Sample Analysis at Mars
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Sample Analysis at Mars (SAM) is a suite of instruments on the
Mars Science Laboratory Mars Science Laboratory (MSL) is a robotic space probe mission to Mars launched by NASA on November 26, 2011, which successfully landed ''Curiosity'', a Mars rover, in Gale Crater on August 6, 2012. The overall objectives include investigati ...
''Curiosity'' rover. The SAM instrument suite will analyze organics and gases from both atmospheric and solid samples. It was developed by the NASA
Goddard Space Flight Center The Goddard Space Flight Center (GSFC) is a major NASA space research laboratory located approximately northeast of Washington, D.C. in Greenbelt, Maryland, United States. Established on May 1, 1959 as NASA's first space flight center, GSFC empl ...
, the Laboratoire des Atmosphères Milieux Observations Spatiales (LATMOS) associated to the Laboratoire Inter-Universitaire des Systèmes Atmosphériques (LISA) (jointly operated by France's
Centre national de la recherche scientifique The French National Centre for Scientific Research (french: link=no, Centre national de la recherche scientifique, CNRS) is the French state research organisation and is the largest fundamental science agency in Europe. In 2016, it employed 31,63 ...
and
Paris Paris () is the capital and most populous city of France, with an estimated population of 2,165,423 residents in 2019 in an area of more than 105 km² (41 sq mi), making it the 30th most densely populated city in the world in 2020. Si ...
ian universities), and
Honeybee Robotics Honeybee Robotics Spacecraft Mechanisms Corporation is a small spacecraft technology and robotics company Erik Baard,Alligators Below City? Try Robo-Inchworms ''The New York Times'' BUSINESS: DIARY; November 10, 2002 headquartered in Brooklyn, ...
, along with many additional external partners.


Instruments

The SAM suite consists of three instruments: #The
quadrupole mass spectrometer The quadrupole mass analyzer, originally conceived by Nobel Laureate Wolfgang Paul and his student Helmut Steinwedel, also known as quadrupole mass filter, is one type of mass analyzer used in mass spectrometry. As the name implies, it consists o ...
(QMS) detects gases sampled from the atmosphere or those released from solid samples by heating. #The
gas chromatograph Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substan ...
(GC) is used to separate out individual gases from a complex mixture into molecular components. The resulting gas flow is analyzed in the mass spectrometer with a mass range of 2–535 Daltons. #The tunable laser spectrometer (TLS) performs precision measurements of
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
and
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
ratios in
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
(CO2) and
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
(CH4) in the
atmosphere of Mars The atmosphere of Mars is the layer of gases surrounding Mars. It is primarily composed of carbon dioxide (95%), molecular nitrogen (2.8%), and argon (2%). It also contains trace levels of water vapor, oxygen, carbon monoxide, hydrogen, and no ...
in order to distinguish between their
geochemical Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
or
biological Biology is the scientific study of life. It is a natural science with a broad scope but has several unifying themes that tie it together as a single, coherent field. For instance, all organisms are made up of cells that process hereditary in ...
origin.


Subsystems

The SAM also has three subsystems: the 'chemical separation and processing laboratory', for enrichment and
derivatization Derivatization is a technique used in chemistry which converts a chemical compound into a product (the reaction's derivate) of similar chemical structure, called a derivative. Generally, a specific functional group of the compound participat ...
of the
organic molecules In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The s ...
of the sample; the sample manipulation system (SMS) for transporting powder delivered from the MSL drill to a SAM inlet and into one of 74 sample cups. The SMS then moves the sample to the SAM oven to release gases by heating to up to 1000 °C; and the pump subsystem to purge the separators and analysers. Th
Space Physics Research Laboratory
at the
University of Michigan , mottoeng = "Arts, Knowledge, Truth" , former_names = Catholepistemiad, or University of Michigania (1817–1821) , budget = $10.3 billion (2021) , endowment = $17 billion (2021)As o ...
built the main power supply, command and data handling unit, valve and heater controller, filament/bias controller, and high voltage module. The uncooled infrared detectors were developed and provided by the Polish company VIGO System.


Timeline

* 9 November 2012: A pinch of fine sand and dust became the first solid
Martian Mars, the fourth planet from the Sun, has appeared as a setting in works of fiction since at least the mid-1600s. It became the most popular celestial object in fiction in the late 1800s as the Moon was evidently lifeless. At the time, the pr ...
sample deposited into the SAM. The sample came from the patch of windblown material called Rocknest, which had provided a sample previously for mineralogical analysis by
CheMin Chemin or Le Chemin may refer to: Arts and media * ''Le chemin'' (Emmanuel Moire album), 2013 album by French singer Emmanuel Moire * ''Le chemin'' (Kyo album), 2003 album by French band Kyo ** "Le Chemin" (song), title song from same-titled Kyo ...
instrument. *3 December 2012: NASA reported SAM had detected
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
molecules,
chlorine Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine i ...
and
sulphur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
. Hints of organic compounds couldn't be ruled out as contamination from ''Curiosity'' itself, however. * 16 December 2014: NASA reported the ''Curiosity'' rover detected a "tenfold spike", likely localized, in the amount of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
in the Martian atmosphere. Sample measurements taken "a dozen times over 20 months" showed increases in late 2013 and early 2014, averaging "7 parts of methane per billion in the atmosphere." Before and after that, readings averaged around one-tenth that level. In addition, high levels of
organic chemicals In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The s ...
, particularly
chlorobenzene Chlorobenzene is an aromatic organic compound with the chemical formula C6H5Cl. This colorless, flammable liquid is a common solvent and a widely used intermediate in the manufacture of other chemicals. Uses Historical The major use of chlorob ...
, were detected in powder drilled from one of the rocks, named "
Cumberland Cumberland ( ) is a historic counties of England, historic county in the far North West England. It covers part of the Lake District as well as the north Pennines and Solway Firth coast. Cumberland had an administrative function from the 12th c ...
", analyzed by the Curiosity rover. * 24 March 2015: NASA reported the first detection of
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
released after heating surface sediments on the planet Mars. The nitrogen in
nitrate Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insolu ...
is in a "fixed" state, meaning that it is in an oxidized form that can be used by
living organisms In biology, an organism () is any living system that functions as an individual entity. All organisms are composed of cells (cell theory). Organisms are classified by taxonomy into groups such as multicellular animals, plants, and fun ...
. The discovery supports the notion that ancient Mars may have been habitable for
life Life is a quality that distinguishes matter that has biological processes, such as signaling and self-sustaining processes, from that which does not, and is defined by the capacity for growth, reaction to stimuli, metabolism, energy ...
. * 4 April 2015: NASA reported studies, based on measurements by the Sample Analysis at Mars (SAM) instrument on the ''Curiosity'' rover, of the Martian atmosphere using
xenon Xenon is a chemical element with the symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
and
argon Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice a ...
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
s. Results provided support for a "vigorous" loss of atmosphere early in the history of Mars and were consistent with an atmospheric signature found in bits of atmosphere captured in some Martian meteorites found on Earth. * 1 November 2021: Astronomers reported detecting, in a "first-of-its-kind" process based on SAM instruments,
organic molecules In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The s ...
, including
benzoic acid Benzoic acid is a white (or colorless) solid organic compound with the formula , whose structure consists of a benzene ring () with a carboxyl () substituent. It is the simplest aromatic carboxylic acid. The name is derived from gum benzoin ...
,
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
and other related unknown compounds, on the planet Mars by the ''Curiosity'' rover.


Gallery


Videos


See also

* Thermal and Evolved Gas Analyzer (Phoenix lander) * Urey instrument


References


External links


Sample Analysis at Mars - NASASAM is loaded into the Rover - NASA
{{Satellite and spacecraft instruments Mars Science Laboratory instruments Space science experiments Articles containing video clips