thermodynamic equilibrium, including radiative exchange equilibrium. It is a special case of Onsager reciprocal relations as a consequence of the time reversibility of microscopic dynamics, also known as microscopic reversibility. A body at temperature radiates electromagnetic energy. A perfect black body in thermodynamic equilibrium absorbs all light that strikes it, and radiates energy according to a unique law of radiative emissive power for temperature (Stefan–Boltzmann law), universal for all perfect black bodies. Kirchhoff's law states that: Here, the dimensionless coefficient of absorption (or the absorptivity) is the fraction of incident light (power) at each spectral frequency that is absorbed by the body when it is radiating and absorbing in thermodynamic equilibrium. In slightly different terms, the emissive power ...
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Calorimetry
In chemistry and thermodynamics, calorimetry () is the science or act of measuring changes in '' state variables'' of a body for the purpose of deriving the heat transfer associated with changes of its state due, for example, to chemical reactions, physical changes, or phase transitions under specified constraints. Calorimetry is performed with a calorimeter. Scottish physician and scientist Joseph Black, who was the first to recognize the distinction between heat and temperature, is said to be the founder of the science of calorimetry. Indirect calorimetry calculates heat that living organisms produce by measuring either their production of carbon dioxide and nitrogen waste (frequently ammonia in aquatic organisms, or urea in terrestrial ones), or from their consumption of oxygen. Lavoisier noted in 1780 that heat production can be predicted from oxygen consumption this way, using multiple regression. The dynamic energy budget theory explains why this procedure is corre ...
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Thermodynamic System
A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes. According to internal processes, passive systems and active systems are distinguished: passive, in which there is a redistribution of available energy, active, in which one type of energy is converted into another. Depending on its interaction with the environment, a thermodynamic system may be an isolated system, a Closed system#In thermodynamics, closed system, or an Open system (systems theory), open system. An isolated system does not exchange matter or energy with its surroundings. A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its ...
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