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Alloy Broadening
Alloy broadening is a mechanism by which the spectral lines of an alloy are broadened by the random distribution of atoms within the alloy. It is one of a number of spectral line broadening mechanisms. Alloy broadening occurs because the random distribution of atoms in an alloy causes a different material composition at different positions. In semiconductors and insulators the different material composition leads to different band gap energies. This gives different exciton recombination energies. Therefore, depending on the position where an exciton recombines the emitted light has a different energy. The alloy broadening is an inhomogeneous line broadening, meaning that its shape is Gaussian. Binary alloy In the mathematical description it is assumed that no clustering occurs within the alloy. Then, for a binary alloy of the form A_B_, e.g. Si_Ge_, the standard deviation of the composition is given by: :\Delta x = \sqrt, where N is the number of atoms within the excitons' v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Lines
A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible. Types of line spectra Spectral lines are the result of interaction between a quantum system (usually atoms, but sometimes molecules or atomic nuclei) and a single photon. When a photon has about the right amount of energy (which is connected to its frequency) to allow a change in the energy state of the system (in the case of an atom this is usually an electron changing orbitals), the photon is absorbed. Then the energy will be spontaneously re-emitted, either as one photon at the same ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Line
A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission (electromagnetic radiation), emission or absorption (electromagnetic radiation), absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible. Types of line spectra Spectral lines are the result of interaction between a Quantum mechanics, quantum system (usually atoms, but sometimes molecules or atomic nucleus, atomic nuclei) and a single photon. When a photon has about the right amount of photon energy, energy (which is connected to its frequency) to allow a change in the energy state of the system (in the case of an atom this is usually an electron cha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atom
Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element. Atoms are extremely small, typically around 100 picometers across. A human hair is about a million carbon atoms wide. Atoms are smaller than the shortest wavelength of visible light, which means humans cannot see atoms with conventional microscopes. They are so small that accurately predicting their behavior using classical physics is not possible due to quantum mechanics, quantum effects. More than 99.94% of an atom's mass is in the nucleus. Protons hav ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called " metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Band Gap Energy
In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to the energy difference (often expressed in electronvolts) between the top of the valence band and the bottom of the conduction band in insulators and semiconductors. It is the energy required to promote an electron from the valence band to the conduction band. The resulting conduction-band electron (and the electron hole in the valence band) are free to move within the crystal lattice and serve as charge carriers to conduct electric current. It is closely related to the HOMO/LUMO gap in chemistry. If the valence band is completely full and the conduction band is completely empty, then electrons cannot move within the solid because there are no available states. If the electrons are not free to move within the crystal lattice, then there is no ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Exciton
An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb's law, Coulomb force resulting from their opposite charges. It is an electrically neutral quasiparticle regarded as an elementary excitation primarily in condensed matter, such as Electrical insulation, insulators, semiconductors, some metals, and in some liquids. It transports energy without transporting net electric charge. An exciton can form when an electron from the valence band of a crystal is promoted in energy to the conduction band e.g., when a material absorbs a photon. Promoting the electron to the conduction band leaves a positively charged hole in the valence band. Here 'hole' represents the unoccupied quantum mechanical electron state with a positive charge, an analogue in crystal of a positron. Because of the attractive coulomb force between the electron and the hole, a bound state is formed, akin to that of the electron and proton in a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inhomogeneous Broadening
Homogeneous broadening is a type of emission spectrum broadening in which all atoms radiating from a specific level under consideration radiate with equal opportunity. If an optical emitter (e.g. an atom) shows homogeneous broadening, its spectral linewidth is its natural linewidth, with a Lorentzian profile. Broadening in laser systems Broadening in laser physics is a physical phenomenon that affects the spectroscopic line shape of the laser emission profile. The laser emission is due to the (excitation and subsequent) relaxation of a quantum system (atom, molecule, ion, etc.) between an excited state (higher in energy) and a lower one. These states can be thought of as the eigenstates of the energy operator. The difference in energy between these states is proportional to the frequency/wavelength of the photon emitted. Since this energy difference has a fluctuation, then the frequency/wavelength of the "macroscopic emission" (the beam) will have a certain width (i.e. it will b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Standard Deviation
In statistics, the standard deviation is a measure of the amount of variation of the values of a variable about its Expected value, mean. A low standard Deviation (statistics), deviation indicates that the values tend to be close to the mean (also called the expected value) of the set, while a high standard deviation indicates that the values are spread out over a wider range. The standard deviation is commonly used in the determination of what constitutes an outlier and what does not. Standard deviation may be abbreviated SD or std dev, and is most commonly represented in mathematical texts and equations by the lowercase Greek alphabet, Greek letter Sigma, σ (sigma), for the population standard deviation, or the Latin script, Latin letter ''s'', for the sample standard deviation. The standard deviation of a random variable, Sample (statistics), sample, statistical population, data set, or probability distribution is the square root of its variance. (For a finite population, v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorescence
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colored visible light. The color of the light emitted depends on the chemical composition of the substance. Fluorescent materials generally cease to glow nearly immediately when the radiation source stops. This distinguishes them from the other type of light emission, phosphorescence. Phosphorescent materials continue to emit light for some time after the radiation stops. This difference in duration is a result of quantum spin effects. Fluorescence occurs when a photon from incoming radiation is absorbed by a molecule, exciting it to a higher energy level, followed by the emission of light as the molecule returns to a lower energy state. The emitted light may have a longer wavelength and, therefore, a lower photon energy than the absorbed radi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Line Shape
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentz distribution, Lorentzian, Normal distribution, Gaussian and Voigt function, Voigt functions, whose parameters are the line position, maximum height and half-width. Actual line shapes are determined principally by Doppler broadening, Doppler, Spectral line#Broadening and shift, collision and proximity broadening. For each system the half-width of the shape function varies with temperature, pressure (or concentration (chemistry), concentration) and phase. A knowledge of shape function is needed for spectroscopic curve fitting and deconvolution. Origins A spectral line can result from an electron transition in an atom, molecule or ion, which is associated with a specific amount of energy, ''E''. When this energy is measured by means of some spectroscopic te ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
