Dry Lubricants
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Dry Lubricants
Dry lubricants or solid lubricants are materials that, despite being in the solid phase, are able to reduce friction between two surfaces sliding against each other without the need for a liquid oil medium. The two main dry lubricants are graphite and molybdenum disulfide. They offer lubrication at temperatures higher than liquid and oil-based lubricants operate. Dry lubricants are often used in applications such as locks or dry lubricated bearings. Such materials can operate up to 350 °C (662 °F) in oxidizing environments and even higher in reducing / non-oxidizing environments (molybdenum disulfide up to 1100 °C, 2012 °F). The low-friction characteristics of most dry lubricants are attributed to a layered structure on the molecular level with weak bonding between layers. Such layers are able to slide relative to each other with minimal applied force, thus giving them their low friction properties. However, a layered crystal structure alone is not necessar ...
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Friction
Friction is the force resisting the relative motion of solid surfaces, fluid layers, and material elements sliding against each other. Types of friction include dry, fluid, lubricated, skin, and internal -- an incomplete list. The study of the processes involved is called tribology, and has a history of more than 2000 years. Friction can have dramatic consequences, as illustrated by the use of friction created by rubbing pieces of wood together to start a fire. Another important consequence of many types of friction can be wear, which may lead to performance degradation or damage to components. It is known that frictional energy losses account for about 20% of the total energy expenditure of the world. As briefly discussed later, there are many different contributors to the retarding force in friction, ranging from asperity deformation to the generation of charges and changes in local structure. When two bodies in contact move relative to each other, due to these variou ...
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Lubricity
Lubricity is the measure of the reduction in friction and/or wear by a lubricant. The study of lubrication and wear mechanisms is called tribology. Measurement of lubricity The lubricity of a substance is not a material property, and cannot be measured directly. Tests are performed to quantify a lubricant's performance for a specific system. This is often done by determining how much wear is caused to a surface by a given wear-inducing object in a given amount of time. Other factors such as surface size, temperature, and pressure are also specified. For two fluids with the same viscosity, the one that results in a smaller wear scar is considered to have higher lubricity. For this reason, lubricity is also termed a substance's ''anti-wear property''. Examples of tribometer test setups include "Ball-on-cylinder" and "Ball-on-three-discs" tests. Lubricity in diesel engines In a modern diesel engine, the fuel is part of the engine lubrication process. Diesel fuel Diesel fuel, ...
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Nylon
Nylon is a family of synthetic polymers characterised by amide linkages, typically connecting aliphatic or Polyamide#Classification, semi-aromatic groups. Nylons are generally brownish in color and can possess a soft texture, with some varieties exhibiting a silk-like appearance. As Thermoplastic, thermoplastics, nylons can be melt-processed into fibres, Thin film, films, and diverse shapes. The properties of nylons are often modified by blending with a variety of additives. Numerous types of nylon are available. One family, designated nylon-XY, is derived from diamines and dicarboxylic acids of carbon chain lengths X and Y, respectively. An important example is nylon-6,6 (). Another family, designated nylon-Z, is derived from amino acid, aminocarboxylic acids with carbon chain length Z. An example is nylon-[6]. Nylon polymers have extensive commercial applications, including uses in textiles and fibres (such as apparel, flooring and rubber reinforcement), molded components fo ...
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O-ring
An O-ring, also known as a packing or a toric joint, is a mechanical gasket in the shape of a torus; it is a loop of elastomer with a round cross section (geometry), cross-section, designed to be seated in a groove and compressed during assembly between two or more parts, forming a seal (mechanical), seal at the interface. The O-ring may be used in static applications or in dynamic applications where there is relative motion between the parts and the O-ring. Dynamic examples include rotating pump shafts and hydraulic cylinder pistons. Static applications of O-rings may include fluid or gas sealing applications in which: (1) the O-ring is compressed resulting in zero clearance, (2) the O-ring material is vulcanized solid such that it is permeation, impermeable to the fluid or gas, and (3) the O-ring material is resistant to degradation by the fluid or gas. The wide range of potential liquids and gases that need to be sealed has necessitated the development of a wide range of O-r ...
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Universal Joint
A universal joint (also called a universal coupling or U-joint) is a joint or coupling connecting rigid shafts whose axes are inclined to each other. It is commonly used in shafts that transmit rotary motion. It consists of a pair of hinges located close together, oriented at 90° to each other, connected by a cross shaft. The universal joint is not a constant-velocity joint. U-joints are also sometimes called by various eponymous names, as follows: * Cardan joint, after Gerolamo Cardano, a polymath of the 16th century who contributed to knowledge of various clever mechanisms, including gimbals * Hooke joint or Hooke's joint, after Robert Hooke, a polymath of the 17th century who contributed to knowledge of various clever mechanisms * Spicer joint, after Clarence W. Spicer and the Spicer Manufacturing Company, who manufactured U joints * Hardy Spicer joint, after the Hardy Spicer brand, a successor to the Spicer brand History The main concept of the universal joi ...
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Spline (mechanical)
A spline is a ridge or tooth on a drive shaft that matches with a groove in a mating piece and transfers torque to it, maintaining the angular correspondence between them. For instance, a gear mounted on a shaft might use a male spline on the shaft that matches the female spline on the gear. Adjacent images in the section below show a transmission input shaft with male splines and a clutch plate with mating female splines in the center hub, where the smooth tip of the axle would be supported in a pilot bearing in the flywheel (not pictured). An alternative to splines is a keyway and key, though splines provide a longer fatigue life, and can carry significantly greater torques for the size. Types There are several types of splines: ;Parallel key spline: where the sides of the equally spaced grooves are parallel in both directions, radial and axial. ;Involute spline: where the sides of the equally spaced grooves are involute, as with an involute gear, but not as tall. The c ...
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Surface Energy
In surface science, surface energy (also interfacial free energy or surface free energy) quantifies the disruption of intermolecular bonds that occurs when a surface is created. In solid-state physics, surfaces must be intrinsically less energetically favorable than the bulk of the material (that is, the atoms on the surface must have more energy than the atoms in the bulk), otherwise there would be a driving force for surfaces to be created, removing the bulk of the material by sublimation. The surface energy may therefore be defined as the excess energy at the surface of a material compared to the bulk, or it is the work required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cut a bulk sample, creating two surfaces. There is "excess energy" as a result of the now-incomplete, unrealized bonding between the two created surfaces. Cutting a solid body into pieces disrupts its bonds and increases the surfac ...
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Polytetrafluorethylene
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from DuPont, which originally invented the compound in 1938. Polytetrafluoroethylene is a fluorocarbon solid, as it is a high- molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. When used as a lubricant, PTFE reduces friction, wea ...
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Boron Nitride
Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula B N. It exists in various crystalline forms that are isoelectronic to a similarly structured carbon lattice. The hexagonal form corresponding to graphite is the most stable and soft among BN polymorphs, and is therefore used as a lubricant and an additive to cosmetic products. The cubic ( zincblende aka sphalerite structure) variety analogous to diamond is called c-BN; it is softer than diamond, but its thermal and chemical stability is superior. The rare wurtzite BN modification is similar to lonsdaleite but slightly softer than the cubic form. Because of excellent thermal and chemical stability, boron nitride ceramics are used in high-temperature equipment and metal casting. Boron nitride has potential use in nanotechnology. History Boron nitride was discovered by chemistry teacher of the Liverpool Institute in 1842 via reduction of boric acid with ...
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Molybdenum Disulfide
Molybdenum disulfide (or moly) is an inorganic chemistry, inorganic compound composed of molybdenum and sulfur. Its chemical formula is . The compound is classified as a transition metal dichalcogenide. It is a silvery black solid that occurs as the mineral molybdenite, the principal ore for molybdenum.Sebenik, Roger F. ''et al''. (2005) "Molybdenum and Molybdenum Compounds", ''Ullmann's Encyclopedia of Chemical Technology''. Wiley-VCH, Weinheim. is relatively unreactive. It is unaffected by dilute acids and oxygen. In appearance and feel, molybdenum disulfide is similar to graphite. It is widely used as a dry lubricant because of its low friction and robustness. Bulk is a Diamagnetism, diamagnetic, indirect bandgap semiconductor similar to silicon, with a bandgap of 1.23 eV. Production is naturally found as either molybdenite, a crystalline mineral, or jordisite, a rare low temperature form of molybdenite. Molybdenite ore is processed by Froth flotation, flotation to give ...
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Graphitization
Graphitization is a process of transforming a carbonaceous material, such as coal or the carbon in certain forms of iron alloys, into graphite. Process The graphitization process involves a restructuring of the molecular structure of the carbon material. In the initial state, these materials can have an amorphous structure or a crystalline structure different from graphite. Graphitization generally occurs at high temperatures (up to ), and can be accelerated by catalysts such as iron or nickel. When carbonaceous material is exposed to high temperatures for an extended period of time, the carbon atoms begin to rearrange and form layered crystal planes. In the structure of graphite, carbon atoms are arranged in flat hexagonal sheets that are stacked on top of each other. These crystal planes give graphite its characteristic flake structure, giving it specific properties such as good electrical and thermal conductivity, low friction and excellent lubrication. Interest Graphiti ...
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Sintering
Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The atoms/molecules in the sintered material diffuse across the boundaries of the particles, fusing the particles together and creating a solid piece. Since the sintering temperature does not have to reach the melting point of the material, sintering is often chosen as the shaping process for materials with extremely high melting points, such as tungsten and molybdenum. The study of sintering in metallurgy, metallurgical powder-related processes is known as powder metallurgy. An example of sintering can be observed when ice cubes in a glass of water adhere to each other, which is driven by the temperature difference between the water and the ice. Examples of pressure-driven sintering are the compacting of snowfa ...
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