Acetates
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Acetates
An acetate is a salt formed by the combination of acetic acid with a base (e.g. alkaline, earthy, metallic, nonmetallic, or radical base). "Acetate" also describes the conjugate base or ion (specifically, the negatively charged ion called an anion) typically found in aqueous solution and written with the chemical formula . The neutral molecules formed by the combination of the acetate ion and a ''positive'' ion (called a cation) are also commonly called "acetates" (hence, ''acetate of lead'', ''acetate of aluminium'', etc.). The simplest of these is hydrogen acetate (called acetic acid) with corresponding salts, esters, and the polyatomic anion , or . Most of the approximately 5 million tonnes of acetic acid produced annually in industry are used in the production of acetates, which usually take the form of polymers. In nature, acetate is the most common building block for biosynthesis. Nomenclature and common formula When part of a salt, the formula of the acetate ion is ...
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Acetic Acid
Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water. Historically, vinegar was produced from the third century BC and was likely the first acid to be produced in large quantities. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important Reagent, chemical reagent and industrial chemical across various fields, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood Adhesive, glue, and synthetic fibres and fabrics. In households, diluted acetic acid is often used in descaling agents. In the food industry, acetic acid is controlled by the E number, food additive code E260 as an acidity regulator and as a condiment. In biochemistry, the acetyl group, derived from acetic acid, is funda ...
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Aluminium Acetate
Aluminium acetate or aluminium ethanoate (also "aluminum ~"), sometimes abbreviated AlAc in geochemistry, can refer to a number of different salts of aluminium with acetic acid. In the solid state, three salts exist under this name: basic aluminium monoacetate, (HO)2AlCH3CO2, basic aluminium diacetate, HOAl(CH3CO2)2, and neutral aluminium triacetate, Al(CH3CO2)3. In aqueous solution, aluminium triacetate hydrolyses to form a mixture of the other two, and all solutions of all three can be referred to as "aluminium acetate" as the species formed co-exist and inter-convert in chemical equilibrium. Stoichiometry Monoacetate Aluminium monoacetate, also known as dibasic aluminium acetate, forms from Al(OH)3 and dilute aqueous acetic acid. More concentrated acid leads to the di- and triacetate. Diacetate Aluminium diacetate, also known as basic aluminium acetate, is prepared from aqueous aluminium acetate solution resulting in a white powder. This basic salt forms from the h ...
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Acetic Acid
Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water. Historically, vinegar was produced from the third century BC and was likely the first acid to be produced in large quantities. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important Reagent, chemical reagent and industrial chemical across various fields, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood Adhesive, glue, and synthetic fibres and fabrics. In households, diluted acetic acid is often used in descaling agents. In the food industry, acetic acid is controlled by the E number, food additive code E260 as an acidity regulator and as a condiment. In biochemistry, the acetyl group, derived from acetic acid, is funda ...
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Sodium Acetate
Sodium acetate, CH3COONa, also abbreviated Sodium, NaOxygen, OAcetyl, Ac, is the sodium Salt (chemistry), salt of acetic acid. This salt is colorless, deliquescent, and hygroscopy, hygroscopic. Applications Biotechnological Sodium acetate is used as the carbon source (biology) , carbon source for culturing Bacterial growth, bacteria. Sodium acetate can also be useful for increasing yields of DNA extraction, DNA isolation by ethanol precipitation. Industrial Sodium acetate is used in the textile industry to neutralize sulfuric acid waste streams and also as a photoresist while using aniline dyes. It is also a pickling (metal), pickling agent in chrome Tanning (leather), tanning and helps to impede vulcanization of chloroprene in synthetic rubber production. It is also used to reduce static electricity during production of disposable cotton pads. Concrete longevity Sodium acetate is used as a sealant to mitigate water damage to concrete. It is environm ...
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Chromium(II) Acetate
Chromium(II) acetate hydrate, also known as chromous acetate, is the coordination compound with the chemical formula, formula Cr2(CH3CO2)4(H2O)2. This formula is commonly abbreviated Cr2(OAc)4(H2O)2. This red-coloured compound features a quadruple bond. It exists as the dihydrate and the anhydrous forms. Both are diamagnetic. Cr2(OAc)4(H2O)2 is a reddish diamagnetic powder, although diamond-shaped tabular crystals can be grown. Consistent with the fact that it is nonionic, Cr2(OAc)4(H2O)2 exhibits poor solubility in water and methanol. Structure The Cr2(OAc)4(H2O)2 molecule contains two atoms of chromium, two ligand, ligated molecules of water, and four acetate bridging ligands. The coordination environment around each chromium atom consists of four oxygen atoms (one from each acetate ligand) in a square, one water molecule (in an axial position), and the other chromium atom (opposite the water molecule), giving each chromium centre an Octahedral molecular geometry, octahedral ...
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Actinide
The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part of the 6d transition series. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC nomenclature of inorganic chemistry, IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Actinium through nobelium are f-block elements, while lawrencium is a d-block element and a transition metal. The series mostly corresponds to the filling of the 5f electron shell, although as isolated atoms in the ground state many have anomalous configu ...
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Ethyl Acetate
Ethyl acetate commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula , simplified to . This flammable, colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues, nail polish removers, and the decaffeination process of tea and coffee. Ethyl acetate is the ester of ethanol and acetic acid; it is manufactured on a large scale for use as a solvent. Production and synthesis Ethyl acetate was first synthesized by the Louis-Léon de Brancas, Count de Lauraguais in 1759 by distilling a mixture of ethanol and acetic acid. In 2004, an estimated 1.3 million tonnes were produced worldwide. The combined annual production in 1985 of Japan, North America, and Europe was about 400,000 tonnes. The global ethyl acetate market was valued at $3.3 billion in 2018. Ethyl acetate is produced in industry mainly via the classic Fischer esterification reaction of ethanol and acetic acid. This mixture converts to the ester in about 65% ...
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Acetyl
In organic chemistry, an acetyl group is a functional group denoted by the chemical formula and the structure . It is sometimes represented by the symbol Ac (not to be confused with the element actinium). In IUPAC nomenclature, an acetyl group is called an ethanoyl group. An acetyl group contains a methyl group () that is single-bonded to a carbonyl (), making it an acyl group. The carbonyl center of an acyl radical has one non-bonded electron with which it forms a chemical bond to the remainder (denoted with the letter ''R'') of the molecule. The acetyl moiety is a component of many organic compounds, including acetic acid, the neurotransmitter acetylcholine, acetyl-CoA, acetylcysteine, acetaminophen (also known as paracetamol), and acetylsalicylic acid (also known as aspirin). Acetylation Acetylation is the chemical reaction known as "ethanoylation" in the IUPAC nomenclature. It depicts a reactionary process that injects an acetyl functional group into a chemical ...
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Pseudoelement Symbol
The skeletal formula, line-angle formula, bond-line formula or shorthand formula of an organic compound is a type of minimalist structural formula representing a molecule's atoms, bonds and some details of its geometry. The lines in a skeletal formula represent bonds between carbon atoms, unless labelled with another element. Labels are optional for carbon atoms, and the hydrogen atoms attached to them. An early form of this representation was first developed by organic chemist August Kekulé, while the modern form is closely related to and influenced by the Lewis structure of molecules and their valence electrons. Hence they are sometimes termed Kekulé structures or Lewis–Kekulé structures. Skeletal formulas have become ubiquitous in organic chemistry, partly because they are relatively quick and simple to draw, and also because the curved arrow notation used for discussions of reaction mechanisms and electron delocalization can be readily superimposed. Several oth ...
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Actinium
Actinium is a chemical element; it has chemical symbol, symbol Ac and atomic number 89. It was discovered by Friedrich Oskar Giesel in 1902, who gave it the name ''emanium''; the element got its name by being wrongly identified with a substance André-Louis Debierne found in 1899 and called actinium. The actinide series, a set of 15 elements between actinium and lawrencium in the periodic table, are named for actinium. Together with polonium, radium, and radon, actinium was one of the first Primordial element, non-primordial radioactive elements to be discovered. A soft, silvery-white radioactive metal, actinium reacts rapidly with oxygen and moisture in air forming a white coating of actinium oxide that prevents further oxidation. As with most lanthanides and many actinides, actinium assumes oxidation state +3 in nearly all its chemical compounds. Actinium is found only in traces in uranium and thorium ores as the isotope 227Ac, which decays with a half-life of 21.772 years, ...
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Ball-and-stick Model
In chemistry, the ball-and-stick model is a molecular model of a chemical substance which displays both the Molecular geometry, three-dimensional position of the atoms and the chemical bond, bonds between them. The atoms are typically represented by sphere (geometry), spheres, connected by rods which represent the bonds. Double bond, Double and triple bonds are usually represented by two or three curved rods, respectively, or alternately by correctly positioned sticks for the sigma bond, sigma and pi bonds. In a good model, the angles between the rods should be the same as the Bond angle, angles between the bonds, and the distances between the centers of the spheres should be proportional to the distances between the corresponding atomic nucleus, atomic nuclei. The chemical element of each atom is often indicated by the sphere's color. In a ball-and-stick model, the radius of the spheres is usually much smaller than the rod lengths, in order to provide a clearer view of the atoms ...
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Peracetic Acid
Peracetic acid (also known as peroxyacetic acid, or Percidine) is an organic compound with the formula CH3CO3H. This peroxy acid is a colorless liquid with a characteristic acrid odor reminiscent of acetic acid. It can be highly corrosive. Peracetic acid is a weaker acid than the parent acetic acid, with a p''K''a of 8.2. Production Peracetic acid is produced industrially by the autoxidation of acetaldehyde: :O2 + CH3CHO → CH3CO3H Peracetic acid is conventionally prepared by combining acetic acid and hydrogen peroxide with homogeneous acid catalysts (e.g., sulfuric acid), which facilitate the reaction and achieve equilibrium between the reagents and product: :H2O2 + CH3CO2H CH3CO3H + H2O While it is feasible to create peracetic acid by combining consumer-grade vinegar (5% acetic acid) and hydrogen peroxide (3%) without an acid catalyst, the low concentration of reagents will result in a slow reaction rate at room temperature. Extrapolating from published reaction rates, th ...
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