Richard Willstätter
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Richard Martin Willstätter FRS(For) H FRSE (, 13 August 1872 – 3 August 1942) was a German
organic chemist Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J. ...
whose study of the structure of plant pigments, chlorophyll included, won him the 1915
Nobel Prize for Chemistry ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "M ...
. Willstätter invented
paper chromatography Paper chromatography is an analytical method used to separate coloured chemicals or substances. It is now primarily used as a teaching tool, having been replaced in the laboratory by other chromatography methods such as thin-layer chromatography ...
independently of
Mikhail Tsvet Mikhail Semyonovich Tsvet (Михаил Семёнович Цвет, also spelled Tsvett, Tswett, Tswet, Zwet, and Cvet; 14 May 1872 – 26 June 1919) was a Russian-Italian botanist who invented chromatography. His last name is Russian for "colo ...
.


Life

Willstätter was born into a Jewish family in
Karlsruhe Karlsruhe ( , , ; South Franconian: ''Kallsruh'') is the third-largest city of the German state (''Land'') of Baden-Württemberg after its capital of Stuttgart and Mannheim, and the 22nd-largest city in the nation, with 308,436 inhabitants. ...
. He was the son of Maxwell (Max) Willstätter, a textile merchant, and his wife, Sophie Ulmann. He went to school at the Karlsruhe Gymnasium and, when his family moved to
Nuremberg Nuremberg ( ; german: link=no, Nürnberg ; in the local East Franconian dialect: ''Nämberch'' ) is the second-largest city of the German state of Bavaria after its capital Munich, and its 518,370 (2019) inhabitants make it the 14th-largest ...
, he attended the Technical School there. At age 18 he entered the
University of Munich The Ludwig Maximilian University of Munich (simply University of Munich or LMU; german: Ludwig-Maximilians-Universität München) is a public research university in Munich, Germany. It is Germany's sixth-oldest university in continuous operatio ...
to study science and stayed for the next fifteen years. He was in the Department of Chemistry, first as a student of Alfred Einhorn—he received his doctorate in 1894 – then as a faculty member. His doctoral thesis was on the structure of
cocaine Cocaine (from , from , ultimately from Quechua: ''kúka'') is a central nervous system (CNS) stimulant mainly used recreationally for its euphoric effects. It is primarily obtained from the leaves of two Coca species native to South Ameri ...
. Willstätter continued his research into other
alkaloid Alkaloids are a class of basic, naturally occurring organic compounds that contain at least one nitrogen atom. This group also includes some related compounds with neutral and even weakly acidic properties. Some synthetic compounds of similar ...
s and synthesized several of them. In 1896 he was named Lecturer and in 1902 ''Professor extraordinarius'' (professor without a chair). In 1905 he left Munich to become professor at the
ETH Zürich (colloquially) , former_name = eidgenössische polytechnische Schule , image = ETHZ.JPG , image_size = , established = , type = Public , budget = CHF 1.896 billion (2021) , rector = Günther Dissertori , president = Joël Mesot , a ...
and there he worked on the plant pigment chlorophyll. He first determined its empirical formula. In 1912 he became professor of chemistry at the
University of Berlin Humboldt-Universität zu Berlin (german: Humboldt-Universität zu Berlin, abbreviated HU Berlin) is a German public research university in the central borough of Mitte in Berlin. It was established by Frederick William III on the initiative ...
and director of the Kaiser Wilhelm Institute for Chemistry, studying the structure of pigments of flowers and fruits. It was here that Willstätter showed that chlorophyll was a mixture of two compounds, chlorophyll a and
chlorophyll b } Chlorophyll ''b'' is a form of chlorophyll. Chlorophyll ''b'' helps in photosynthesis by absorbing light energy. It is more soluble than chlorophyll ''a'' in polar solvents because of its carbonyl group. Its color is green, and it primarily a ...
. He lived in the Dahlem neighborhood near other scientists. In 1915 his friend
Fritz Haber Fritz Haber (; 9 December 186829 January 1934) was a German chemist who received the Nobel Prize in Chemistry in 1918 for his invention of the Haber–Bosch process, a method used in industry to synthesize ammonia from nitrogen gas and hydroge ...
asked him to join in the development of poison gases. Willstätter would not work on poisons but agreed to work on protection. He and his coworkers developed a three layer filter that absorbed all of the enemy's gases. Thirty million were manufactured by 1917 and Willstätter was awarded the Iron Cross Second Class. In 1916 he returned to Munich as the successor to his mentor Baeyer. During the 1920s Willstätter investigated the mechanisms of enzyme reactions and did much to establish that
enzyme Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products ...
s are chemical substances, not biological organisms. However, to the end of his life he refused to accept that enzymes were proteins. In 1924 Willstätter's career came to "a tragic end when, as a gesture against increasing antisemitism, he announced his retirement." According to his Nobel biography: "Expressions of confidence by the Faculty, by his students and by the Minister failed to shake the fifty-three year old scientist in his decision to resign. He lived on in retirement in Munich....Dazzling offers both at home and abroad were alike rejected by him." His only research was with assistants who telephoned their results. Despite pleas for him to move to Jerusalem or to Switzerland earlier in the 1930s, Willstätter did not flee from Germany until 1939. In 1933, the ''Centralverein'' (Central Union of German Citizens of the Jewish Faith) created a publication project entitled ''Juden im deutschen Kulturbereich: ein Sammelwerk'' or 'Jews in the Realm of German Culture' --pathetic only in retrospect-- of Jewish 'achievements' and Jewish 'achievers,' which included Jewish luminaries in literature and the arts, in Jewish as well as Christian theology, in politics, warfare, industry, and the natural sciences. "It was a vast, meticulously detailed encyclopedia of Jewish contributions to German life and culture during the past two centuries." The oversized book ran to 1,060 pages and comprised thousands of entries and names. Willstätter wrote the introduction. However, not surprisingly, in December 1934 the (Nazi) Berlin State Police confiscated all the copies that had already been printed. In 1939 Willstätter emigrated to Switzerland. He spent the last three years of his life there in
Muralto Muralto is a municipality in the district of Locarno, in the canton of Ticino in Switzerland. Geography Muralto has an area, , of . Of this area, or 71.7% is used for agricultural purposes, while or 3.3% is forested. Of the rest of the lan ...
near
Locarno , neighboring_municipalities= Ascona, Avegno, Cadenazzo, Cugnasco, Gerra (Verzasca), Gambarogno, Gordola, Lavertezzo, Losone, Minusio, Muralto, Orselina, Tegna, Tenero-Contra , twintowns =* Gagra, Georgia * Karlovy Vary, Czech Republic ...
writing his autobiography. He died of a heart attack in 1942. Willstätter's autobiography, ''Aus meinem Leben'', was not published in German until 1949. It was translated into English as ''From My Life'' in 1965.Richard Willstätter: ''Aus meinem Leben'', edited by A. Stoll, Verlag Chemie, Weinheim, 1949; English edition: ''From My Life'', Benjamin, New York, 1965.


Family

In 1903, he married Sophie Leser, who died in 1908. They had two children.


Honours

In 1965, the school in Nuremberg he had attended named itself ''Willstätter-Gymnasium'', in his honour.School Homepage ''The Meaning of our School's Name – Richard Willstätter and his Legacy'', accessed 3 May 2020
/ref>


See also

* List of Jewish Nobel laureates


References


External links

* including the Nobel Lecture, 3 June 1920 ''On Plant Pigments''
Mahnmale, Gedenkstätten, Erinnerungsorte für die Opfer des Nationalsozialismus in München 1933–1945
pages 158–166 * {{DEFAULTSORT:Willstatter, Richard 1872 births 1942 deaths Nobel laureates in Chemistry German Nobel laureates Jewish Nobel laureates People from the Grand Duchy of Baden Scientists from Karlsruhe Organic chemists ETH Zurich faculty German physical chemists Jewish chemists Ludwig Maximilian University of Munich alumni Ludwig Maximilian University of Munich faculty Humboldt University of Berlin faculty Jewish emigrants from Nazi Germany to Switzerland German emigrants to Switzerland Faraday Lecturers Foreign Members of the Royal Society Foreign associates of the National Academy of Sciences Recipients of the Pour le Mérite (civil class)