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Buckminsterfullerene Intercalates
Fullerides are chemical compounds containing fullerene anions. Common fullerides are derivatives of the most common fullerenes, i.e. C60 and C70. The scope of the area is large because multiple charges are possible, i.e., 60sup>''n''− (''n'' = 1, 2...6), and all fullerenes can be converted to fullerides. The suffix "-ide" implies their negatively charged nature. Fullerides can be isolated as derivatives with a wide range of cations. Most heavily studied derivatives are those with alkali metals, but fullerides have been prepared with organic cations. Fullerides are typically dark colored solids that generally dissolve in polar organic solvents. Structure and bonding According to electronic structure calculations, the LUMO of C60 is a triply degenerate orbital of t1u symmetry. Using the technique cyclic voltammetry, C60 can be shown to undergo six reversible reductions starting at −1 V referenced to the Fc+/Fc couple. Reduction causes only subtle changes in the struc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intercalation (chemistry)
Intercalation is the reversible inclusion or insertion of a molecule (or ion) into layered materials with layered structures. Examples are found in graphite and transition metal dichalcogenides. : Examples Graphite One famous intercalation host is graphite, which intercalates potassium as a guest. Intercalation expands the van der Waals gap between sheets, which requires energy. Usually this energy is supplied by charge transfer between the guest and the host solid, i.e., redox. Two potassium graphite compounds are KC8 and KC24. Carbon fluorides (e.g., (CF)x and (C4F)) are prepared by reaction of fluorine with graphitic carbon. The color is greyish, white, or yellow. The bond between the carbon and fluorine atoms is covalent, thus fluorine is not intercalated. Such materials have been considered as a cathode in various lithium batteries. Treating graphite with strong acids in the presence of oxidizing agents causes the graphite to oxidise. Graphite bisulfate, 24sup>+ SO4sup ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mott Transition
Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators (particularly at low temperatures). These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model. The band gap in a Mott insulator exists between bands of like character, such as 3d electron bands, whereas the band gap in charge-transfer insulators exists between anion and cation states. History Although the band theory of solids had been very successful in describing various electrical properties of materials, in 1937 Jan Hendrik de Boer and Evert Johannes Willem Verwey pointed out that a variety of transitio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Density Of States
In condensed matter physics, the density of states (DOS) of a system describes the number of allowed modes or quantum state, states per unit energy range. The density of states is defined as where N(E)\delta E is the number of states in the system of volume V whose energies lie in the range from E to E+\delta E. It is mathematically represented as a distribution by a probability density function, and it is generally an average over the space and time domains of the various states occupied by the system. The density of states is directly related to the dispersion relations of the properties of the system. High DOS at a specific energy level means that many states are available for occupation. Generally, the density of states of matter is continuous. In isolated systems however, such as atoms or molecules in the gas phase, the density distribution is Discrete distribution, discrete, like a spectral density. Local variations, most often due to distortions of the original system, are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
BCS Theory
In physics, the Bardeen–Cooper–Schrieffer (BCS) theory (named after John Bardeen, Leon Cooper, and John Robert Schrieffer) is the first microscopic theory of superconductivity since Heike Kamerlingh Onnes's 1911 discovery. The theory describes superconductivity as a microscopic effect caused by a condensation of Cooper pairs. The theory is also used in nuclear physics to describe the pairing interaction between nucleons in an atomic nucleus. It was proposed by Bardeen, Cooper, and Schrieffer in 1957; they received the Nobel Prize in Physics for this theory in 1972. History Rapid progress in the understanding of superconductivity gained momentum in the mid-1950s. It began with the 1948 paper, "On the Problem of the Molecular Theory of Superconductivity", where Fritz London proposed that the phenomenological London equations may be consequences of the coherence of a quantum state. In 1953, Brian Pippard, motivated by penetration experiments, proposed that this would mo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nature Materials
''Nature Materials'' is a monthly peer-reviewed scientific journal published by Nature Portfolio. It was launched in September 2002. Vincent Dusastre is the launching and current chief editor. Aims and scope ''Nature Materials'' is focused on all topics within the combined disciplines of ''materials science'' and ''engineering''. Topics published in the journal are presented from the view of the impact that materials research has on other scientific disciplines such as (for example) physics, chemistry, and biology. Coverage in this journal encompasses fundamental research and applications from synthesis to processing, and from structure to composition. Coverage also includes basic research and applications of properties and performance of materials. Materials are specifically described as "substances in the condensed states (liquid, solid, colloidal)", and which are "designed or manipulated for technological ends." Furthermore, ''Nature Materials'' functions as a forum for the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Caesium
Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoricity, pyrophoric and reacts with water even at . It is the least electronegativity, electronegative stable element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. Caesium-137, a fission product, is extracted from waste produced by nuclear reactor technology, nuclear reactors. It has the largest atomic radius of all elements whose radii have been measured or calculated, at about 260 picometres. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the new ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Review B
''Physical Review B: Condensed Matter and Materials Physics'' (also known as PRB) is a peer-reviewed, scientific journal, published by the American Physical Society (APS). The Lead Editor of PRB is Stephen E. Nagler and the Chief Editor is Sarma Kancharla. It is part of the '' Physical Review'' family of journals. About the Physical Review Journals The current Editor in Chief is Randall Kamien. PRB currently publishes over 5000 papers a year, making it one of the largest physics journals in the world. PRB ranked by the Eigenfactor, University of Washington, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Science (journal)
''Science'' is the peer review, peer-reviewed academic journal of the American Association for the Advancement of Science (AAAS) and one of the world's top academic journals. It was first published in 1880, is currently circulated weekly and has a subscriber base of around 130,000. Because institutional subscriptions and online access serve a larger audience, its estimated readership is over 400,000 people. ''Science'' is based in Washington, D.C., United States, with a second office in Cambridge, UK. Contents The major focus of the journal is publishing important original scientific research and research reviews, but ''Science'' also publishes science-related news, opinions on science policy and other matters of interest to scientists and others who are concerned with the wide implications of science and technology. Unlike most scientific journals, which focus on a specific field, ''Science'' and its rival ''Nature (journal), Nature'' cover the full range of List of academ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Review Letters
''Physical Review Letters'' (''PRL''), established in 1958, is a peer-reviewed, scientific journal that is published 52 times per year by the American Physical Society. The journal is considered one of the most prestigious in the field of physics. Over a quarter of Physics Nobel Prize-winning papers between 1995 and 2017 were published in it. ''PRL'' is published both online and as a print journal. Its focus is on short articles ("letters") intended for quick publication. The Lead Editor is Hugues Chaté. The Managing Editor is Robert Garisto. History The journal was created in 1958. Samuel Goudsmit, who was then the editor of '' Physical Review'', the American Physical Society's flagship journal, organized and published ''Letters to the Editor of Physical Review'' into a new standalone journal'','' which became ''Physical Review Letters''. It was the first journal intended for the rapid publication of short articles, a format that eventually became popular in many other fiel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nature (journal)
''Nature'' is a British weekly scientific journal founded and based in London, England. As a multidisciplinary publication, ''Nature'' features Peer review, peer-reviewed research from a variety of academic disciplines, mainly in science and technology. It has core editorial offices across the United States, continental Europe, and Asia under the international scientific publishing company Springer Nature. ''Nature'' was one of the world's most cited scientific journals by the Science Edition of the 2022 ''Journal Citation Reports'' (with an ascribed impact factor of 50.5), making it one of the world's most-read and most prestigious academic journals. , it claimed an online readership of about three million unique readers per month. Founded in the autumn of 1869, ''Nature'' was first circulated by Norman Lockyer and Alexander MacMillan (publisher), Alexander MacMillan as a public forum for scientific innovations. The mid-20th century facilitated an editorial expansion for the j ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Body-centered Cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the Crystal structure#Unit cell, unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc) Note: the term fcc is often used in synonym for the Close-packing of equal spheres, ''cubic close-packed'' or ccp structure occurring in metals. However, fcc stands for a face-centered cubic Bravais lattice, which is not necessarily close-packed when a motif is set onto the lattice points. E.g. the diamond and the zincblende lattices are fcc but not close-packed. Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive cell, primitiv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
