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Clausius–Clapeyron Relation
The Clausius–Clapeyron relation, named after Rudolf Clausius and Benoît Paul Émile Clapeyron, specifies the temperature dependence of pressure, most importantly vapor pressure, at a discontinuous phase transition between two phases of matter of a single constituent. Its relevance to meteorology and climatology is the increase of the water-holding capacity of the atmosphere by about 7% for every 1 °C (1.8 °F) rise in temperature. Definition On a pressure–temperature (''P''–''T'') diagram, the line separating the two phases is known as the coexistence curve. The Clapeyron relation gives the slope of the tangents to this curve. Mathematically, :\frac = \frac=\frac, where \mathrmP/\mathrmT is the slope of the tangent to the coexistence curve at any point, L is the specific latent heat, T is the temperature, \Delta v is the specific volume change of the phase transition, and \Delta s is the specific entropy change of the phase transition. The Clausius� ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rudolf Clausius
Rudolf Julius Emanuel Clausius (; 2 January 1822 – 24 August 1888) was a German physicist and mathematician and is considered one of the central founding fathers of the science of thermodynamics. By his restatement of Sadi Carnot's principle known as the Carnot cycle, he gave the theory of heat a truer and sounder basis. His most important paper, "On the Moving Force of Heat", published in 1850, first stated the basic ideas of the second law of thermodynamics. In 1865 he introduced the concept of entropy. In 1870 he introduced the virial theorem, which applied to heat. Life Clausius was born in Köslin (now Koszalin, Poland) in the Province of Pomerania in Prussia. His father was a Protestant pastor and school inspector, and Rudolf studied in the school of his father. In 1838, he went to the Gymnasium in Stettin. Clausius graduated from the University of Berlin in 1844 where he had studied mathematics and physics since 1840 with, among others, Gustav Magnus, Peter Gus ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Maxwell Relation
file:Thermodynamic map.svg, 400px, Flow chart showing the paths between the Maxwell relations. P is pressure, T temperature, V volume, S entropy, \alpha coefficient of thermal expansion, \kappa compressibility, C_V heat capacity at constant volume, C_P heat capacity at constant pressure. Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell. Equations The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant ( Schwarz theorem). In the case of Maxwell relations the function considered is a thermodynamic potential and x_i and x_j are two different natural variables for that potential, we have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names ''thermodynamic function'' and ''heat-potential''. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Binodal
In thermodynamics, the binodal, also known as the coexistence curve or binodal curve, denotes the condition at which two distinct phases may coexist. Equivalently, it is the boundary between the set of conditions in which it is thermodynamically favorable for the system to be fully mixed and the set of conditions in which it is thermodynamically favorable for it to phase separate.IUPAC binodal curve definition http://old.iupac.org/goldbook/BT07273.pdf accessed 2/20/13 In general, the binodal is defined by the condition at which the chemical potential of all solution components is equal in each phase. The extremum of a binodal curve in temperature coincides with the one of the spinodal In thermodynamics, the limit of local stability with respect to small fluctuations is clearly defined by the condition that the second derivative of Gibbs free energy is zero. : 0 The locus of these points (the inflection point within a G-x or ... curve and is known as a critical point. Bi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Specific Latent Heat
Latent heat (also known as latent energy or heat of transformation) is energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process — usually a first-order phase transition. Latent heat can be understood as energy in hidden form which is supplied or extracted to change the state of a substance without changing its temperature. Examples are latent heat of fusion and latent heat of vaporization involved in phase changes, i.e. a substance condensing or vaporizing at a specified temperature and pressure. The term was introduced around 1762 by Scottish chemist Joseph Black. It is derived from the Latin ''latere'' (''to lie hidden''). Black used the term in the context of calorimetry where a heat transfer caused a volume change in a body while its temperature was constant. In contrast to latent heat, sensible heat is energy transferred as heat, with a resultant temperature change in a body. Usage The terms ″sensible heat″ and ″laten ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Specific Enthalpy
Enthalpy , a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; bond, lattice, solvation and other "energies" in chemistry are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal energy, pressure, and volume, not on the path taken to achieve it. In the International System of Units (SI), the unit of measurement for enthalpy is the joule ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Internal Energy
The internal energy of a thermodynamic system is the total energy contained within it. It is the energy necessary to create or prepare the system in its given internal state, and includes the contributions of potential energy and internal kinetic energy. It keeps account of the gains and losses of energy of the system that are due to changes in its internal state. It does not include the kinetic energy of motion of the system as a whole, or any external energies from surrounding force fields. The internal energy of an isolated system is constant, which is expressed as the law of conservation of energy, a foundation of the first law of thermodynamics. The internal energy is an extensive property. The internal energy cannot be measured directly and knowledge of all its components is rarely interesting, such as the static rest mass energy of its constituent matter. Thermodynamics is chiefly concerned only with ''changes'' in the internal energy, not with its absolute value. Inste ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
First Law Of Thermodynamics
The first law of thermodynamics is a formulation of the law of conservation of energy, adapted for thermodynamic processes. It distinguishes in principle two forms of energy transfer, heat and thermodynamic work for a system of a constant amount of matter. The law also defines the internal energy of a system, an extensive property for taking account of the balance of energies in the system. The law of conservation of energy states that the total energy of any isolated system, which cannot exchange energy or matter, is constant. Energy can be transformed from one form to another, but can be neither created nor destroyed. The first law for a thermodynamic process is often formulated asThe sign convention (Q is heat supplied ''to'' the system but W is work done ''by'' the system) is that of Rudolf Clausius (Equation IIa on page 384 of Clausius, R. (1850)), and it is followed below. :\Delta U = Q - W, where \Delta U denotes the change in the internal energy of a closed syste ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reversible Process (thermodynamics)
In thermodynamics, a reversible process is a process, involving a system and its surroundings, whose direction can be reversed by infinitesimal changes in some properties of the surroundings, such as pressure or temperature. Throughout an entire reversible process, the system is in thermodynamic equilibrium, both physical and chemical, and ''nearly'' in pressure and temperature equilibrium with its surroundings. This prevents unbalanced forces and acceleration of moving system boundaries, which in turn avoids friction and other dissipation. To maintain equilibrium, reversible processes are extremely slow ( ''quasistatic''). The process must occur slowly enough that after some small change in a thermodynamic parameter, the physical processes in the system have enough time for the other parameters to self-adjust to match the new, changed parameter value. For example, if a container of water has sat in a room long enough to match the steady temperature of the surrounding air, fo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Integral
In mathematics, an integral assigns numbers to functions in a way that describes displacement, area, volume, and other concepts that arise by combining infinitesimal data. The process of finding integrals is called integration. Along with differentiation, integration is a fundamental, essential operation of calculus,Integral calculus is a very well established mathematical discipline for which there are many sources. See and , for example. and serves as a tool to solve problems in mathematics and physics involving the area of an arbitrary shape, the length of a curve, and the volume of a solid, among others. The integrals enumerated here are those termed definite integrals, which can be interpreted as the signed area of the region in the plane that is bounded by the graph of a given function between two points in the real line. Conventionally, areas above the horizontal axis of the plane are positive while areas below are negative. Integrals also refer to the concept of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Factorization
In mathematics, factorization (or factorisation, see English spelling differences) or factoring consists of writing a number or another mathematical object as a product of several ''factors'', usually smaller or simpler objects of the same kind. For example, is a factorization of the integer , and is a factorization of the polynomial . Factorization is not usually considered meaningful within number systems possessing division, such as the real or complex numbers, since any x can be trivially written as (xy)\times(1/y) whenever y is not zero. However, a meaningful factorization for a rational number or a rational function can be obtained by writing it in lowest terms and separately factoring its numerator and denominator. Factorization was first considered by ancient Greek mathematicians in the case of integers. They proved the fundamental theorem of arithmetic, which asserts that every positive integer may be factored into a product of prime numbers, which cannot be further ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
