Silver acetylide is an inorganic

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

with the formula Ag₂C₂, a

metal acetylide In organometallic chemistry, acetylide refers to chemical compounds with the chemical formulas and , where M is a metal. The term is used loosely and can refer to substituted acetylides having the general structure (where R is an organic side ch ...

. The compound can be regarded as a

salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quant ...

of the weak

acid In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a se ...

acetylene Acetylene ( systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure ...

. The salt's

anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

consists of two

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...

atoms linked by a

triple bond A triple bond in chemistry is a chemical bond between two atoms involving six bonding electrons instead of the usual two in a covalent single bond. Triple bonds are stronger than the equivalent single bonds or double bonds, with a bond order o ...

. The alternate name "silver carbide" is rarely used, although the analogous calcium compound CaC₂ is called

calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of Ca C2. Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of te ...

. Silver acetylide is a high

explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...

Synthesis

Silver acetylide can be produced by passing

gas through a solution of silver nitrate: :2 (aq) + (g) → (s) + 2 (aq) The reaction product is a greyish to white precipitate. This is the same synthesis from Berthelot in which he first found silver acetylide in 1866. The double salt is formed in acidic or neutral silver nitrate solutions. Performing the synthesis in basic ammonia solution does not allow the double salt to form, producing pure silver acetylide. To properly form the double salt, acetylene gas is passed through dilute silver nitrate and nitric acid solution. Instead of the conventional synthesis of passing acetylene gas through silver nitrate solution, a purer and whiter precipitate can be formed by passing acetylene gas through acetone and adding the acetylene solution drop-wise to a dilute silver nitrate and nitric acid solution. The reaction was performed at ambient room temperature. Silver acetylide can be formed on the surface of silver or high-silver alloys, e.g. in pipes used for transport of acetylene, if silver brazing was used in their joints.

Explosive character

Pure silver acetylide is a heat- and shock-sensitive high explosive. Silver acetylide decompose through the reaction: : (s) → 2 Ag (s) + 2 C (s) The

detonation velocity Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonated explosive. Explosive velocities are always faster than the local speed of sound in t ...

of the silver acetylide-silver nitrate double salt is 1980 m/s, while that of pure silver acetylide is 1200 m/s.

Solubility

Silver acetylide is not soluble in water and is not appreciably soluble in any other solvent.

References

{{Carbides Organosilver compounds Acetylides Explosive chemicals