Sodium peroxide is an inorganic compound with the formula Na₂O₂. This yellowish solid is the product of sodium ignited in excess oxygen. It is a strong base. This metal peroxide exists in several hydrates and peroxyhydrates including Na₂O₂·2H₂O₂·4H₂O, Na₂O₂·2H₂O, Na₂O₂·2H₂O₂, and Na₂O₂·8H₂O.Harald Jakob, Stefan Leininger, Thomas Lehmann, Sylvia Jacobi, Sven Gutewort. "Peroxo Compounds, Inorganic". ''Ullmann's Encyclopedia of Industrial Chemistry'', 2007, Wiley-VCH, Weinheim. . The octahydrate, which is simple to prepare, is white, in contrast to the anhydrous material.

Properties

Sodium peroxide crystallizes with hexagonal symmetry. Upon heating, the hexagonal form undergoes a transition into a phase of unknown symmetry at 512 °C. With further heating above the 657 °C boiling point, the compound decomposes to Na₂O, releasing O₂.Lewis, R. J. ''Sax's Dangerous Properties of Industrial Materials, 10th ed.'', John Wiley & Sons, Inc.: 2000. : 2 Na₂O₂ → 2 Na₂O + O₂

Preparation

The octahydrate is produced by treating sodium hydroxide with hydrogen peroxide. Sodium peroxide can be prepared on a large scale by the reaction of metallic sodium with oxygen at 130–200 °C, a process that generates sodium oxide, which in a separate stage absorbs oxygen:Macintyre, J. E., ed. ''Dictionary of Inorganic Compounds,'' Chapman & Hall: 1992.E. Dönges "Lithium and Sodium Peroxides" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 979. : 4 Na + O₂ → 2 Na₂O : 2 Na₂O + O₂ → 2 Na₂O₂ It may also be produced by passing ozone gas over solid sodium iodide inside a

platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Pla ...

palladium Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself na ...

tube. The ozone oxidizes the sodium to form sodium peroxide. The iodine can be sublimed by mild heating. The platinum or palladium catalyzes the reaction and is not attacked by the sodium peroxide.

Uses

Sodium peroxide hydrolyzes to give sodium hydroxide and

hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%� ...

according to the reaction : Na₂O₂ + 2 H₂O → 2 NaOH + H₂O₂ Sodium peroxide was used to bleach wood pulp for the production of paper and textiles. Presently it is mainly used for specialized laboratory operations, e.g., the extraction of minerals from various ores. Sodium peroxide may go by the commercial names of ''Solozone'' and ''Flocool''.Lewis, R. J. ''Sax's Dangerous Properties of Industrial Materials, 10th ed.'', John Wiley & Sons, Inc.: 2000. In chemistry preparations, sodium peroxide is used as an oxidizing agent. It is also used as an oxygen source by reacting it with carbon dioxide to produce oxygen and sodium carbonate: : 2 Na₂O₂ + 2 CO₂ → 2 Na₂CO₃ + O₂ It is thus particularly useful in scuba gear, submarines, etc.

Lithium peroxide Lithium peroxide is the inorganic compound with the formula Li2 O2. It is a white, nonhygroscopic solid. Because of its high oxygen:mass and oxygen:volume ratios, the solid has been used to remove CO2 from the atmosphere in spacecraft. Preparat ...

and potassium superoxide have similar uses.

References

External links

International Chemical Safety Card 1606
{{oxygen compounds Peroxides Sodium compounds Oxidizing agents