Nonanoate Esters
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Nonanoate Esters
Pelargonic acid, also called nonanoic acid, is an organic compound with structural formula . It is a nine-carbon fatty acid. Nonanoic acid is a colorless oily liquid with an unpleasant, rancid odor. It is nearly insoluble in water, but very soluble in organic solvents. The esters and salts of pelargonic acid are called pelargonates or nonanoates. The acid is named after the pelargonium plant, since oil from its leaves contains esters of the acid. Preparation Together with azelaic acid, it is produced industrially by ozonolysis of oleic acid. : Alternatively, pelargonic acid can be produced in a two-step process beginning with coupled dimerization and hydroesterification of 1,3-butadiene. This step produces a doubly unsaturated C9-ester, which can be hydrogenated to give esters of pelargonic acid. : : A laboratory preparation involves permanganate oxidation of 1-decene. Occurrence and uses Pelargonic acid occurs naturally as esters in the oil of ''Pelargonium''. Synthetic ...
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Fatty Acid
In chemistry, in particular in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated and unsaturated compounds#Organic chemistry, saturated or unsaturated. Most naturally occurring fatty acids have an Branched chain fatty acids, unbranched chain of an even number of carbon atoms, from 4 to 28. Fatty acids are a major component of the lipids (up to 70% by weight) in some species such as microalgae but in some other organisms are not found in their standalone form, but instead exist as three main classes of esters: triglycerides, phospholipids, and cholesteryl esters. In any of these forms, fatty acids are both important diet (nutrition), dietary sources of fuel for animals and important structural components for cell (biology), cells. History The concept of fatty acid (''acide gras'') was introduced in 1813 by Michel Eugène Chevreul, though he initially used some variant terms: ''graisse acide'' and ''acide huileux'' ("acid fat" and "oi ...
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1-Decene
Decene is an organic compound with the chemical formula . Decene contains a chain of ten carbon atoms with one double bond, making it an alkene. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance. As an alpha olefin, it is used as a comonomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids and alkylated aromatics. The industrial processes used in the production of dec-1-ene are oligomerization of ethylene by the Ziegler process or by the cracking of petrochemical waxes. In ethenolysis, methyl oleate, the ''methyl ester'' of oleic acid, converts to 1-decene and methyl 9- decenoate: ::\overset + \longrightarrow \overset + \overset Dec-1-ene has been isolated from the leaves and rhizome In botany and dendrology, a rhizome ( ) is a modified subterranean plant stem that sends out roots and S ...
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Solanum Lycopersicum
The tomato (, ), ''Solanum lycopersicum'', is a plant whose fruit is an edible berry that is eaten as a vegetable. The tomato is a member of the nightshade family that includes tobacco, potato, and chili peppers. It originated from and was domesticated in western South America. It was introduced to the Old World by the Spanish in the Columbian exchange in the 16th century. Tomato plants are vines, largely annual and vulnerable to frost, though sometimes living longer in greenhouses. The flowers are able to self-fertilise. Modern varieties have been bred to ripen uniformly red, in a process that has impaired the fruit's sweetness and flavor. There are thousands of cultivars, varying in size, color, shape, and flavor. Tomatoes are attacked by many insect pests and nematodes, and are subject to diseases caused by viruses and by mildew and blight fungi. The tomato has a strong savoury umami flavor, and is an important ingredient in cuisines around the world. It is used in pizz ...
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Meloidogyne Javanica
''Meloidogyne javanica'' is a species of plant-pathogenic nematodes. It is one of the tropical root-knot nematodes and a major agricultural pest in many countries. It has many hosts. ''Meloidogyne javanica'' reproduces by obligatory mitotic parthenogenesis (apomixis). Hosts ''Meloidogyne javanica'' is a nematode pathogen that affects over 770 species of plants (Cabi 2018). The hosts of this pathogen include both weeds and crops of economic importance. Those of economic importance include tea, grapevine, vegetables, fruit trees, cereals, and ornamentals (Cabi 2018). ''Meloidogyne javanica'' is considered an agricultural pest, as it is extremely abundant and damaging (Alford 2012). Symptoms Because there are so many different hosts for this pathogen, the symptoms are very variable. Common symptoms include abnormal leaf color, abnormal leaf form, wilting leaves, galls, swollen roots, reduced root system, dwarfing and senescence (Cabi 2018). This pathogen does the most damage w ...
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Nematicide
A nematicide is a type of chemical pesticide used to kill plant- parasitic nematodes. Nematicides have tended to be broad-spectrum toxicants possessing high volatility or other properties promoting migration through the soil. Aldicarb (Temik), a carbamate insecticide marketed by Bayer CropScience, is an example of a commonly used commercial nematicide. It is important in potato production, where it has been used for control of soil-borne nematodes. Aldicarb is a cholinesterase inhibitor, which prevents the breakdown of acetylcholine in the synapse. In case of severe poisoning, the victim dies of respiratory failure. It is no longer authorised for use in the EU and, in August 2010, Bayer CropScience announced that it planned to discontinue aldicarb by 2014. Human health safety and environmental concerns have resulted in the widespread deregistration of several other agronomically important nematicides. Prior to 1985, the persistent halocarbon DBCP was a widely used nematicide and ...
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Turfgrass
Sod is the upper layer of turf that is harvested for transplanting. Turf consists of a variable thickness of a soil medium that supports a community of turfgrasses. In British and Australian English, sod is more commonly known as ''turf'', and the word "sod" is limited mainly to agricultural senses. Uses Sod is generally used for lawns, golf courses, and sports stadiums around the world. In residential construction, it is sold to landscapers, home builders or home owners who use it to establish a lawn quickly and avoid soil erosion. Sod can be used to repair a small area of lawn, golf course, or athletic field that has died and is used as a quicker alternative to re-growing a lawn from seed. Sod is also effective in increasing cooling, improving air and water quality, and assisting in flood prevention by draining water. Scandinavia has a long history of employing sod roofing and a traditional house type is the Icelandic turf house. In the United States, following the ...
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Glyphosate
Glyphosate (IUPAC name: ''N''-(phosphonomethyl)glycine) is a broad-spectrum systemic herbicide and crop desiccant. It is an organophosphorus compound, specifically a phosphonate, which acts by EPSP inhibitor, inhibiting the plant enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSP). Glyphosate-based herbicides (GBHs) are used to kill weeds, especially annual Forbs, broadleaf weeds and grasses that compete with crops. Monsanto brought it to market for agricultural use in 1974 under the trade name Roundup (herbicide), ''Roundup''. Monsanto's last commercially relevant United States patent expired in 2000. Farmers quickly adopted glyphosate for agricultural weed control, especially after Monsanto introduced glyphosate-resistant Roundup Ready crops, enabling farmers to kill weeds without killing their crops. In 2007, glyphosate was the most used herbicide in the United States' agricultural sector and the second-most used (after 2,4-Dichlorophenoxyacetic acid, 2,4-D) in home ...
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Herbicide
Herbicides (, ), also commonly known as weed killers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page for EPA reports on pesticide use ihere Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides (sometimes called "total weed killers") kill plants indiscriminately. The combined effects of herbicides, nitrogen fertilizer, and improved cultivars has increased yields (per acre) of major crops by three to six times from 1900 to 2000. In the United States in 2012, about 91% of all herbicide usage, was determined by weight applied, in agriculture. In 2012, world pesticide expenditures totaled nearly US$24.7 billion; herbicides were about 44% of those sales and constituted the biggest portion, followed by insecticides, fungicides, and fumigants. Herbicide is also used ...
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Ammonium Pelargonate
Ammonium nonanoate is a nonsystemic, broad-spectrum contact herbicide that has no soil activity. It can be used for the suppression and control of weeds, including grasses, vines, underbrush, and annual/perennial plants, including moss, saplings, and tree suckers. Ammonium nonanoate is marketed as an aqueous solutions, at room temperature at its maximum concentration in water (40%). Solutions are colorless to pale yellow liquid with a slight fatty acid odor. It is stable in storage. Ammonium nonanoate exists as white crystals.Biopesticide Registration Action Document, Ammonium Nonanoate, US EPA, 2006 Ammonium nonanoate is made from ammonia and nonanoic acid, a carboxylic acid widely distributed in nature, mainly as derivatives (ester In chemistry, an ester is a compound derived from an acid (either organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group () of that acid is replaced by an organyl group (R). These compounds contain a distin ...
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Ammonium Salt
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged (cationic) molecular ion with the chemical formula or . It is formed by the addition of a proton (a hydrogen nucleus) to ammonia (). Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic or other groups (indicated by R). Not only is ammonium a source of nitrogen and a key metabolite for many living organisms, but it is an integral part of the global nitrogen cycle. As such, human impact in recent years could have an effect on the biological communities that depend on it. Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): : The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : Thus, the treatment of concentrated solutio ...
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Pepper Spray
Pepper spray, oleoresin capsicum spray, OC spray, capsaicin spray, mace, or capsicum spray is a Tear gas, lachrymator (tear gas) product containing as its active ingredient the chemical compound capsaicin, which irritates the eyes with burning and pain sensations and so causes them to close, bringing temporary blindness. This blindness allows officers to more easily restrain subjects and permits people in danger to use pepper spray in self-defense for an opportunity to escape. It also causes temporary discomfort and burning of the lungs which causes shortness of breath. Pepper spray is used as a less lethal weapon in Police, policing, riot control, crowd control, and self-defense, including defense against dogs and bears. Pepper spray was engineered originally for defense against bears, cougars, wolves and other dangerous predators, and is often referred to colloquially as bear spray. Kamran Loghman, who developed it for use in riot control, wrote the guide for police departm ...
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4-nonanoylmorpholine
4-Nonanoylmorpholine ''pelargonic acid morpholide, N-nonanoylmorpholine, MPK or МПК (for ), or MPAis an amide of pelargonic acid and morpholine. Properties 4-Nonanoylmorpholine was first synthesized in 1954 by L. M. Rice, from morpholine and acyl chloride of pelargonic acid. It is a liquid insoluble in water and soluble in polar organic solvents (e.g. acetone, propanol, and dimethyl formamide) and fats. Its volatility is 27 mg/m3 at 20 °C and 43 mg/m3 at 35 °C. Uses It is a used as a solvent in lachrymatory formulations containing CR gas or CS gas. It is reported to be effective against dogs and starts being effective in concentrations of over 20–40 mg•min/m3. It is considered very safe, with high differences between effective and toxic concentrations. At one time it was reportedly used as food seasoning with no reported adverse effects. However, its effectiveness when used alone is rather low even in the highest permitted concentration, so ...
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