Concrete

Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminum combined. Globally, the ready-mix concrete industry, the largest segment of the concrete market, is projected to exceed $600 billion in revenue by 2025. This widespread use results in a number of environmental impacts. Most notably, the production process for cement produces large volumes of greenhouse gas emissions, leading to net 8% of global emissions. Other environmental concerns include widespread illegal sand mining, impacts on the surrounding environment such as increased surface runoff or urban heat island effect, and potential public health implications from toxic ingredients. Significant research and development is being done to try to reduce the emissions or make concrete a source of carbon sequestration, and increase recycled and secondary raw materials content into the mix to achieve a circular economy. Concrete is expected to be a key material for structures resilient to climate disasters, as well as a solution to mitigate the pollution of other industries, capturing wastes such as coal fly ash or bauxite tailings and residue.

When aggregate is mixed with dry Portland cement and water, the mixture forms a fluid slurry that is easily poured and molded into shape. The cement reacts with the water through a process calle
concrete hydration
that hardens over several hours to form a hard matrix that binds the materials together into a durable stone-like material that has many uses. This time allows concrete to not only be cast in forms but also to have a variety of tooled processes preformed. The hydration process is exothermic, which means ambient temperature plays a significant role in how long it takes concrete to set. Often, additives (such as pozzolans or superplasticizers) are included in the mixture to improve the physical properties of the wet mix, delay or accelerate the curing time, or otherwise change the finished material. Most concrete is poured with reinforcing materials (such as rebar) embedded to provide tensile strength, yielding reinforced concrete.

In the past, lime based cement binders, such as lime putty, were often used but sometimes with other hydraulic cements, (water resistant) such as a calcium aluminate cement or with Portland cement to form Portland cement concrete (named for its visual resemblance to Portland stone). Many other non-cementitious types of concrete exist with other methods of binding aggregate together, including asphalt concrete with a bitumen binder, which is frequently used for road surfaces, and polymer concretes that use polymers as a binder. Concrete is distinct from mortar. Whereas concrete is itself a building material, mortar is a bonding agent that typically holds bricks, tiles and other masonry units together.

Etymology

The word concrete comes from the Latin word "''concretus''" (meaning compact or condensed), the perfect passive participle of "''concrescere''", from "''con''-" (together) and "''crescere''" (to grow).

History

Ancient times

Mayan concrete at the ruins of Uxmal (850-925 A.D.) is referenced in ''Incidents of Travel in the Yucatán'' by John L. Stephens. "The roof is flat and had been covered with cement". "The floors were cement, in some places hard, but, by long exposure, broken, and now crumbling under the feet." "But throughout the wall was solid, and consisting of large stones imbedded in mortar, almost as hard as rock."

Small-scale production of concrete-like materials was pioneered by the Nabatean traders who occupied and controlled a series of oases and developed a small empire in the regions of southern Syria and northern Jordan from the 4th century BC. They discovered the advantages of hydraulic lime, with some self-cementing properties, by 700 BC. They built kilns to supply mortar for the construction of rubble masonry houses, concrete floors, and underground waterproof cisterns. They kept the cisterns secret as these enabled the Nabataeans to thrive in the desert. Some of these structures survive to this day.

Classical era

In the Ancient Egyptian and later Roman eras, builders discovered that adding volcanic ash to the mix allowed it to set underwater.

Concrete floors were found in the royal palace of Tiryns, Greece, which dates roughly to 1400–1200 BC. Lime mortars were used in Greece, Crete, and Cyprus in 800 BC. The Assyrian Jerwan Aqueduct (688 BC) made use of waterproof concrete. Concrete was used for construction in many ancient structures.

The Romans used concrete extensively from 300 BC to 476 AD. During the Roman Empire, Roman concrete (or '' opus caementicium'') was made from quicklime, pozzolana and an aggregate of pumice. Its widespread use in many Roman structures, a key event in the history of architecture termed the Roman architectural revolution, freed Roman construction from the restrictions of stone and brick materials. It enabled revolutionary new designs in terms of both structural complexity and dimension. The Colosseum in Rome was built largely of concrete, and the Pantheon has the world's largest unreinforced concrete dome.

Concrete, as the Romans knew it, was a new and revolutionary material. Laid in the shape of arches, vaults and domes, it quickly hardened into a rigid mass, free from many of the internal thrusts and strains that troubled the builders of similar structures in stone or brick.

Modern tests show that ''opus caementicium'' had as much compressive strength as modern Portland-cement concrete (ca. ). However, due to the absence of reinforcement, its tensile strength was far lower than modern reinforced concrete, and its mode of application also differed:

Modern structural concrete differs from Roman concrete in two important details. First, its mix consistency is fluid and homogeneous, allowing it to be poured into forms rather than requiring hand-layering together with the placement of aggregate, which, in Roman practice, often consisted of rubble. Second, integral reinforcing steel gives modern concrete assemblies great strength in tension, whereas Roman concrete could depend only upon the strength of the concrete bonding to resist tension.

The long-term durability of Roman concrete structures has been found to be due to its use of pyroclastic (volcanic) rock and ash, whereby the crystallization of strätlingite (a specific and complex calcium aluminosilicate hydrate) and the coalescence of this and similar calcium–aluminum-silicate–hydrate cementing binders helped give the concrete a greater degree of fracture resistance even in seismically active environments. Roman concrete is significantly more resistant to erosion by seawater than modern concrete; it used pyroclastic materials which react with seawater to form Al- tobermorite crystals over time.

The widespread use of concrete in many Roman structures ensured that many survive to the present day. The Baths of Caracalla in Rome are just one example. Many Roman aqueducts and bridges, such as the magnificent Pont du Gard in southern France, have masonry cladding on a concrete core, as does the dome of the Pantheon.

After the Roman Empire collapsed, use of concrete became rare until the technology was redeveloped in the mid-18th century. Worldwide, concrete has overtaken steel in tonnage of material used.

Middle Ages

After the Roman Empire, the use of burned lime and pozzolana was greatly reduced. Low kiln temperatures in the burning of lime, lack of pozzolana, and poor mixing all contributed to a decline in the quality of concrete and mortar. From the 11th century, the increased use of stone in church and castle construction led to an increased demand for mortar. Quality began to improve in the 12th century through better grinding and sieving. Medieval lime mortars and concretes were non-hydraulic and were used for binding masonry, "hearting" (binding rubble masonry cores) and foundations. Bartholomaeus Anglicus in his ''De proprietatibus rerum'' (1240) describes the making of mortar. In an English translation from 1397, it reads "lyme ... is a stone brent; by medlynge thereof with sonde and water sement is made". From the 14th century, the quality of mortar was again excellent, but only from the 17th century was pozzolana commonly added.

The '' Canal du Midi'' was built using concrete in 1670.

Industrial era

Perhaps the greatest step forward in the modern use of concrete was Smeaton's Tower, built by British engineer John Smeaton in Devon, England, between 1756 and 1759. This third Eddystone Lighthouse pioneered the use of hydraulic lime in concrete, using pebbles and powdered brick as aggregate.

A method for producing Portland cement was developed in England and patented by Joseph Aspdin in 1824. Aspdin chose the name for its similarity to Portland stone, which was quarried on the Isle of Portland in Dorset, England. His son William continued developments into the 1840s, earning him recognition for the development of "modern" Portland cement.

Reinforced concrete was invented in 1849 by Joseph Monier. and the first reinforced concrete house was built by François Coignet in 1853.
The first concrete reinforced bridge was designed and built by Joseph Monier in 1875.

Composition

Concrete is an artificial composite material, comprising a matrix of cementitious binder (typically Portland cement paste or asphalt) and a dispersed phase or "filler" of aggregate (typically a rocky material, loose stones, and sand). The binder "glues" the filler together to form a synthetic conglomerate. Many types of concrete are available, determined by the formulations of binders and the types of aggregate used to suit the application of the engineered material. These variables determine strength and density, as well as chemical and thermal resistance of the finished product.

Aggregates consist of large chunks of material in a concrete mix, generally a coarse gravel or crushed rocks such as limestone, or granite, along with finer materials such as sand.

Cement paste, most commonly made of Portland cement, is the most prevalent kind of concrete binder. For cementitious binders, water is mixed with the dry cement powder and aggregate, which produces a semi-liquid slurry (paste) that can be shaped, typically by pouring it into a form. The concrete solidifies and hardens through a chemical process called hydration. The water reacts with the cement, which bonds the other components together, creating a robust, stone-like material. Other cementitious materials, such as fly ash and slag cement, are sometimes added—either pre-blended with the cement or directly as a concrete component—and become a part of the binder for the aggregate. Fly ash and slag can enhance some properties of concrete such as fresh properties and durability. Alternatively, other materials can also be used as a concrete binder: the most prevalent substitute is asphalt, which is used as the binder in asphalt concrete.

Admixtures are added to modify the cure rate or properties of the material. Mineral admixtures use recycled materials as concrete ingredients. Conspicuous materials include fly ash, a by-product of coal-fired power plants; ground granulated blast furnace slag, a by-product of steelmaking; and silica fume, a by-product of industrial electric arc furnaces.

Structures employing Portland cement concrete usually include steel reinforcement because this type of concrete can be formulated with high compressive strength, but always has lower tensile strength. Therefore, it is usually reinforced with materials that are strong in tension, typically steel rebar.

The '' mix design'' depends on the type of structure being built, how the concrete is mixed and delivered, and how it is placed to form the structure.

Cement

Portland cement is the most common type of cement in general usage. It is a basic ingredient of concrete, mortar, and many plasters. British masonry worker Joseph Aspdin patented Portland cement in 1824. It was named because of the similarity of its color to Portland limestone, quarried from the English Isle of Portland and used extensively in London architecture. It consists of a mixture of calcium silicates ( alite, belite), aluminates and ferrites—compounds which combine calcium, silicon, aluminum and iron in forms which will react with water. Portland cement and similar materials are made by heating limestone (a source of calcium) with clay or shale (a source of silicon, aluminum and iron) and grinding this product (called ''clinker'') with a source of sulfate (most commonly gypsum).

In modern cement kilns, many advanced features are used to lower the fuel consumption per ton of clinker produced. Cement kilns are extremely large, complex, and inherently dusty industrial installations, and have emissions which must be controlled. Of the various ingredients used to produce a given quantity of concrete, the cement is the most energetically expensive. Even complex and efficient kilns require 3.3 to 3.6 gigajoules of energy to produce a ton of clinker and then grind it into cement. Many kilns can be fueled with difficult-to-dispose-of wastes, the most common being used tires. The extremely high temperatures and long periods of time at those temperatures allows cement kilns to efficiently and completely burn even difficult-to-use fuels.

Water

Combining water with a cementitious material forms a cement paste by the process of hydration. The cement paste glues the aggregate together, fills voids within it, and makes it flow more freely.

As stated by Abrams' law, a lower water-to-cement ratio yields a stronger, more durable concrete, whereas more water gives a freer-flowing concrete with a higher slump. Impure water used to make concrete can cause problems when setting or in causing premature failure of the structure.

Portland cement consists of five major compounds of calcium silicates and alumninates ranging from 5 to 50% in weight, which all undergo hydration to contribute to final material's strength. Thus, the hydration of cement involves many reactions, often occurring at the same time. As the reactions proceed, the products of the cement hydration process gradually bond together the individual sand and gravel particles and other components of the concrete to form a solid mass.

Hydration of tricalcium silicate

: Cement chemist notation: C₃S + H → C-S-H + CH + heat
:Standard notation: Ca₃SiO₅ + H₂O → (CaO)·(SiO₂)·(H₂O)(gel) + Ca(OH)₂
:Balanced: 2Ca₃SiO₅ + 7H₂O → 3(CaO)·2(SiO₂)·4(H₂O)(gel) + 3Ca(OH)₂ (approximately; the exact ratios of the CaO, SiO₂ and H₂O in C-S-H can vary)

Due to the nature of the chemical bonds created in these reactions and the final characteristics of the particles formed, the process of cement hydration is considered irreversible, which makes methods of cement recycling prohibitive.

Aggregates

Fine and coarse aggregates make up the bulk of a concrete mixture. Sand, natural gravel, and crushed stone are used mainly for this purpose. Recycled aggregates (from construction, demolition, and excavation waste) are increasingly used as partial replacements for natural aggregates, while a number of manufactured aggregates, including air-cooled blast furnace slag and bottom ash are also permitted.

The size distribution of the aggregate determines how much binder is required. Aggregate with a very even size distribution has the biggest gaps whereas adding aggregate with smaller particles tends to fill these gaps. The binder must fill the gaps between the aggregate as well as paste the surfaces of the aggregate together, and is typically the most expensive component. Thus, variation in sizes of the aggregate reduces the cost of concrete. The aggregate is nearly always stronger than the binder, so its use does not negatively affect the strength of the concrete.

Redistribution of aggregates after compaction often creates non-homogeneity due to the influence of vibration. This can lead to strength gradients.

Decorative stones such as quartzite, small river stones or crushed glass are sometimes added to the surface of concrete for a decorative "exposed aggregate" finish, popular among landscape designers.

Admixtures

Admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. Admixtures are defined as additions "made as the concrete mix is being prepared". The most common admixtures are retarders and accelerators. In normal use, admixture dosages are less than 5% by mass of cement and are added to the concrete at the time of batching/mixing. (See below.) The common types of admixtures are as follows:
* Accelerators speed up the hydration (hardening) of the concrete. Typical materials used are calcium chloride, calcium nitrate and sodium nitrate. However, use of chlorides may cause corrosion in steel reinforcing and is prohibited in some countries, so that nitrates may be favored, even though they are less effective than the chloride salt. Accelerating admixtures are especially useful for modifying the properties of concrete in cold weather.
* Air entraining agents add and entrain tiny air bubbles in the concrete, which reduces damage during freeze-thaw cycles, increasing durability. However, entrained air entails a tradeoff with strength, as each 1% of air may decrease compressive strength by 5%. If too much air becomes trapped in the concrete as a result of the mixing process, defoamers can be used to encourage the air bubble to agglomerate, rise to the surface of the wet concrete and then disperse.
* Bonding agents are used to create a bond between old and new concrete (typically a type of polymer) with wide temperature tolerance and corrosion resistance.
* Corrosion inhibitors are used to minimize the corrosion of steel and steel bars in concrete.
* Crystalline admixtures are typically added during batching of the concrete to lower permeability. The reaction takes place when exposed to water and un-hydrated cement particles to form insoluble needle-shaped crystals, which fill capillary pores and micro-cracks in the concrete to block pathways for water and waterborne contaminates. Concrete with crystalline admixture can expect to self-seal as constant exposure to water will continuously initiate crystallization to ensure permanent waterproof protection.
* Pigments can be used to change the color of concrete, for aesthetics.
* Plasticizers increase the workability of plastic, or "fresh", concrete, allowing it to be placed more easily, with less consolidating effort. A typical plasticizer is lignosulfonate. Plasticizers can be used to reduce the water content of a concrete while maintaining workability and are sometimes called water-reducers due to this use. Such treatment improves its strength and durability characteristics.
* Superplasticizers (also called high-range water-reducers) are a class of plasticizers that have fewer deleterious effects and can be used to increase workability more than is practical with traditional plasticizers. Superplasticizers are used to increase compressive strength. It increases the workability

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