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Canonical Commutation Relation
In quantum mechanics, the canonical commutation relation is the fundamental relation between canonical conjugate quantities (quantities which are related by definition such that one is the Fourier transform of another). For example, hat x,\hat p_x= i\hbar \mathbb between the position operator and momentum operator in the direction of a point particle in one dimension, where is the commutator of and , is the imaginary unit, and is the reduced Planck constant , and \mathbb is the unit operator. In general, position and momentum are vectors of operators and their commutation relation between different components of position and momentum can be expressed as hat x_i,\hat p_j= i\hbar \delta_, where \delta_ is the Kronecker delta. This relation is attributed to Werner Heisenberg, Max Born and Pascual Jordan (1925), who called it a "quantum condition" serving as a postulate of the theory; it was noted by E. Kennard (1927) to imply the Heisenberg uncertainty principle. The St ...
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Quantum Mechanics
Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot. Classical physics can describe many aspects of nature at an ordinary (macroscopic and Microscopic scale, (optical) microscopic) scale, but is not sufficient for describing them at very small submicroscopic (atomic and subatomic) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales. Quantum systems have Bound state, bound states that are Quantization (physics), quantized to Discrete mathematics, discrete values of energy, momentum, angular momentum, and ot ...
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Hilbrand J
Hilbrand is both a given name and a surname. Notable people with the name include: * Hilbrand Boschma (1893–1976), Dutch zoologist and museum curator * Hilbrand J. Groenewold (1910–1996), Dutch theoretical physicist * Hilbrand Nawijn (born 1948), Dutch politician * Sophie Hilbrand (born 1975), Dutch actress, television host and radio host See also * Hillebrand {{given name, type=both ...
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Heisenberg Group
In mathematics, the Heisenberg group H, named after Werner Heisenberg, is the group of 3×3 upper triangular matrices of the form : \begin 1 & a & c\\ 0 & 1 & b\\ 0 & 0 & 1\\ \end under the operation of matrix multiplication. Elements ''a, b'' and ''c'' can be taken from any commutative ring with identity, often taken to be the ring of real numbers (resulting in the "continuous Heisenberg group") or the ring of integers (resulting in the "discrete Heisenberg group"). The continuous Heisenberg group arises in the description of one-dimensional quantum mechanical systems, especially in the context of the Stone–von Neumann theorem. More generally, one can consider Heisenberg groups associated to ''n''-dimensional systems, and most generally, to any symplectic vector space. Three-dimensional case In the three-dimensional case, the product of two Heisenberg matrices is given by : \begin 1 & a & c\\ 0 & 1 & b\\ 0 & 0 & 1\\ \end \begin 1 & a' & c'\\ 0 & 1 & b'\\ 0 & 0 & ...
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Lie Algebra
In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi identity. In other words, a Lie algebra is an algebra over a field for which the multiplication operation (called the Lie bracket) is alternating and satisfies the Jacobi identity. The Lie bracket of two vectors x and y is denoted ,y/math>. A Lie algebra is typically a non-associative algebra. However, every associative algebra gives rise to a Lie algebra, consisting of the same vector space with the commutator Lie bracket, ,y= xy - yx . Lie algebras are closely related to Lie groups, which are groups that are also smooth manifolds: every Lie group gives rise to a Lie algebra, which is the tangent space at the identity. (In this case, the Lie bracket measures the failure of commutativity for the Lie group.) Conversely, to any finite-di ...
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Exponential Map (Lie Theory)
In the theory of Lie groups, the exponential map is a map from the Lie algebra \mathfrak g of a Lie group G to the group, which allows one to recapture the local group structure from the Lie algebra. The existence of the exponential map is one of the primary reasons that Lie algebras are a useful tool for studying Lie groups. The ordinary exponential function of mathematical analysis is a special case of the exponential map when G is the multiplicative group of positive real numbers (whose Lie algebra is the additive group of all real numbers). The exponential map of a Lie group satisfies many properties analogous to those of the ordinary exponential function, however, it also differs in many important respects. Definitions Let G be a Lie group and \mathfrak g be its Lie algebra (thought of as the tangent space to the identity element of G). The exponential map is a map :\exp\colon \mathfrak g \to G which can be defined in several different ways. The typical modern definition ...
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Lie Group
In mathematics, a Lie group (pronounced ) is a group (mathematics), group that is also a differentiable manifold, such that group multiplication and taking inverses are both differentiable. A manifold is a space that locally resembles Euclidean space, whereas groups define the abstract concept of a binary operation along with the additional properties it must have to be thought of as a "transformation" in the abstract sense, for instance multiplication and the taking of inverses (to allow division), or equivalently, the concept of addition and subtraction. Combining these two ideas, one obtains a continuous group where multiplying points and their inverses is continuous. If the multiplication and taking of inverses are smoothness, smooth (differentiable) as well, one obtains a Lie group. Lie groups provide a natural model for the concept of continuous symmetry, a celebrated example of which is the circle group. Rotating a circle is an example of a continuous symmetry. For an ...
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Functional Derivative
In the calculus of variations, a field of mathematical analysis, the functional derivative (or variational derivative) relates a change in a functional (a functional in this sense is a function that acts on functions) to a change in a function on which the functional depends. In the calculus of variations, functionals are usually expressed in terms of an integral of functions, their arguments, and their derivatives. In an integrand of a functional, if a function is varied by adding to it another function that is arbitrarily small, and the resulting integrand is expanded in powers of , the coefficient of in the first order term is called the functional derivative. For example, consider the functional J = \int_a^b L( \, x, f(x), f' \, ) \, dx \, , where . If is varied by adding to it a function , and the resulting integrand is expanded in powers of , then the change in the value of to first order in can be expressed as follows:According to , this notation is customary in ...
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Heisenberg Picture
In physics, the Heisenberg picture or Heisenberg representation is a Dynamical pictures, formulation (largely due to Werner Heisenberg in 1925) of quantum mechanics in which observables incorporate a dependency on time, but the quantum state, states are time-independent. It stands in contrast to the Schrödinger picture in which observables are constant and the states evolve in time. It further serves to define a third, hybrid, picture, the interaction picture. Mathematical details In the Heisenberg picture of quantum mechanics the state vectors do not change with time, while observables satisfy where "H" and "S" label observables in Heisenberg and Schrödinger picture respectively, is the Hamiltonian (quantum mechanics), Hamiltonian and denotes the commutator of two operators (in this case and ). Taking expectation values automatically yields the Ehrenfest theorem, featured in the correspondence principle. By the Stone–von Neumann theorem, the Heisenberg picture and ...
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Schrödinger Equation
The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after Erwin Schrödinger, an Austrian physicist, who postulated the equation in 1925 and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of the wave function, the quantum-mechanical characterization of an isolated physical system. The equation was postulated by Schrödinger based on a postulate of Louis de Broglie that all matter has an associated matter wave. The equati ...
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Correspondence Principle
In physics, a correspondence principle is any one of several premises or assertions about the relationship between classical and quantum mechanics. The physicist Niels Bohr coined the term in 1920 during the early development of quantum theory; he used it to explain how quantized classical orbitals connect to quantum radiation. Modern sources often use the term for the idea that the behavior of systems described by quantum theory reproduces classical physics in the limit of large quantum numbers: for large orbits and for large energies, quantum calculations must agree with classical calculations. A "generalized" correspondence principle refers to the requirement for a broad set of connections between any old and new theory. History Max Planck was the first to introduce the idea of quanta of energy, while studying black-body radiation in 1900. In 1906, he was also the first to write that quantum theory should replicate classical mechanics at some limit, particularly if the Pl ...
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Phase-space Formulation
The phase space of a physical system is the set of all possible physical states of the system when described by a given parameterization. Each possible state corresponds uniquely to a point in the phase space. For mechanical systems, the phase space usually consists of all possible values of the position and momentum parameters. It is the direct product of direct space and reciprocal space. The concept of phase space was developed in the late 19th century by Ludwig Boltzmann, Henri Poincaré, and Josiah Willard Gibbs. Principles In a phase space, every degree of freedom or parameter of the system is represented as an axis of a multidimensional space; a one-dimensional system is called a phase line, while a two-dimensional system is called a phase plane. For every possible state of the system or allowed combination of values of the system's parameters, a point is included in the multidimensional space. The system's evolving state over time traces a path (a phase- ...
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Wigner–Weyl Transform
In quantum mechanics, the Wigner–Weyl transform or Weyl–Wigner transform (after Hermann Weyl and Eugene Wigner) is the invertible mapping between functions in the quantum phase space formulation and Hilbert space operators in the Schrödinger picture. Often the mapping from functions on phase space to operators is called the Weyl transform or Weyl quantization, whereas the inverse mapping, from operators to functions on phase space, is called the Wigner transform. This mapping was originally devised by Hermann Weyl in 1927 in an attempt to map symmetrized ''classical'' phase space functions to operators, a procedure known as ''Weyl quantization''. It is now understood that Weyl quantization does not satisfy all the properties one would require for consistent quantization and therefore sometimes yields unphysical answers. On the other hand, some of the nice properties described below suggest that if one seeks a single consistent procedure mapping functions on the classica ...
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