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Putty is a material with high plasticity, similar in texture to
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
or
dough Dough is a thick, malleable, sometimes elastic paste made from grains or from leguminous or chestnut crops. Dough is typically made by mixing flour with a small amount of water or other liquid and sometimes includes yeast or other leavenin ...
, typically used in domestic construction and repair as a sealant or filler. Although some types of putty (typically those using linseed oil) slowly polymerise and become stiff, many putties can be reworked indefinitely, in contrast to other types of filler which typically set solid relatively rapidly.


Chemical composition

Putty, or
lime putty Lime mortar or torching is composed of lime and an aggregate such as sand, mixed with water. The ancient Egyptians were the first to use lime mortars, which they used to plaster their temples. In addition, the Egyptians also incorporated various ...
, is made from a mixture of calcium oxide (CaO) and water (H2O) in proportions of 38% and 62% by weight respectively, as result, the solution forms hydrated lime (Ca(OH)2) which takes up about a half of the weight. The other putty mixture may be a calcium carbonate (CaCO3, 750-850 parts) based with a admixtures of CaO (ash calcium, 120-180 parts), white cement (40-60 parts), and talc powders in much lower concentrations (fractions).


Applications


Use in construction

Putty has been used extensively in glazing for fixing and sealing panes of glass into wooden frames (or
sashes Sashes Island is an island in the River Thames in England at Cookham Lock near Cookham, Berkshire. It is now open farmland, but has Roman and Anglo-Saxon connections. The island is located between Hedsor Water and the present navigation cha ...
), although its use is decreasing with the prevalence of PVC and metal window frames which use synthetic sealants such as
silicone A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cookin ...
. Glazing putty is traditionally made by mixing a base of whiting (finely ground
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. C ...
) with linseed oil in various proportions. Historically, white lead was sometimes mixed with the whiting.Paul N. Hasluck, Ed.
The Handyman's Enquire Within
Cassel and Co., 1908; page 439.
There are a number of synthetic alternatives such as
polybutene Polybutene is an organic polymer made from a mixture of 1-butene, 2-butene, and isobutylene. Ethylene steam cracker C4s are also used as supplemental feed for polybutene. It is similar to polyisobutylene (PIB), which is produced from essentially p ...
-based putties, where the polybutene is a low
molecular weight A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bio ...
oligomer In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relati ...
replacing the linseed oil.
Butyl rubber Butyl rubber, sometimes just called "butyl", is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known as "PIB" or polyisobutene, (C4H8)n, is the ...
is also added to the mixture to provide some strength and flexibility. Painter's putty is typically a linseed oil-based product used for filling holes, minor cracks, and defacements in wood only. Putties can also be made
intumescent An intumescent is a substance that swells as a result of heat exposure, leading to an increase in volume and decrease in density. Intumescent materials are typically used in passive fire protection and require listing, approval, and compliance in ...
, in which case they are used for firestopping as well as for padding of electrical outlet boxes in fire-resistance rated drywall assemblies. In the latter case,
hydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
s in the putty produce an
endothermic reaction In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. ...
to mitigate
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
transfer to the unexposed side. In
woodworking Woodworking is the skill of making items from wood, and includes cabinet making (cabinetry and furniture), wood carving, joinery, carpentry, and woodturning. History Along with stone, clay and animal parts, wood was one of the first mate ...
, water-based putties are more commonly used, as these emit very little odour, are more easily cleaned up and are compatible with water-based and latex sealers.


Polyester based putty

Polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natura ...
putty and epoxy putty are plastics that can be molded by hand but become stiff and hard after curing. Pratley Putty is an epoxy putty used primarily for steel bonding. Milliput is another epoxy putty. Bondo is a polyester putty.


Plumber's putty

Plumber's putty is the common name encompassing a variety of products of completely different compositions, all used for making watertight seals in
plumbing Plumbing is any system that conveys fluids for a wide range of applications. Plumbing uses pipes, valves, plumbing fixtures, tanks, and other apparatuses to convey fluids. Heating and cooling (HVAC), waste removal, and potable water delive ...
. It is a pliable substance used to make watertight seals around faucets and drains. The putty is a basic component of a plumber's toolkit and is often used when replacing plumbing fixtures. Plumber's putty formulations vary but commonly include powdered
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
and linseed oil. Other formulas use
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
, talc, or fish oil. RTV silicone or
epoxy Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also co ...
sealants may be used in place of putty. Plumber's putty contains
mineral oil Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils. The name 'mineral oil' by itself is imprecise ...
s and/or vegetable oils so it can stain porous materials such as marble or some plastics.


Other uses

Certain types of putty also have use in the field of terminal ballistics, where the putty can accurately represent the average density of the human body. As such it can be used, for instance, to test the penetrative power of
projectile A projectile is an object that is propelled by the application of an external force and then moves freely under the influence of gravity and air resistance. Although any objects in motion through space are projectiles, they are commonly found i ...
s, or the stopping power of body armour. Modeling clay and play putty, such as Plasticine and Silly Putty are common toys. Silly Putty comes packaged in plastic eggs.


See also

* Blu Tack * Caulk * Grain filler *
Rope caulk Rope caulk or caulking cord is a type of pliable putty or caulking Caulk or, less frequently, caulking is a material used to seal joints or seams against leakage in various structures and piping. The oldest form of caulk consisted of fibr ...
* Spackling paste * Wood putty *
Whitewash Whitewash, or calcimine, kalsomine, calsomine, or lime paint is a type of paint made from slaked lime (calcium hydroxide, Ca(OH)2) or chalk calcium carbonate, (CaCO3), sometimes known as "whiting". Various other additives are sometimes used. ...


References

* {{cite EB1911 , wstitle=Putty , volume=22 , short=x
Putty & Mastic
at wiki.DIY FAQ.org.uk Materials Passive fire protection Firestops