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Adatom
An adatom is an atom that lies on a crystal surface, and can be thought of as the opposite of a surface vacancy. This term is used in surface chemistry and epitaxy, when describing single atoms lying on surfaces and surface roughness. The word is a portmanteau of " adsorbed atom". A single atom, a cluster of atoms, or a molecule or cluster of molecules may all be referred to by the general term " adparticle". This is often a thermodynamically unfavorable state. However, cases such as graphene may provide counter-examples. Growth ″Adatom″ is a portmanteau word, short for adsorbed atom. When the atom arrives at a crystal surface, it is adsorbed by the periodic potential of the crystal, thus becoming an adatom. The minima of this potential form a network of adsorption sites on the surface. There are different types of adsorption sites. Each of these sites corresponds to a different structure of the surface. There are five different types of adsorption sites, which are: o ...
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Terrace Ledge Kink Model
In chemistry, the terrace ledge kink (TLK) model, which is also referred to as the terrace step kink (TSK) model, describes the thermodynamics of crystal surface formation and transformation, as well as the energetics of surface defect formation. It is based upon the idea that the energy of an atom’s position on a crystal surface is determined by its bonding to neighboring atoms and that transitions simply involve the counting of broken and formed bonds. The TLK model can be applied to surface science topics such as crystal growth, surface diffusion, roughening, and vaporization. History The TLK model is credited as having originated from papers published in the 1920s by the German chemist Walther Kossel and the Bulgarian chemist Ivan Stranski Definitions Depending on the position of an atom on a surface, it can be referred to by one of several names. Figure 1 illustrates the names for the atomic positions and point defects on a surface for a simple cubic lattice. Fi ...
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Adsorption
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). While adsorption does often precede absorption, which involves the transfer of the absorbate into the volume of the absorbent material, alternatively, adsorption is distinctly a surface phenomenon, wherein the adsorbate does not penetrate through the material surface and into the bulk of the adsorbent. The term '' sorption'' encompasses both adsorption and absorption, and ''desorption'' is the reverse of sorption. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in ...
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Sticking Coefficient
Sticking coefficient is the term used in surface physics to describe the ratio of the number of adsorbate atoms (or molecules) that Adsorption, adsorb, or "stick", to a surface to the total number of atoms that impinge upon that surface during the same period of time. Sometimes the symbol Sc is used to denote this coefficient, and its value is between 1 (all impinging atoms stick) and 0 (no atoms stick). The coefficient is a function of surface temperature, surface coverage (θ) and Structure, structural details as well as the kinetic energy of the impinging particles. The original formulation was for molecules adsorbing from the gas phase and the equation was later extended to adsorption from the liquid phase by comparison with molecular dynamics simulations. For use in adsorption from liquids the equation is expressed based on solute density (molecules per volume) rather than the pressure. Derivation When arriving at a site of a surface, an Adatoms, adatom has three option ...
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Atom
Atoms are the basic particles of the chemical elements. An atom consists of a atomic nucleus, nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element. Atoms are extremely small, typically around 100 picometers across. A human hair is about a million carbon atoms wide. Atoms are smaller than the shortest wavelength of visible light, which means humans cannot see atoms with conventional microscopes. They are so small that accurately predicting their behavior using classical physics is not possible due to quantum mechanics, quantum effects. More than 99.94% of an atom's mass is in the nucleus. Protons hav ...
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Fundamental Interaction
In physics, the fundamental interactions or fundamental forces are interactions in nature that appear not to be reducible to more basic interactions. There are four fundamental interactions known to exist: * gravity * electromagnetism * weak interaction * strong interaction The gravitational and electromagnetic interactions produce long-range forces whose effects can be seen directly in everyday life. The strong and weak interactions produce forces at subatomic scales and govern nuclear interactions inside atoms. Some scientists hypothesize that a fifth force might exist, but these hypotheses remain speculative. Each of the known fundamental interactions can be described mathematically as a '' field''. The gravitational interaction is attributed to the curvature of spacetime, described by Einstein's general theory of relativity. The other three are discrete quantum fields, and their interactions are mediated by elementary particles described by the Standard Model of particl ...
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Magnetic Field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, electric currents, and electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function (mathematics), function assigning a Euclidean vector, vector to each point of space, ...
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Magnetic Moment
In electromagnetism, the magnetic moment or magnetic dipole moment is the combination of strength and orientation of a magnet or other object or system that exerts a magnetic field. The magnetic dipole moment of an object determines the magnitude of torque the object experiences in a given magnetic field. When the same magnetic field is applied, objects with larger magnetic moments experience larger torques. The strength (and direction) of this torque depends not only on the magnitude of the magnetic moment but also on its orientation relative to the direction of the magnetic field. Its direction points from the south pole to the north pole of the magnet (i.e., inside the magnet). The magnetic moment also expresses the magnetic force effect of a magnet. The magnetic field of a magnetic dipole is proportional to its magnetic dipole moment. The dipole component of an object's magnetic field is symmetric about the direction of its magnetic dipole moment, and decreases as the inverse ...
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Electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up quark, up and down quark, down quarks. Electrons are extremely lightweight particles that orbit the positively charged atomic nucleus, nucleus of atoms. Their negative charge is balanced by the positive charge of protons in the nucleus, giving atoms their overall electric charge#Charge neutrality, neutral charge. Ordinary matter is composed of atoms, each consisting of a positively charged nucleus surrounded by a number of orbiting electrons equal to the number of protons. The configuration and energy levels of these orbiting electrons determine the chemical properties of an atom. Electrons are bound to the nucleus to different degrees. The outermost or valence electron, valence electrons are the least tightly bound and are responsible for th ...
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Face-centered Cubic Lattice
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc) Note: the term fcc is often used in synonym for the ''cubic close-packed'' or ccp structure occurring in metals. However, fcc stands for a face-centered cubic Bravais lattice, which is not necessarily close-packed when a motif is set onto the lattice points. E.g. the diamond and the zincblende lattices are fcc but not close-packed. Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais latices in ...
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Ivan Stranski
Ivan Nikolov Stranski (; ; – 19 June 1979) was a Bulgarian and later a German physical chemist who is considered the father of crystal growth research. He was the founder of the Bulgarian school of physical chemistry, heading the departments of physical chemistry at Sofia University and later at ''Technische Hochschule Berlin'' (today Technische Universität Berlin), of which he was also rector. The Stranski–Krastanov growth and Kossel–Stranski model are some of Stranski's contributions which bear his name. Biography Early life and studies Ivan Stranski was born on 21 December 1896 O.S. (2 January 1897 N.S.) in Sofia, the capital of the Principality of Bulgaria, the third child of Nikola Stranski (1854 - 1910), pharmacist to the royal court, and his wife Maria Krohn, a Baltic German.* Ever since his childhood he suffered from bone tuberculosis, an incurable disease at the time. Stranski finished the First Sofia High School for Boys. Seeking ways to fight ...
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Walther Kossel
Walther Ludwig Julius Kossel (; 4 January 1888 – 22 May 1956) was a German chemist and physicist known for his theory of the chemical bond (ionic bond/octet rule), Sommerfeld–Kossel displacement law of atomic spectra, the Kossel–Stranski model for crystal growth, and the Kossel effect. Walther was the son of Albrecht Kossel who won the Nobel Prize in Physiology or Medicine in 1910. Career Kossel was born in Berlin, and began studies at the University of Heidelberg in 1906, but was at the University of Berlin during 1907 and 1908. In 1910, he became assistant to Philipp Lenard, who was also his thesis advisor. Kossel was awarded his Ph.D. in 1910, and he stayed on as assistant to Leonard until 1913. In 1913, the year in which Niels Bohr introduced the Bohr model of the atom, Kossel went to the University of Munich as assistant to Arnold Sommerfeld, under whom he did his Habilitation. Under Sommerfeld, Munich was a theoretical center for the developing atomic theory, e ...
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