Roman cement
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Roman cement is a substance developed by James Parker in the 1780s, being patented in 1796. The name is misleading, as it is nothing like any material used by the Romans, but was a "natural
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
" made by burning
septaria A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
– nodules that are found in certain clay deposits, and that contain both clay minerals and calcium carbonate. The burnt nodules were ground to a fine powder. This product, made into a mortar with sand, set in 5–15 minutes. The success of Roman cement led other manufacturers to develop rival products by burning artificial mixtures of clay and
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...
.


History

There has been recent resurgence of interest in natural cements and Roman cements due mainly to the need for repair of façades done in this material in the 19th century. The major confusion involved for many people in this subject is the terminology used. Roman cement was originally the name given, by Parker, to the cement he patented which is a natural cement (i.e. it is a marl, or limestone containing integral
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
, dug out of the ground, burnt and ground to a fine powder). In 1791, Parker was granted a
patent A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an enabling disclosure of the invention."A ...
"Method of Burning bricks, Tiles, Chalk". His second patent in 1796 "A certain Cement or Terras to be used in Aquatic and other Buildings and Stucco Work", covers Roman cement, the term he used in a 1798 pamphlet advertising his cement. He set up his manufacturing plant on Northfleetcreek,
Kent Kent is a county in South East England and one of the home counties. It borders Greater London to the north-west, Surrey to the west and East Sussex to the south-west, and Essex to the north across the estuary of the River Thames; it faces ...
. It was notably patented late on but James Parker is still the subject of all the credit. Later, in the 1800s various sources of the correct type of marl, known also as cement stone, were discovered across Europe and so there were a range of natural cements (with varying properties) in use across Europe. An Austrian standard from 1880, providing a contemporary definition of Roman cements, reads: "Roman cements are products obtained from argillaceous marlstones by burning below the sintering temperature. They do not slake in contact with water and must therefore be ground to a floury fineness."modified in 1890: "Roman cements are products obtained from argillaceous marlstones by burning below the sintering temperature. They do not slake in contact with water and must therefore be ground to a floury fineness." It specifies the range of setting times which facilitated the choice of a suitable material for a given decorative task: "Roman cements bind fast, medium and slow. By fast binding cements one should understand those which with no addition of sand start to harden within 7 minutes from the moment water is added. Roman cement is considered a slow binding variety if hardening starts later than after 15 minutes." From around 1807 a number of people looked to make artificial versions of this cement (or more strictly hydraulic lime as it was not burnt at fusion temperatures). Amongst these were
James Frost James Martin Frost (born 22 August 1986) is the guitarist, keyboardist and backing vocalist of Welsh band The Automatic, and guitarist and backing vocalist for Cardiff-based band Effort. As well as his musical duties for The Automatic, Frost ha ...
who had about twenty patents from 1811 to 1822 including one for "British Cement" and in 1824 Joseph Aspdin, a British bricklayer from Leeds, with his now famous patent for a method of making a cement he called "Portland cement". This was done by adding various materials together to make an artificial version of natural cement. The name "Portland cement" is also recorded in a directory published in 1823 being associated with William Lockwood, Dave Stewart, and possibly others. There then followed a number of independently discovered or copied versions of this "Portland cement" (also referred to as proto-Portland cement). Proto-Portland cement had a different chemical makeup from other natural cements being produced at the same time: It was burnt at a higher temperature than other Natural cements and thus crosses the barrier between traditional vertical kiln fired natural cement and the later horizontal kiln fired artificial cements. This cement is not, however, the same as the modern ordinary
Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th ...
, which can be defined as artificial cement. James Frost is reported to have erected a manufactory for making of an artificial cement in 1826. In 1843, Aspdin's son
William William is a male given name of Germanic origin.Hanks, Hardcastle and Hodges, ''Oxford Dictionary of First Names'', Oxford University Press, 2nd edition, , p. 276. It became very popular in the English language after the Norman conquest of Engl ...
improved their cement, which was initially called "Patent Portland cement," although he had no patent. In 1848, William Aspdin further improved his cement and in 1853, he moved to Germany where he was involved in cement making. William Aspdin made what could be called meso-Portland cement (a mix of Portland cement and hydraulic lime). Development in the 1860s of rotating horizontal kiln technology brought dramatic changes in properties, arguably resulting in modern cement. Certainly it is difficult to define whether an old render was a natural cement (single source marl) or an artificial one, but there is no doubt as whether the cement was fired in a vertical or horizontal kiln. The names natural cement or Roman cement then defines a cement coming from a single source rock. Early or proto-Portland cement could be used for early cement that comes from a number of sourced and mixed materials. There is no widely used terminology for these 19th-century cements. There had been, in order to rediscover this technology, two projects carried out by the European Union ROCEM and subsequently ROCARE (an ongoing project). Both these only deal with natural cement - referred to as Roman cement without reference to the early artificial cements.


References

;Notes ;Bibliography *Thurston A P, ''Parker's "Roman" Cement'', Transactions of the Newcomen Society 1939 P193-206
Newcomen Society
*Major A J Francis, ''The Cement Industry 1796-1914 A History'', 1977, Davis & Charles (Publishers) Ltd, Devon UK, North Pomfret Vermont US, North Vancouver Canada *Weber J, Mayr N, Bayer K, Hughes D, Kozłowski R, Stillhammerova M, Ullrich D, Vyskocilova R (2007) Roman cement mortars in Europe’s architectural heritage of the 19th century. Journal of the American Society for Testing Materials International, Vol, 4 No 8 ;Footnotes {{Reflist, group=footnote


External links


Parker's Roman Cement 1796
Building materials Cement