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Corrosion In Ballast Tanks
Corrosion in Ballast Tanks is the deterioration process where the surface of a ballast tank progresses from microblistering, to hydroscaletric electration, and finally to cracking of the tank steel itself. ::“Effective corrosion control in segregated water ballast spaces is probably the single most important feature, next to the integrity of the initial design, in determining the ship’s effective life span and structural reliability,” said Alan Gavin, Germanischer Lloyd's Principal surveyor. Throughout the years the merchant fleet has become increasingly aware of the importance of avoiding corrosion in ballast tanks. Factors influencing corrosion in ballast tanks Epoxy and modified epoxy are standard coatings used to provide protective barriers to corrosion in ballast tanks. Exposed, unprotected steel will corrode much more rapidly than steel covered with this protective layer. Many ships also use sacrificial anodes or an impressed current for additional protection. Em ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ballast Tank
A ballast tank is a compartment within a boat, ship or other floating structure that holds water, which is used as ballast to provide hydrostatic stability for a vessel, to reduce or control buoyancy, as in a submarine, to correct trim or list, to provide a more even load distribution along the hull to reduce structural hogging or sagging stresses, or to increase draft, as in a semi-submersible vessel or platform, or a SWATH, to improve seakeeping. Using water in a tank provides easier weight adjustment than the stone or iron ballast used in older vessels, and makes it easy for the crew to reduce a vessel's draft when it enters shallower water, by temporarily pumping out ballast. Airships use ballast tanks mainly to control buoyancy and correct trim. History The basic concept behind the ballast tank can be seen in many forms of aquatic life, such as the blowfish or argonaut octopus. The concept has been invented and reinvented many times by humans to serve a variety ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anodic Oxidation
An electrolytic cell is an electrochemical cell that utilizes an external source of electrical energy to force a chemical reaction that would not otherwise occur. The external energy source is a voltage applied between the cell′s two electrodes; an anode (positively charged electrode) and a cathode (negatively charged electrode), which are immersed in an electrolyte solution. This is in contrast to a galvanic cell, which itself is a source of electrical energy and the foundation of a Electric battery, battery. The net reaction taking place in a galvanic cell is a Spontaneous process, spontaneous reaction, i.e, the Gibbs free energy remains -ve, while the net reaction taking place in an electrolytic cell is the reverse of this Spontaneous process, spontaneous reaction, i.e, the Gibbs free energy is +ve.Skoog, Douglas A.; West, Donald M.; Holler, F. James; Crouch, Stanley R. (2014). ''Fundamentals of Analytical Chemistry.'' (9th ed.)''.'' Belmont: Brooks/Cole, Cengage Learning. p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Corrosion Engineering
Corrosion engineering is an engineering specialty that applies scientific, technical, engineering skills, and knowledge of natural laws and physical resources to design and implement materials, structures, devices, systems, and procedures to manage corrosion. From a holistic perspective, corrosion is the phenomenon of metals returning to the state they are found in nature. The driving force that causes metals to corrode is a consequence of their temporary existence in metallic form. To produce metals starting from naturally occurring minerals and ores, it is necessary to provide a certain amount of energy, e.g. Iron ore in a blast furnace. It is therefore thermodynamically inevitable that these metals when exposed to various environments would revert to their state found in nature. Corrosion and corrosion engineering thus involves a study of chemical kinetics, thermodynamics, electrochemistry and materials science. General background Generally related to metallurgy or material ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
MARPOL
The International Convention for the Prevention of Pollution from Ships, 1973 as modified by the Protocol of 1978, or "MARPOL 73/78" is one of the most important international marine environmental conventions. MARPOL 73/78, MARPOL is an amalgamation of the words "marine and pollution" in multiple languages and a short way to refer to the purpose of the convention. and 73/78 short for the years 1973 and 1978) It was developed by the International Maritime Organization with an objective to minimize pollution of the oceans and seas, including dumping, oil and air pollution. The original MARPOL was signed on 17 February 1973, but did not come into force at the signing date. The current convention is a combination of 1973 Convention and the 1978 Protocol, which entered into force on 2 October 1983. As of January 2018, 156 states are parties to the convention, being flag states of 99.42% of the world's shipping tonnage. All ships flagged under countries that are signatories to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
OPA 90
The Oil Pollution Act of 1990 (OPA) (101 H.R.1465, P.L. 101-380) was passed by the 101st United States Congress and signed by President George H. W. Bush. It works to avoid oil spills from vessels and facilities by enforcing removal of spilled oil and assigning liability for the cost of cleanup and damage; requires specific operating procedures; defines responsible parties and financial liability; implements processes for measuring damages; specifies damages for which violators are liable; and establishes a fund for damages, cleanup, and removal costs. This statute has resulted in instrumental changes in the oil production, transportation, and distribution industries. History/Background Laws governing oil spills in the United States began in 1851 with the Limitation of Liability Act. This statue, in an attempt to protect the shipping industry, stated that vessel owners were liable for incident-related costs up to the post-incident value of their vessel. The shortcomings of this l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Double-hulled Tankers
A double hull is a ship hull design and construction method where the bottom and sides of the ship have two complete layers of watertight hull surface: one outer layer forming the normal hull of the ship, and a second inner hull which is some distance inboard, typically by a few feet, which forms a redundant barrier to seawater in case the outer hull is damaged and leaks. The space between the two hulls is sometimes used for storage of ballast water. Double hulls are a more extensive safety measure than double bottoms, which have two hull layers only in the bottom of the ship but not the sides. In low-energy collisions, double hulls can prevent flooding beyond the penetrated compartment. In high-energy collisions, however, the distance to the inner hull is not sufficient and the inner compartment is penetrated as well. Double hulls or double bottoms have been required in all passenger ships for decades as part of the Safety Of Life At Sea or SOLAS Convention. Uses Double hulls ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cathodic
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. Consequently, the mnemonic ''cathode current departs'' also means that electrons flow ''into'' the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode. The electrode through which conventional current flows the other way, into the device, is termed an anode. Charge flow Conventional current flows from cathode to anode outside the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode. Cathode polarity with respect to the anode can be positive o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ullage
Ullage or headspace is the unfilled space in a container, particularly with a liquid. Etymology The word ''ullage'' comes from the Latin word ''oculus'', used by the Romans to refer to a barrel cork hole. This word was, in turn, taken in medieval French as ''oeil'', from which a verb ''ouiller'' was created, meaning to fill a barrel to full capacity. Around 1300, the word ''ouillage'' was created by the Normans to refer to the amount of liquid needed to fill a barrel to capacity. Alcoholic beverages In winemaking, ''ullage'' came to refer to any amount by which a barrel is unfilled, perhaps because some of the contents have been used. It is also applied to the unfilled air space at the top of a bottle of wine, which in this case is essential to allow for expansion of the contents as the temperature changes. By further extension, in brewing and beer retail, ''ullage'' is the residue of beer left in a barrel that has been emptied. When calculating tax returns and the like, licens ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemical Corrosion Potential
In electrochemistry, electrode potential is the electromotive force of a galvanic cell built from a standard reference electrode and another electrode to be characterized. By convention, the reference electrode is the standard hydrogen electrode (SHE). It is defined to have a potential of zero volts. It may also be defined as the potential difference between the charged metallic rods and salt solution. The electrode potential has its origin in the potential difference developed at the interface between the electrode and the electrolyte. It is common, for instance, to speak of the electrode potential of the M+/M redox couple. Origin and interpretation Electrode potential appears at the interface between an electrode and electrolyte due to the transfer of charged species across the interface, specific adsorption of ions at the interface, and specific adsorption/orientation of polar molecules, including those of the solvent. In an electrochemical cell, the cathode and the anode ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen or hydroxide. Rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion. This type of damage typically produces oxide(s) or salt(s) of the original metal and results in a distinctive orange colouration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including strength, appearance and permeability to liquids and gases. Many ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Resistivity And Conductivity
Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allows electric current. Resistivity is commonly represented by the Greek letter (rho). The SI unit of electrical resistivity is the ohm-meter (Ω⋅m). For example, if a solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is , then the resistivity of the material is . Electrical conductivity or specific conductance is the reciprocal of electrical resistivity. It represents a material's ability to conduct electric current. It is commonly signified by the Greek letter (sigma), but (kappa) (especially in electrical engineering) and ( gamma) are sometimes used. The SI unit of electrical conductivity is siemens per metre (S/m). Resistivity and conductivity are inte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffusion
Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical potential. It is possible to diffuse "uphill" from a region of lower concentration to a region of higher concentration, like in spinodal decomposition. The concept of diffusion is widely used in many fields, including physics (particle diffusion), chemistry, biology, sociology, economics, and finance (diffusion of people, ideas, and price values). The central idea of diffusion, however, is common to all of these: a substance or collection undergoing diffusion spreads out from a point or location at which there is a higher concentration of that substance or collection. A gradient is the change in the value of a quantity, for example, concentration, pressure, or temperature with the change in another variable, usually distance. A change in c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
