Actinium Oxyfluoride
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Actinium Oxyfluoride
Actinium oxyfluoride is an inorganic compound, with the chemical formula AcOF. It is radioactive. It crystallises in a calcium fluoride structure. It can be obtained by reacting actinium fluoride with ammonia and water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...: : AcF3 + 2 NH3 + H2O → AcOF + 2 NH4F The reaction proceeds completely at 1200 °C, and unreacted AcF3 will remain at lower temperatures. Notes References {{Fluorine compounds Actinium compounds Oxyfluorides ...
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Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc) Note: the term fcc is often used in synonym for the ''cubic close-packed'' or ccp structure occurring in metals. However, fcc stands for a face-centered cubic Bravais lattice, which is not necessarily close-packed when a motif is set onto the lattice points. E.g. the diamond and the zincblende lattices are fcc but not close-packed. Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais latices ...
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Calcium Fluoride
Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white solid that is practically insoluble in water. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities. Chemical structure The compound crystallizes in a cubic motif called the fluorite structure. Ca2+ centres are eight-coordinate, being centred in a cube of eight F− centres. Each F− centre is coordinated to four Ca2+ centres in the shape of a tetrahedron. Although perfectly packed crystalline samples are colorless, the mineral is often deeply colored due to the presence of F-centers. The same crystal structure is found in numerous ionic compounds with formula AB2, such as CeO2, cubic ZrO2, UO2, ThO2, and PuO2. In the corresponding anti-structure, called the antifluorite structure, anions and cations are swapped, such as Be2C. Gas phase The gas phase is noteworthy for failing the predictions of VSEP ...
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Actinium Fluoride
Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine. Synthesis Actinium fluoride can be prepared in solution or by a solid-state reaction. In the first method, actinium hydroxide is treated with hydrofluoric acid and the product precipitates: : In the solid-state reaction, actinium metal is treated with hydrogen fluoride gas at 700 °C in a platinum crucible.Meyer, Gerd and Morss, Lester R. (1991) ''Synthesis of lanthanide and actinide compounds.'' Springer. . pp. 87–88 Properties Actinium fluoride is a white solid that reacts with ammonia at 900–1000 °C to yield an actinium oxyfluoride: : While lanthanum oxyfluoride is easily formed by heating lanthanum fluoride Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is . The LaF3 structure Bonding is ionic with lanthanum highly coordinated. The cation sits at the center of a trigonal prism. Nine fluorine ... in air, a ...
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Ammonia
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. It is widely used in fertilizers, refrigerants, explosives, cleaning agents, and is a precursor for numeous chemicals. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. Around 70% of ammonia produced industrially is used to make fertilisers in various forms and composition, such as urea and diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many chemicals. In many countries, it is classified as an List of extremely hazardous substances, extremely hazardous substance. Ammonia is toxic, cau ...
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Water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy or organic micronutrients. Its chemical formula, , indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. In liquid form, is also called "water" at standard temperature and pressure. Because Earth's environment is relatively close to water's triple point, water exists on Earth as a solid, a liquid, and a gas. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice ...
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Ammonium Fluoride
Ammonium fluoride is the inorganic compound with the formula NH4F. It crystallizes as small colourless prisms, having a sharp saline taste, and is highly soluble in water. Like all fluoride salts, it is moderately toxic in both acute and chronic overdose. Crystal structure Ammonium fluoride adopts the wurtzite crystal structure, in which both the ammonium cations and the fluoride anions are stacked in ABABAB... layers, each being tetrahedrally surrounded by four of the other. There are N−H···F hydrogen bonds between the anions and cations. This structure is very similar to ice, and ammonium fluoride is the only substance which can form mixed crystals with water. Reactions On passing hydrogen fluoride gas (in excess) through the salt, ammonium fluoride absorbs the gas to form the addition compound ammonium bifluoride. The reaction occurring is: :NH4F + HF → NH4HF2 Ammonium fluoride sublimes when heated—a property common among ammonium salts. In the sublimation, the salt ...
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Actinium Compounds
Actinium compounds are compounds containing the element actinium (Ac). Due to actinium's intense radioactivity, only a limited number of actinium compounds are known. These include: Actinium fluoride, AcF3, Actinium(III) chloride, AcCl3, Actinium(III) bromide, AcBr3, AcOF, AcOCl, AcOBr, Actinium(III) sulfide, Ac2S3, Actinium oxide, Ac2O3, Actinium(III) phosphate, AcPO4 and Actinium(III) nitrate, Ac(NO3)3. Except for AcPO4, they are all similar to the corresponding lanthanum compounds. They all contain actinium in the oxidation state +3.Actinium
Great Soviet Encyclopedia (in Russian)
In particular, the lattice constants of the analogous lanthanum and actinium compounds differ by only a few percent.


Properties of actinium compounds

Here ''a'', ''b'' and ''c'' are lattice constants, No is ...
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