Refined coal
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Refined coal is the product of the coal-upgrading technology that removes moisture and certain pollutants from lower-rank coals such as
sub-bituminous Sub-bituminous coal is a lower grade of coal that contains 35–45% carbon. The properties of this type are between those of lignite, the lowest grade of coal, and those of bituminous coal, the second-highest grade of coal. Sub-bituminous coal i ...
and lignite (brown) coals, raising their calorific values.http://www.nextgenenergy.org/Portals/Nextgen/docs/TechPapers/NextGen_EEE_Clean_new.pdf NextGen Energy Council Breakthrough Paper Coal refining or upgrading technologies are typically pre-combustion treatments and processes that alter the characteristics of coal before it is burned. Pre-combustion coal-upgrading technologies aim to increase efficiency and reduce emissions when coal is burned. Depending on the situation, pre-combustion technology can be used in place of or as a supplement to post-combustion technologies to control emissions from coal-fueled boilers.http://www.fmifuel.com/pcia/index.html Pre Combustion Innovations Alliance A primary benefit of refined coal is the capacity to reduce the net volume of carbon emissions that is currently emitted from power generators and would reduce the number of emissions that is proposed to be managed via emerging
carbon sequestration Carbon sequestration is the process of storing carbon in a carbon pool. Carbon dioxide () is naturally captured from the atmosphere through biological, chemical, and physical processes. These changes can be accelerated through changes in lan ...
methodologies. Refined coal technologies have primarily been developed in the United States. Several similar technologies have been researched, developed, and tested in
Victoria Victoria most commonly refers to: * Victoria (Australia), a state of the Commonwealth of Australia * Victoria, British Columbia, provincial capital of British Columbia, Canada * Victoria (mythology), Roman goddess of Victory * Victoria, Seychelle ...
, Australia, including the Densified coal technology (
Coldry Process Densified coal is the product of the Coldry Process coal upgrading technology that removes moisture from low-rank coals such as sub-bituminous and lignite/brown coal. The densification process raises the calorific value of low-rank coal to equal ...
) developed to alter the chemical bonds of brown coal to create a product that is cleaner, stable (not prone to spontaneous combustion), exportable and of sufficiently high calorific value to be a
black coal equivalent Black coal equivalent (BCE) is an export coal product derived from the Coldry Process, a patented coal upgrading technology operated by Environmental Clean Technologies Limited, in Victoria, Australia. The Coldry Process is applied to brown coal ...
.


Coal-upgrading technology

Coal-upgrading technology refers to a class of technologies developed to remove moisture, and certain pollutants from low rank coals such as sub- Bituminous coal and lignite (
brown coal Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
) and raise their calorific values. Companies in Australia, Germany, and the United States are the principal drivers of these technologies' research, development, and commercialization.


Environmental rationale

Around 30 nations collectively operate more than 1,400 brown coal-fired power stations worldwide. Brown coal power stations that cannot economically dewater brown coal are inefficient and cause high levels of carbon emissions. High-emitting power stations, notably the
Hazelwood power station The Hazelwood Power Station is a decommissioned brown coal-fuelled thermal power station located in the Latrobe Valley of Victoria, Australia. Built between 1964 and 1971, the 1,600-megawatt-capacity power station was made up of eight 200MW uni ...
in Australia, attract environmental criticism. Many modern economies, including
Greece Greece,, or , romanized: ', officially the Hellenic Republic, is a country in Southeast Europe. It is situated on the southern tip of the Balkans, and is located at the crossroads of Europe, Asia, and Africa. Greece shares land borders ...
and
Victoria Victoria most commonly refers to: * Victoria (Australia), a state of the Commonwealth of Australia * Victoria, British Columbia, provincial capital of British Columbia, Canada * Victoria (mythology), Roman goddess of Victory * Victoria, Seychelle ...
(Australia), are highly dependent on brown coal for electricity. Improved environmental performance and the need for stable economic environment provide incentives for investment to substantially reduce the negative environmental impact of burning raw ('as mined') brown coal.


Economic rationale

Coal-upgrading technologies remove moisture from 'as mined' brown coal and transform the calorific performance of brown coal to a 'cleaner' burning status relatively equivalent to high calorific value black coal. Some coal-upgrading processes result in a densified coal product that is considered to be a
Black coal equivalent Black coal equivalent (BCE) is an export coal product derived from the Coldry Process, a patented coal upgrading technology operated by Environmental Clean Technologies Limited, in Victoria, Australia. The Coldry Process is applied to brown coal ...
product suitable for burning in black coal boilers. Victorian brown coal, with a characteristic moisture content of 60% by weight, is regarded as the world's 'wettest' brown coal. The high moisture content is the key reason the state's three major power stations are collectively regarded as the dirtiest carbon emitters in the world. Studies undertaken by the
University of Melbourne The University of Melbourne is a public research university located in Melbourne, Australia. Founded in 1853, it is Australia's second oldest university and the oldest in Victoria. Its main campus is located in Parkville, an inner suburb no ...
and
Monash University Monash University () is a public research university based in Melbourne, Victoria, Australia. Named for prominent World War I general Sir John Monash, it was founded in 1958 and is the second oldest university in the state. The university h ...
confirm that when moisture is removed from Victorian brown coal, naturally low levels of ash, sulfur, and other elements rank it as being one of the cleanest coals in the world. When dewatered, upgraded brown coal can compete in the export market at comparable prices to black coal. With significant brown coal mining occurring worldwide and mining levels increasing, the need for coal-upgrading technologies has become more apparent. the technologies will help to address the global environmental concern of rising emissions from the burning of brown coal and provide alternative fuel options to rapidly emerging economies such as Vietnam that face difficulty competing for black coal with China, India, Japan, and other nations.


Technology comparison

Because of inherent high moisture content, all lignites need to be dried prior to combustion. Depending on the technology type drying is achieved either via a discrete operation or part of a process. The comparison chart identifies different technology drying methods that are in development in different countries and provides a qualitative comparison.


History and advantages


United States

The best known producer of refined coal is a company based in Denver, Colorado calle
Evergreen Energy Inc.
The company is publicly traded and is listed on the
NYSE Arca NYSE Arca, previously known as ArcaEx, an abbreviation of Archipelago Exchange, is an exchange on which both stocks and options are traded. It was owned by Intercontinental Exchange. It merged with the New York Stock Exchange in 2006 and now op ...
exchange. According to th
company's website
and its Form 10-K on file with the U.S. Securities and Exchange Commission, it was founded in 1984 to commercialize a coal-upgrading technology first developed in a Stanford University laboratory by Edward Koppelman. Taking the K from Koppelman's name, Evergreen, formerly KFx Inc., branded its refined coal product as "K-Fuel." Much of the coal in the western United States is known as "lower-rank" coal that falls under the categories of "sub-bituminous" and "lignite" coals. These coals have high moisture levels and can be 20 to 30 percent water. This relatively high moisture content compared to "higher rank" coals like bituminous and anthracite coals make lower-rank coals less efficient. The average heat content of sub-bituminous coal consumed in the United States is approximately 8,500 British thermal units (Btu) per pound. The K-Fuel(R) process uses heat and pressure to remove approximately 30 percent of the moisture from raw, low-rank coal and raises its thermal content to approximately 11,000 Btu per pound. In addition to raising the coal's heat value, a significant amount, up to 70 percent, of the elemental mercury in the coal is removed and, because of its higher efficiency, lower chloride and nitrogen oxides emissions are achieved on a per kilowatt hour generated basis.http://evgenergy.com/documents/BHP_Results_ES.shtml Refined Coal Test Burn Results Black Hills Power The advantages of the refined coal process are more efficient transportation and the ability of utilities to switch to a fuel made of 100 percent refined coal or a blend of raw and refined coals in order to achieve lower emissions and greater efficiency.http://evgenergy.com/documents/EEE-PA-Test-Burn-Ex-Summary.pdf Test Burn Results with Pennsylvania Utility A disadvantage is that the industry requires significant subsidies. An examination of government figures show that in 2007, for every
megawatt-hour A kilowatt-hour (unit symbol: kW⋅h or kW h; commonly written as kWh) is a Units of measurement, unit of energy: one kilowatt of power for one hour. In terms of SI derived units with special names, it equals 3.6 Joule, megajoules (MJ). Kil ...
generated, refined coal received $29.81 in federal support,
solar power Solar power is the conversion of energy from sunlight into electricity, either directly using photovoltaics (PV) or indirectly using concentrated solar power. Photovoltaic cells convert light into an electric current using the photovolta ...
received $24.34,
wind power Wind power or wind energy is mostly the use of wind turbines to generate electricity. Wind power is a popular, sustainable, renewable energy source that has a much smaller impact on the environment than burning fossil fuels. Historically ...
received $23.37, and
nuclear power Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced ...
received $1.59.


Australia

The producer of densified coal in Australia is a company based in
Melbourne Melbourne ( ; Boonwurrung/Woiwurrung: ''Narrm'' or ''Naarm'') is the capital and most populous city of the Australian state of Victoria, and the second-most populous city in both Australia and Oceania. Its name generally refers to a met ...
, Victoria called Environmental Clean Technologies Limited (ECT Limited) The company is publicly traded and listed on the
Australian Stock Exchange Australian Securities Exchange Ltd or ASX, is an Australian public company that operates Australia's primary securities exchange, the Australian Securities Exchange (sometimes referred to outside of Australia as, or confused within Australia as ...
(ASX). The company was listed in 2005 with the primary purpose of commercialising the
Coldry Process Densified coal is the product of the Coldry Process coal upgrading technology that removes moisture from low-rank coals such as sub-bituminous and lignite/brown coal. The densification process raises the calorific value of low-rank coal to equal ...
coal-upgrading methodology first developed in the Chemical Laboratory of
Melbourne University The University of Melbourne is a public research university located in Melbourne, Australia. Founded in 1853, it is Australia's second oldest university and the oldest in Victoria. Its main campus is located in Parkville, an inner suburb no ...
by Dr B. A. John in the 1980s. The name of the process derived from the Calleja Group, which acquired the technology in 1994 and developed the technology to pilot demonstration at
Maddingley Mine Maddingley Mine near Bacchus Marsh Railway Station, Victoria, Australia contains a concentration of a particular brown coal ( lignite) formation called Leonardite. A relatively high altitude formation, Maddingley brown coal is distinguished as ...
, Bacchus Marsh, Victoria in 2004 before licensing the technology to ECT Limited for further commercialisation in 2005. The State of Victoria contains approximately 25% of the world's known reserves of brown coal (lignite). This coal is also amongst the world's 'wettest' coal, with a typical moisture content of 60 per cent water by weight. High moisture content makes Victorian brown coal an inefficient fuel source and is the primary reason why the
Hazelwood power station The Hazelwood Power Station is a decommissioned brown coal-fuelled thermal power station located in the Latrobe Valley of Victoria, Australia. Built between 1964 and 1971, the 1,600-megawatt-capacity power station was made up of eight 200MW uni ...
in the Latrobe Valley is regarded as the world's dirtiest coal-fired power station. The Coldry Process uses low-pressure mechanical shear to create a natural exothermic reaction within the coal that then naturally expels 80 per cent of the moisture content. Expelled moisture is then captured and recovered as distilled water. Victorian brown coal transformed by the Coldry Process has a raised thermal content of 5874 kcal/kg, which is comparable to most export-grade Australian black coal. The advantage of the Coldry Process is its ability to allow power generators to switch to a blend of raw as mined brown coal and Coldry pellets to achieve lower emissions in existing inefficient boilers, or achieve substantially less emissions by introducing black coal boilers and using 100 per cent Coldry refined coal pellets as a black coal equivalent. The Coldry Process provides the added advantage of creating new revenue streams for power generators through the production of a product that can be exported to other countries as a replacement for black coal. Unlike other refined coal processes, the Coldry Process is a commercial methodology that does not require subsidy.


Commercial development


United States

Evergreen Energy constructed a full-scale coal refinery near
Gillette, Wyoming Gillette (, '' jih-LET'') is a city in and the county seat of Campbell County, Wyoming, United States. The town was founded in 1891 as a major railway town on the Chicago, Burlington and Quincy Railroad. The population was estimated at 32,030 a ...
that began operation in late 2005. Designed originally to be a commercial plant, the facility encountered design and operational problems. Evergreen idled the facility in March 2008http://www.evgenergy.com/documents/2008-03-20-EEE_Shareholder_Letter.shtml Evergreen Letter to Shareholders March 2008 and instead used the plant as a process development platform with its engineering, construction and procurement contractor Bechtel Power Corporation. Evergreen is now seeking to construct a coal refinery using the improved Bechtel design at locations in the Midwestern United States and in Asia.http://www.evgenergy.com/documents/2008-11-10-EEE_Shareholder_Letter.shtml Evergreen Letter to Shareholders November 2008


Australia

Calleja Group constructed a full-scale 16,000 tonne per annum pilot demonstration plant at JBD Business Park at Maddingley Mine near Bacchus Marsh, Victoria that began operation in early 2004. From 2005 ECT Limited upgraded the facility, added a water recovery process with Victorian Government funding in 2007 and operated the plant as a process development platform with its engineering partner ARUP. In 2009 ECT Limited secured and agreement with Thang Long Investment Company (Tincom) of
Vietnam Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...
to finalise commercial feasibility ahead of construction of a 2 million tonne pa export plant by 2014 and 20 million tonne pa export by 2020. ECT Limited is using the ARUP improved design to secure technology licensing agreements with brown coal suppliers in China,
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
,
Indonesia Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania between the Indian and Pacific oceans. It consists of over 17,000 islands, including Sumatra, Java, Sulawesi, and parts of Borneo and New Guine ...
,
Poland Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populou ...
,
Greece Greece,, or , romanized: ', officially the Hellenic Republic, is a country in Southeast Europe. It is situated on the southern tip of the Balkans, and is located at the crossroads of Europe, Asia, and Africa. Greece shares land borders ...
and
Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-eig ...
.


China

GBCE has built and is now operating the world's first industrial-scale coal-upgrading facility. It has capacity to process 1 MTPA of coal feedstock and is located in Holingol, Inner Mongolia, the largest lignite-producing region in China.http://www.gbce.com/en/projects_yield.php The coal is typically high moisture (35 – 40% TM) and 3200 – 3400 kcal gar. Depending on market requirements, it produces 5000–5500 kcal coal (gar) with greatly reduced moisture content (< 10% gar). The plant uses LCP coal-upgrading technology, which is a pyrolytic process that employs heat and pressure in an oxygen-free environment to continue the coalification process that occurs naturally in the earth. The processed coal by this technology is hydrophobic and transportable, which means it will not reabsorb moisture or break up into powder during transportation.


See also

* Bituminous coal *
Bergius process The Bergius process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of high-volatile bituminous coal at high temperature and pressure. It was first developed by Friedrich Bergius in 1913. In 1931 Bergius ...
*
Coal assay Coal analysis techniques are specific analytical methods designed to measure the particular physical and chemical properties of coals. These methods are used primarily to determine the suitability of coal for coking, power generation or for iron ...
*
Coldry Process Densified coal is the product of the Coldry Process coal upgrading technology that removes moisture from low-rank coals such as sub-bituminous and lignite/brown coal. The densification process raises the calorific value of low-rank coal to equal ...
* Coke fuel * Densified coal *
Energy value of coal The energy value of coal, or fuel content, is the amount of potential energy coal contains that can be converted into heat. This value can be calculated and compared with different grades of coal and other combustible materials, which produce diffe ...
*
Fischer–Tropsch process The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatu ...
*
Karrick process The Karrick process is a low-temperature carbonization (LTC) and pyrolysis process of carbonaceous materials. Although primarily meant for coal carbonization, it also could be used for processing of oil shale, lignite or any carbonaceous materials ...
*
Leonardite Leonardite is a soft waxy, black or brown, shiny, vitreous mineraloid that is easily soluble in alkaline solutions. It is an oxidation product of lignite, associated with near-surface mining. It is a rich source of humic acid (up to 90%) and is us ...
* Lignite *
Maddingley Mine Maddingley Mine near Bacchus Marsh Railway Station, Victoria, Australia contains a concentration of a particular brown coal ( lignite) formation called Leonardite. A relatively high altitude formation, Maddingley brown coal is distinguished as ...
* Orders of magnitude (specific energy density) * List of CO2 emitted per million Joule of energy from various fuels


References

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