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1855 In Science
The year 1855 in science and technology involved some significant events, listed below. Biology * September – Alfred Russel Wallace publishes "On the Law which has Regulated the Introduction of New Species", which he has written while working in Sarawak on the island of Borneo in February; in December, Edward Blyth brings it to the attention of Charles Darwin. * Robert Remak publishes ''Untersuchungen über die Entwickelung der Wirbelthiere'' in Berlin, providing evidence for cell division, which is supported (but not acknowledged) by Rudolf Virchow. Cartography * September – Rev. James Patterson presents the Gall orthographic projection for celestial and terrestrial equal-area cartography. Chemistry * May 10 – The Bunsen burner is invented by Robert Wilhelm Bunsen. * Friedrich Gaedcke first isolates the cocaine alkaloid, which he names "erythroxyline". * William Odling proposes a methane type ( tetravalent) for carbon. * Charles-Adolphe Wurtz publishes the Wurtz re ...
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Glasgow
Glasgow is the Cities of Scotland, most populous city in Scotland, located on the banks of the River Clyde in Strathclyde, west central Scotland. It is the List of cities in the United Kingdom, third-most-populous city in the United Kingdom and the 27th-most-populous city in Europe, and comprises Wards of Glasgow, 23 wards which represent the areas of the city within Glasgow City Council. Glasgow is a leading city in Scotland for finance, shopping, industry, culture and fashion, and was commonly referred to as the "second city of the British Empire" for much of the Victorian era, Victorian and Edwardian eras. In , it had an estimated population as a defined locality of . More than 1,000,000 people live in the Greater Glasgow contiguous urban area, while the wider Glasgow City Region is home to more than 1,800,000 people (its defined functional urban area total was almost the same in 2020), around a third of Scotland's population. The city has a population density of 3,562 p ...
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Annales De Chimie Et De Physique
__NOTOC__ ''Annales de chimie et de physique'' (, ) is a scientific journal founded in Paris, France, in 1789 under the title ''Annales de chimie''. One of the early editors was the French chemist Antoine Lavoisier. Lavoisier, an aristocrat, was guillotined in May 1794, ostensibly for tax fraud: and the journal was not published from 1794 to 1796 while the Reign of Terror was at its height under the French Directory. In 1815, it became the ''Annales de chimie et de physique'', and was published under that name for the next 100 years. In 1914, it split into two successor journals. The first one, '' Annales de physique'', was latterly published by EDP Sciences under the same name up to 2009, when it became integrated in the '' European Physical Journal'' series as the '' European Physical Journal H – Historical Perspectives on Contemporary Physics''. The second successor, ''Annales de chimie'', later became '' Annales de chimie: Science des matériaux'' in 1978; from 1998 to 20 ...
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Wurtz Reaction
In organic chemistry, the Wurtz reaction, named after Charles Adolphe Wurtz, is a coupling reaction in which two alkyl halides are treated with sodium metal to form a higher alkane. : 2 R−X + 2 Na → R−R + 2 NaX The reaction is of little value because yields are low. Exceptions are some intramolecular versions, such as 1,6-dibromohexane + 2 Na → cyclohexane + 2 NaBr. A related reaction, which combines alkyl halides with aryl halides is called the Wurtz–Fittig reaction. Despite its very modest utility, the Wurtz reaction is widely cited as representative of reductive coupling. Mechanism The reaction proceeds by an initial metal–halogen exchange, which is described with the following idealized stoichiometry: : R−X + 2 M → RM + MX This step may involve the intermediacy of radical species R·. The conversion resembles the formation of a Grignard reagent. The RM intermediates have been isolated in several cases. The radical is susceptible to diverse reactions. The or ...
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Charles-Adolphe Wurtz
Charles Adolphe Wurtz (; 26 November 181710 May 1884) was an Alsatian French chemist. He is best remembered for his decades-long advocacy for the atomic theory and for ideas about the structures of chemical compounds, against the skeptical opinions of chemists such as Marcellin Berthelot and Henri Étienne Sainte-Claire Deville. He is well known by organic chemists for the Wurtz reaction, to form carbon-carbon bonds by reacting alkyl halides with sodium, and for his discoveries of ethylamine, ethylene glycol, and the aldol reaction. Wurtz was also an influential writer and educator. Life Adolphe Wurtz (he never used the name "Charles") was born in Strasbourg, where his father, Johann Jacob (Jean Jacques) Wurtz, was a Lutheran pastor in the nearby town of Wolfisheim. His wife, Adolphe's mother, Sophie Kreiss, died in 1878. When he left the Protestant gymnasium at Strasbourg in 1834, his father allowed him to study medicine as next best to theology. He devoted himself specia ...
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Tetravalent
In chemistry, the valence (US spelling) or valency (British spelling) of an atom is a measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Valence is generally understood to be the number of chemical bonds that each atom of a given chemical element typically forms. Double bonds are considered to be two bonds, triple bonds to be three, quadruple bonds to be four, quintuple bonds to be five and sextuple bonds to be six. In most compounds, the valence of hydrogen is 1, of oxygen is 2, of nitrogen is 3, and of carbon is 4. Valence is not to be confused with the related concepts of the coordination number, the oxidation state, or the number of valence electrons for a given atom. Description The valence is the combining capacity of an atom of a given element, determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; ...
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Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an Organic chemistry, organic Organic compound, compound, and among the simplest of organic compounds. Methane is also a hydrocarbon. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the Atmosphere of Earth, atmosphere, it is known as atmospheric methane. ...
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William Odling
William Odling, FRS (5 September 1829 in Southwark, London – 17 February 1921 in Oxford) was an English chemist who contributed to the development of the periodic table.Carmen J. Giunta, Vera V. Mainz, and Julianna Poole-Sawyer (2020), "Periodicity in Britain: The Periodic Tables of Odling and Newlands" in ''150 Years of the Periodic Table'', Springer, pp. 93-131. In the 1860s Odling, like many chemists, was working towards classifying the elements, an effort that would eventually lead to the periodic table of elements. He was intrigued by atomic weights and the periodic occurrence of chemical properties. William Odling and Lothar Meyer drew up tables similar, but with improvements on, Dmitri Mendeleev's original table. Odling drew up a table of elements using repeating units of seven elements, which bears a striking resemblance to Mendeleev's first table. The groups are horizontal, the elements are in order of increasing atomic weight and there are vacant slots for undisc ...
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Archiv Der Pharmazie
The ''Archiv der Pharmazie'' (German pronunciation: [ˈ arˈçiːf ˈdeːɐ̯ farmaˈtsiː], English: ''Archive of Pharmacy'') is a monthly peer-reviewed scientific journal covering all aspects of chemistry in the life sciences. The journal was established in 1822 and is published by Wiley-VCH on behalf of the Deutsche Pharmazeutische Gesellschaft; it is the oldest German pharmaceutical journal still in publication. Until 2019, the editor-in-chief was Holger Stark (Heinrich Heine University Düsseldorf). He was succeeded in 2020 by Andreas Link (University of Greifswald). History The first edition appeared in 1822 under the name ''Archiv des Apothekervereins im nördlichen Teutschland für die Pharmacie und ihre Huelfswissenschaften'' (English: ''Archive of the Pharmacists' Association in Northern Germany for Pharmacy and its Auxiliary Sciences''). In 1832, the journal was merged with ''Liebigs Annalen'' (then known as ''Annalen der Pharmacie''), but would split from it following ...
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Alkaloid
Alkaloids are a broad class of natural product, naturally occurring organic compounds that contain at least one nitrogen atom. Some synthetic compounds of similar structure may also be termed alkaloids. Alkaloids are produced by a large variety of organisms including bacteria, fungus, fungi, Medicinal plant, plants, and animals. They can be purified from crude extracts of these organisms by acid-base extraction, or solvent extractions followed by silica-gel column chromatography. Alkaloids have a wide range of pharmacology, pharmacological activities including antimalarial medication, antimalarial (e.g. quinine), asthma, antiasthma (e.g. ephedrine), chemotherapy, anticancer (e.g. omacetaxine mepesuccinate, homoharringtonine), cholinomimetic (e.g. galantamine), vasodilation, vasodilatory (e.g. vincamine), Antiarrhythmic agent, antiarrhythmic (e.g. quinidine), analgesic (e.g. morphine), antibacterial (e.g. chelerythrine), and anti-diabetic, antihyperglycemic activities (e.g. berb ...
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Cocaine
Cocaine is a tropane alkaloid and central nervous system stimulant, derived primarily from the leaves of two South American coca plants, ''Erythroxylum coca'' and ''Erythroxylum novogranatense, E. novogranatense'', which are cultivated almost exclusively in the Andes. Indigenous peoples of South America, Indigenous South Americans have traditionally used coca leaves for over a thousand years. Notably, there is no evidence that habitual coca leaf use causes addiction or withdrawal, unlike cocaine. Medically, cocaine is rarely employed, mainly as a topical medication under controlled settings, due to its high abuse potential, adverse effects, and expensive cost. Despite this, recreational drug use, recreational use is widespread, driven by its euphoric and aphrodisiac properties. Levamisole induced necrosis syndrome (LINES)-a complication of the common cocaine Lacing (drugs), cutting agent levamisole-and prenatal cocaine exposure is particularly harmful. Street cocaine is ...
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Friedrich Gaedcke
Friedrich Georg Carl (Friedrich) Gaedcke (5 June 1828 – 19 September 1890) was a German chemist. He was the first person to isolate the cocaine alkaloid in 1855. Life Gaedcke worked in a pharmacy in Rostock and studied in Rostock between 1850 and 1851. In 1856, he took over a pharmacy in Dömitz which he ran for 34 years. He is described as having made contributions to the pharmaceutical history of Mecklenburg Discovery of Cocaine Working with coca Coca is any of the four cultivated plants in the family Erythroxylaceae, native to western South America. Coca is known worldwide for its psychoactive alkaloid, cocaine. Coca leaves contain cocaine which acts as a mild stimulant when chewed or ... leaves, Gaedcke isolated the cocaine molecule. Gaedcke named the alkaloid “erythroxyline,” and published a description in the journal Archiv der Pharmazie in 1855. He described the alkaloid as being of small crystal molecules with needle-like points on four to six sides. He repor ...
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